磷灰石单晶体同步辐射X射线荧光探针成分分析   总被引：1，自引：0，他引：1  

汤云晖韩春明  保增宽黄宇营 何伟 《岩矿测试》2007,26(5):367-371

采用同步辐射X荧光（SRXRF）探针技术对河北峪耳崖和甘肃大水两地花岗岩中单颗粒磷灰石的化学成分进行了分析。结果显示，磷灰石含有P、Cl、S、K、Ca、Mn、Fe、La、Ce、Nd、Sm、Gd、Yb、Sr、Y、Zr、U、Th等多种元素，峪耳崖磷灰石富含Mn、Fe，大水磷灰石则富含As。峪耳崖花岗岩为S型，大水花岗岩为Ⅰ型，两地磷灰石在稀土元素（REE）含量上具有明显差别：大水磷灰石呈右倾的REE配分模式和明显的轻稀土（LREE）富集；而峪耳崖呈现上凸的REE配分模式和LREE亏损。依据磷灰石的REE配分模式可有效地区分不同类型的花岗岩，以此作为花岗岩岩浆演化的指示。  相似文献   

Carbon isotopes in eclogite and apatite separate from Huangzhen and Shima in SE Dabie     

LI Yiliang  ZHENG Yongfei  GONG Bing  FU Bin 《中国科学D辑(英文版)》2000,43(5):449-457

The carbon isotope compositions of high- and ultrahigh-pressure eclogite and apatite separate from Huangzhen and Shima in SE Dabie Mountains were analyzed by EA-MS online technique. The δ13C values of the eclogites cover a wide range of -30.7‰ - +1.5‰, whereas those of apatites only have a small range of -28.1‰--21.0‰. Some of the eclogites with the high δ13C values suffered retrogressive alteration by CO2-bearing fluids. The low δ13C values of the apatites indicate that the eclogites contain surficial carbon of organic origin. It is concluded that protoliths of the eclogites were exposed to the surface of the Earth, and that the carbon-bearing fluid was depleted in 13C during the eclogite-facies metamorphism.  相似文献   

鄂尔多斯盆地西南地区蓟县系古地温演化历史及岩浆热事件的影响     

于强  李荣西  任战利  雷享和  孙现瑶  杨麒可  王宝江 《地质学报》2023,97(3):922-937

深层油气成藏机理研究的首要前提是要明确烃源岩的热演化历史,这对区域油气勘探潜力的评价有着重要的指导意义。鄂尔多斯盆地西南缘蓟县系烃源岩在中生代以来的热演化史有何特征,是否受早白垩世岩浆热作用的影响,影响程度如何等问题的不明确,制约着人们对该地区中元古界烃源岩的生烃潜力的认识及进一步勘探开发的思路。通过对安口—铜城地区出露的三叠系、侏罗系及铜城岩体进行磷灰石裂变径迹、磷灰石/锆石(U-Th)/He测试,结合镜质组反射率数据,分别恢复了该地区沉积岩在中三叠世以来和侵入岩在早白垩世以来的冷却历史,结合岩浆岩体的空间分布特征和泥页岩镜质组反射率,估算蓟县系烃源岩古地温。热年代学模拟表明,蓟县系烃源岩自中生代以来先后经历了三叠纪—侏罗纪的正常埋深增温,达到了生烃温度门限,自早白垩世约130～110 Ma开始冷却,其中个别样品表现为自始新世中期至45 Ma微弱加速冷却,中新世晚期至8 Ma以来快速冷却。研究表明,中晚侏罗世是鄂尔多斯盆地西南缘蓟县系生烃的关键时期,烃源岩处于主生油温度范围,之后的早白垩世晚期岩浆侵入事件的热作用范围有限,对蓟县系烃源岩古地温的影响仅发生在局部地区。鄂尔多斯盆地西南缘...  相似文献   

辽东凸起北段新生代隆升时间的确定:来自裂变径迹的证据     

任健  吴智平  徐长贵  李伟  张晓庆  张婧 《世界地质》2015,34(2):408-418

对取自辽东凸起北段凸起带和陡坡带的6个岩芯样品进行了磷灰石裂变径迹(AFT)测试并分析了裂变径迹特征,选定其中2个样品在约束条件下进行热史模拟。结果表明,辽东凸起北段新生代经历了距今50 Ma±孔店组沉积期末及距今24 Ma±的东营组沉积期末的2次构造隆升。通过对辽东湾坳陷东西部的沉积结构和控凹断裂对比可知,辽东湾坳陷一系列NE向隆起具有相似的发育机制。结合渤海湾盆地区域构造背景,推断辽东湾坳陷辽东凸起的形成是古近纪地幔热活动引起的伸展作用在孔店组沉积期末的构造响应,形式为拆离性质的翘倾断块;而辽东凸起的第二次抬升是受东营组沉积期末发生的区域性构造抬升运动影响的结果。  相似文献   

