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41.
出露于阿尔金中段的大通沟花岗岩体,岩性主要为二长花岗岩,LA-ICP-MS锆石U-Pb年龄为(353.7±1.1)Ma。SiO_2为74.5%~76.2%,Al_2O_3为12.62%~14.15%,(Na_2O+K_2O)为7.71%~8.29%,K_2O/Na_2O为0.9~1.22,A/CNK介于1.0~1.19之间,属高钾钙碱性系列的过铝质-强过铝质花岗岩。该岩石富集大离子亲石元素(LILE),亏损素Ba、Nb、Sr、P、Ti等高场强元素(HFSE);∑REE变化范围大(∑REE=85.7×10~(-6)~153.2×10~(-6),平均为111×10~(-6)),具有强烈的负Eu异常(δEu=0.03~0.59,平均0.33),LREE/HREE=3.52~11.9,轻稀土相对富集,轻重稀土分馏明显。微量元素地球化学特征表明,其源区物质主要来源于上地壳的变杂砂岩和变泥质岩类。锆石饱和温度计演算结果显示锆石的结晶温度为722~745℃(平均735℃),估算二长花岗岩源区的压力为0.8~1.6GPa。综合区域地质资料,阿尔金中段大通沟花岗岩体的形成与造山带根部块体的拆沉作用有关。  相似文献   
42.
Cr-spinel bearing wehrlite rocks of Bangriposi are found within the multiply deformed metasedimentary rocks of Singhbhum Group belonging to North Singhbhum Mobile Belt of eastern India. Detailed mineralogical and geochemical studies reveal that these rocks have suffered a two-stage alteration involving a deeper level modal and cryptic metasomatism and a subsequent shallower depth pervasive hydrothermal alteration. Cryptic metasomatism is defined by elevated LREE contents of the wehrlite and its clinopyroxne grains. Metasomatism induced changes in the modal mineralogy of the rocks include the absence of primary orthopyroxene grains, presence of secondary diopside-phlogopite(now present as vermiculite) defining disequilibrium reaction textures and secondary orthopyroxene rims around serpentinized olivine. The mineralogical and geochemical changes due to the metasomatic event present a contrasting picture in regard to the metasomatic history of the rocks. Possible scenarios involving a single stage or multiple stage metasomatism events have been discussed while explaining the metasomatic reactions that took place. An attempt has been made to estimate the REE concentrations of the final equilibrating melt from REE contents of clinopyroxene grains of the wehrlite. The possibility of the LREE-enriched equilibrating melt of the wehrlite rocks(the deeper level metasomatic agent) being similar to residual melts from the E-MORB type parental melts of nearby gabbro suite has been ruled out by geochemical modeling. REE abundance patterns of several natural enriched melts have been compared with REE pattern of calculated LREE-enriched equilibrating melt of the wehrlite and most resemblance has been observed with calcic and potassic melts. It is therefore suggested that the Cr-spinel bearing wehrlite rocks of Bangriposi has been affected by a calcio-potassic melt in deeper level, prior to the shallow level serpentinization event.  相似文献   
43.
We present new data on the age, composition, and environments of formation of granites of the Kystarys complex and the associated Li-rich rare-element pegmatites of the South Sangilen pegmatite belt including the large Tastyg lithium deposit. It has been established that they formed during the Early Paleozoic collisional orogeny in the Tuva-Mongolian massif at the Cambrian-Ordovician boundary. The granites of the Kystarys complex are moderately alkaline high-K rocks and are enriched in Zr, Nb, Y, and REE; therefore, they are classified as postcollisional, transitional to within-plate (A-type). The spodumene pegmatites of the South Sangilen pegmatite belt are similar to the above granites in age and isotopic and geochemical parameters, which suggests a paragenetic relationship between these rocks. Pegmatites form several pegmatite fields within the belt, which differ in trace-element signatures. In addition to predominant Li, Cs, and Ta, specific to all spodumene pegmatites (LCT family), pegmatites of two fields have high contents of Nb, Y, REE, and Zr, which are indicator elements of NYF family pegmatites. It has been established that the formation of spodumene pegmatites with combined LCT-NYF geochemical signatures was preceded by the intrusion of dikes of monzogabbro with the geochemical characteristics of OIB and of alkali aegirine granites and by the formation of associated metasomatites enriched in Zr, Nb, Y, and REE. Based on the geological, mineralogical, and geochemical data, we substantiate the hypothesis of the formation of Li-bearing granite-pegmatite melts from a mixed source resulted from the influence of fluids of an alkaline igneous complex of mantle genesis on the crustal protolith.  相似文献   
44.