Characterisation of Apatites as Potential Uranium Reference Materials for Fission‐track Dating by LA‐ICP‐MS          下载免费PDF全文

Cleber J. Soares  Regina Mertz‐Kraus  Sandro Guedes  Daniel F. Stockli  Thomas Zack 《Geostandards and Geoanalytical Research》2015,39(3):305-313

We report homogeneity tests on large natural apatite crystals to evaluate their potential as U reference materials for apatite fission‐track (AFT) thermochronology by laser ablation‐inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS). The homogeneity tests include the measurements of major element concentrations by electron probe microanalysis (EPMA), whereas for U concentration, isotope dilution (ID) ICP‐MS and laser ablation (LA) ICP‐MS were employed. Two apatite crystals are potential reference materials for LA‐ICP‐MS analysis: a 1 cm³ fraction of a Durango crystal (7.5 μg g^?1 U) and a 1 cm³ Mud Tank crystal (6.9 μg g^?1 U). The relative standard deviation (1 RSD) of the U concentration determined by ID‐ICP‐MS of both apatite crystals was ≤ 1.5%, whereas 1 RSD for the LA‐ICP‐MS results was better than 4%, providing sufficient homogeneity for fission‐track dating. The results on the U homogeneity for two different apatite samples are an important step towards establishing in situ dating routines for AFT analysis by LA‐ICP‐MS.  相似文献   

A tectono-genetic model for porphyry–skarn–stratabound Cu–Au–Mo–Fe and magnetite–apatite deposits along the Middle–Lower Yangtze River Valley, Eastern China     

Jingwen Mao  Guiqing Xie  Chao Duan  Franco Pirajno  Dazio Ishiyama  Yuchuan Chen 《Ore Geology Reviews》2011,43(1):294-314

The Middle–Lower Yangtze River Valley metallogenic belt (YRB), situated along the northern margin of the Yangtze craton, is characterized by porphyry–skarn–stratabound Cu–Au–Mo–Fe deposits in the areas of uplift and magnetite–apatite deposits in Cretaceous fault basins. Following detailed field investigations and a review of published data, we recognize two episodes of magmatism and mineralization in the YRB: 1) 156–137 Ma high-K calc-alkaline granitoids associated with 148–135 Ma porphyry–skarn–stratabound Cu–Au–Mo–Fe deposits and 2) 135–123 Ma shoshonitic series, associated with 134.9–122.9 Ma magnetite–apatite deposits. A-type granitoids and associated alkaline volcanic have a small age range from 126.5 to 124.8 Ma and are temporally, spatially and genetically associated with the second episode. The geodynamic history of the YRB did not experience the Paleozoic to Mesozoic lithospheric thickening that took place in the North China craton. This process is inferred to be linked to partial melting of the delaminated lower crust at high pressures, resulting in the development of C-type adakitic rocks. The petrochemical and Sr/Nd isotopic data show that both the shoshonitic series and A-type granitoids are quite different from adakites, with only some of the K-calc-alkaline granitoids having adakitic signatures. Previous ore genesis models were established based on an assumed relationship with adakites and a continuous tectono-thermal evolution from 150 to 100 Ma.All data obtained for the Middle–Lower Yangtze River region consistently show that the Tan–Lu regional strike-slip fault zone, initiated at 233 ± 6 to 225 ± 6 Ma from the collision between the North China and Yangtze cratons and was reactivated at ca. 160 Ma. The Tan–Lu fault was caused by the oblique subduction of the Izanagi plate, which along the YRB the low-angle subducted slab and the overlying crust was disrupted or broken due to the disharmonious movement of the two blocks. The high-K calc-alkaline granitoids magmas were derived from melting of the subducted slab, with some input of crustal material. These magmas were emplaced at the intersections between NE- and EW-trending faults and formed porphyry–skarn–stratabound Cu–Au–Mo–Fe deposits between 156 and 137 Ma. After 135 Ma the subducted plate changed its direction of motion to northeast, now running parallel to the Eurasian continental margin, and leading to large-scale continental extension. The shoshonitic series and subsequent A-type granitoids magmatism and the development of magnetite–apatite ores in the YRB, took place in both fault basins and NE-trending rifts between 135 and 124 Ma.  相似文献   