辽宁赛马碱性岩体早年因产铀矿而闻名,该岩体主要由响岩、霞石正长岩和异霞正长岩组成,其中铀、锆和稀土等元素矿化主要集中于异霞正长岩岩浆阶段。异性石是异霞正长岩中特征的锆-稀土矿物,主要分为两期,晚期异性石表现出更加富集Nb、REE等高场强元素的特点。早期异性石经历了一系列的热液蚀变,根据蚀变强弱程度,蚀变矿物组合可分为:(1)异性石+钠锆石+霓石±钠沸石;(2)异性石+钠锆石+锆石+钠沸石±霓石;(3)异性石假晶,假晶主要由残余异性石+钠锆石+锆石+钠沸石+霓石+钾长石+铈硅磷灰石组成。相比于岩浆锆石,蚀变组合中次生锆石具有富Ca、Al、Fe的特点,与异性石本身化学成分和流体性质密切相关。通过对异性石及其蚀变组合的精细矿物学研究,我们得知假晶的形成可能是异性石"溶解-再沉淀"的结果,致使假晶形成的流体至少包括:(1)占主导的富Na(±K)、Al、F的自交代流体;(2)少量晚期富Ca流体。假晶中次生锆石和铈硅磷灰石的结晶说明了Zr和REE等高场强元素的热液活动性,自交代碱性流体和富Ca流体在此过程中起到"搬运"和"提纯"的作用,这对认识碱性岩稀有、稀土成矿机制具有重要的指示意义。  相似文献   
45.
湘东地区锡田印支期花岗岩的地球化学特征及其构造意义   总被引:1,自引:1,他引:0  
何苗  刘庆  孙金凤  牛睿 《岩石学报》2018,34(7):2065-2086
华南印支期花岗岩分布较为分散,其构造背景长期存在争议。湘东地区的锡田印支期花岗岩位于扬子板块和华夏板块的结合带中部,主要由黑云母花岗岩和黑云母二长花岗岩组成,二者均含有较高的SiO_2(67.6%~76.8%)和全碱含量(ALK=K_2O+Na_2O,6.8%~10.7%),呈过铝质的特征(A/CNK值范围为1.0~1.2),分异指数D.I值为84~93;微量元素显示出Rb、Th、U富集和Ba、Nb、Sr、P、Ti亏损的特征,稀土元素配分图呈右倾海鸥状,轻重稀土分馏明显,指示岩体经历了高度的分异演化;P_2O_5和微量元素比值随着分异程度变化的特征,表明岩石过铝质的特征是由高度的分离结晶作用造成。锡田印支期花岗岩的ε_(Hf)(t)值为-11.3~-4.34,δ~(18)O值分布范围为6.9‰~10.8‰,O同位素分布较为分散,主要是记录了源岩与流体的不同特征。Hf同位素的二阶段模式年龄为1.6~2.2Ga,反映其源区主要为中元古-古元古代的华夏基底;Hf-O同位素呈现出良好的线性关系,同时未蚀变的花岗岩明显偏离源岩为沉积岩的大容山花岗岩,表明锡田花岗岩的形成受到了幔源岩浆的底侵作用。结合邻区邓阜仙岩体和王仙岭岩体的研究成果,显示研究区在印支期就处于伸展的构造背景,可能与古太平洋板块的俯冲作用有关。  相似文献   
46.
In the Mikengshan-Yanbei area, a special region for the tin mineralization in South China, there are some Yanshanian granites and porphyries and associated porphyry tin deposits (e.g., Yanbei). Although the tin mineralization is closely associated with the granitoids magmatism, the age and petrogenesis of the granites remain controversial. The Mikengshan pluton, which intrudes into the rhyolitic tuff and pyroclastic rocks of the Upper Jurassic Jilongzhang Formation, is the largest one in Mikengshan-Yanbei area and mainly consists of K-feldspar bearing granites. In this study, we report new age and geochemical data for the Mikengshan K-feldspar bearing granites. LA-ICP-MS zircon U-Pb age dating shows that they were generated in the Early Cretaceous (~138 Ma). They have high SiO2 (74.42% to 76.69%), low Al2O3 (12.39% to 13.49%) and Mg# (11 to 19), and negative Eu, Sr and Ba anomalies, and are rich in potassium (most K2O/Na2O=1.37 to 1.94) and high field strength elements (HFSEs), and are weakly peraluminous (A/CNK=1.03 to 1.1) with high 10000×Ga/Al ratios (3.46 to 4.96) and slightly high zircon saturation temperatures (807 ℃ to 817 ℃), showing the characteristics of the typical A-type granites. Moreover, they have high Rb contents 842×10-6 to 1295×10-6, Rb/Sr (90 to 255) ratios and show rare earth elements (REE) tetrad effect, which are similar to those of high fractionated granites. Thus, we suggested that the Mikengshan K-feldspar bearing granites are high fractionated and aluminous A-type granite. Their slightly high εNd(t) values (-3.4 to -4.6) indicate that the mantle components should have played a role during their formation. Taking into account regional igneous rocks and tectonic setting data, we suggest that the Mikengshan K-bearing granites were formed in an extensional setting, which was probably related to the roll-back of the subducted Paleo-Pacific plate. © 2018, Science Press. All right reserved.  相似文献   
47.
Saline alkaline lakes that precipitate sodium carbonate evaporites are most common in volcanic terrains in semi‐arid environments. Processes that lead to trona precipitation are poorly understood compared to those in sulphate‐dominated and chloride‐dominated lake brines. Nasikie Engida (Little Magadi) in the southern Kenya Rift shows the initial stages of soda evaporite formation. This small shallow (<2 m deep; 7 km long) lake is recharged by alkaline hot springs and seasonal runoff but unlike neighbouring Lake Magadi is perennial. This study aims to understand modern sedimentary and geochemical processes in Nasikie Engida and to assess the importance of geothermal fluids in evaporite formation. Perennial hot‐spring inflow waters along the northern shoreline evaporate and become saturated with respect to nahcolite and trona, which precipitate in the southern part of the lake, up to 6 km from the hot springs. Nahcolite (NaHCO3) forms bladed crystals that nucleate on the lake floor. Trona (Na2CO3·NaHCO3·2H2O) precipitates from more concentrated brines as rafts and as bottom‐nucleated shrubs of acicular crystals that coalesce laterally to form bedded trona. Many processes modify the fluid composition as it evolves. Silica is removed as gels and by early diagenetic reactions and diatoms. Sulphate is depleted by bacterial reduction. Potassium and chloride, of moderate concentration, remain conservative in the brine. Clastic sedimentation is relatively minor because of the predominant hydrothermal inflow. Nahcolite precipitates when and where pCO2 is high, notably near sublacustrine spring discharge. Results from Nasikie Engida show that hot spring discharge has maintained the lake for at least 2 kyr, and that the evaporite formation is strongly influenced by local discharge of carbon dioxide. Brine evolution and evaporite deposition at Nasikie Engida help to explain conditions under which ancient sodium carbonate evaporites formed, including those in other East African rift basins, the Eocene Green River Formation (western USA), and elsewhere.  相似文献   
48.
前寒武纪微陆块是北山—阿拉善北部增生造山带的重要组分,旱山、雅干和珠斯楞—杭乌拉地区的前寒武纪基底是否存在学界尚存争议.居延海介于北山造山带北部和阿拉善地块北缘的构造衔接部位,受限于巴丹吉林沙漠覆盖,岩石露头极少,我们通过钻井工程,钻遇一套晚石炭世碱性花岗岩,锆石U-Pb年龄和Hf同位素特征揭示,该花岗质岩浆锆石结晶年龄为(312±1)Ma(MSDW=0.46,n=18)和(315±2)Ma(MSWD=0.93,n=15),具有正的εHf(t)值,介于+0.8~+4.4之间,平均值为+2.2,对应二阶段模式年龄TDM2为1048~1267 Ma,平均值为1183 Ma,具有古老地壳的源区属性.通过与旱山构造带、雀儿山构造带、雅干构造带和珠斯楞—杭乌拉构造带的晚石炭世花岗质岩浆对比分析,结合旱山构造带、雅干构造带和珠斯楞—杭乌拉构造带0.9 Ga花岗质岩石的出露以及区域上的重磁资料解译,我们认为旱山、雅干和珠斯楞—杭乌拉构造带存在中—新元古代地壳,且可开展进一步的衔接关系研究.  相似文献   
49.
米仓山碱性岩中的主要矿物研究及其成因信息   总被引:3,自引:0,他引:3       下载免费PDF全文
米仓山碱性岩中的主要矿物为富铝的(次硅)铝铁质透辉石、钙质角闪石、霞石等,且大量出现霞石,但无或极少有碱性暗色矿物。研究表明:氧逸度低是碱性岩浆不能结晶出碱性暗色矿物的原因。本区这种无碱性暗色矿物的碱性岩是在封闭体系及深成条件下结晶的,而其它地区含有碱性暗色矿物的岩石则是在开放体系中形成的。  相似文献   
50.
内蒙古中部二叠纪碱性花岗岩及其地球动力学意义   总被引:95,自引:0,他引:95  
洪大卫  肖宜君 《地质学报》1994,68(3):219-230
西伯利亚板块南缘白音乌拉-东乌珠穆沁旗带的碱性花岗岩(Rb-Sr年龄276-286Ma)生成于张性的构造环境,较西伯亚板块同中朝板块之间晚泥盆世-早石炭世的碰撞事件晚约60Ma,属于造山后的A型花岗岩,可作为造山作用结束的标志。但在中朝板块北缘晚石炭世-二叠纪只发育钙碱性的晚造山花岗岩,直到三叠纪才出现碱性正长岩。相邻两大板块边缘之间岩浆活动的非对称性可能是受板块间面积和质量差别的制约。  相似文献   
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