非稀释剂法电感耦合等离子体质谱测定磷灰石中铀钍钐同位素的含量   总被引：2，自引：0，他引：2  

张彦  陈文  胡明月 《岩矿测试》2011,30(6):727-731

准确测定238U、232Th、147Sm同位素含量是磷灰石(U-Th)/He同位素定年方法的关键。本文建立了非稀释剂法电感耦合等离子体质谱测定磷灰石中238U、232Th和147Sm同位素含量的测定流程。该方法假定样品中的238 U、232 Th和147 Sm同位素丰度与其自然丰度是一致的,根据238 U、232 Th和147 Sm同位素的自然丰度和测得的样品中总的U、Th和Sm的含量得到样品中238U、232Th和147Sm同位素的含量。对国内玄武岩标准物质和(U-Th)/He定年法的年龄标准物质Durango磷灰石进行了总U、Th、Sm含量的测试,验证流程的可行性,结果表明玄武岩标准物质的测定值与标准值在误差范围内一致,经计算得到该磷灰石的(U-Th)/He年龄为30.0 Ma,与文献获得的该磷灰石(U-Th)/He年龄(31.02±1.01)Ma(1σ)在误差范围内一致,表明本文建立的238U、232Th和147Sm同位素含量的测定流程是可行的。对于没有稀释剂的实验室,该方法简单适用,值得推广应用。  相似文献   

Evolution of Tectonic Uplift, Hydrocarbon Migration, and Uranium Mineralization in the NW Junggar Basin: An Apatite Fission-Track Thermochronology Study     

QIN Mingkuan  HUANG Shaohu  HE Zhongbo  XU Qiang  SONG Jiye  LIU Zhangyue  GUO Qiang 《《地质学报》英文版》2018,92(5):1901-1916

The Mesozoic–Cenozoic tectonic movement largely controls the northwest region of the Junggar Basin (NWJB), which is a significant area for the exploration of petroleum and sandstone-type uranium deposits in China. This work collected six samples from this sedimentary basin and surrounding mountains to conduct apatite fission track (AFT) dating, and utilized the dating results for thermochronological modeling to reconstruct the uplift history of the NWJB and its response to hydrocarbon migration and uranium mineralization. The results indicate that a single continuous uplift event has occurred since the Early Cretaceous, showing spatiotemporal variation in the uplift and exhumation patterns throughout the NWJB. Uplift and exhumation initiated in the northwest and then proceeded to the southeast, suggesting that the fault system induced a post spread-thrust nappe into the basin during the Late Yanshanian. Modeling results indicate that the NWJB mountains have undergone three distinct stages of rapid cooling: Early Cretaceous (ca. 140–115 Ma), Late Cretaceous (ca. 80–60 Ma), and Miocene–present (since ca. 20 Ma). These three stages regionally correspond to the Lhasa-Eurasian collision during the Late Jurassic–Early Cretaceous (ca. 140–125 Ma), the Lhasa-Gandise collision during the Late Cretaceous (ca. 80–70 Ma), and a remote response to the India-Asian collision since ca. 55 Ma, respectively. These tectonic events also resulted in several regional unconformities between the J3/K1, K2/E, and E/N, and three large-scale hydrocarbon injection events in the Piedmont Thrust Belt (PTB). Particularly, the hydrocarbon charge event during the Early Cretaceous resulted in the initial inundation and protection of paleo-uranium ore bodies that were formed during the Middle–Late Jurassic. The uplift and denudation of the PTB was extremely slow from 40 Ma onward due to a slight influence from the Himalayan orogeny. However, the uplift of the PTB was faster after the Miocene, which led to re-uplift and exposure at the surface during the Quaternary, resulting in its oxidation and the formation of small uranium ore bodies.  相似文献   

Late Cretaceous‐Cenozoic Multi‐Stage Denudation at the Western Ordos Block: Constraints by the Apatite Fission Track Dating on the Langshan   总被引：1，自引：0，他引：1  

CUI Xianyue  ZHAO Qihu  ZHANG Jin  WANG Yannan  ZHANG Beihang  NIE Fengjun  QU Junfeng  ZHAO Heng 《《地质学报》英文版》2018,92(2):536-555

The apatite fission track dating of samples from the Dabashan(i.e., the Langshan in the northeastern Alxa Block) by the laser ablation method and their thermal history modeling of AFT ages are conducted in this study. The obtained results and lines of geological evidence in the study region indicate that the Langshan has experienced complicated tectonic-thermal events during the the Late Cretaceous-Cenozoic. Firstly, it experienced a tectonic-thermal event in the Late Cretaceous(~90–70 Ma). The event had little relation with the oblique subduction of the Izanagi Plate along the eastern Eurasian Plate, but was related to the Neo-Tethys subduction and compression between the Lhasa Block and Qiangtang Block. Secondly, it underwent the dextral slip faulting in the Eocene(~50–45 Ma). The strike slip fault may develop in the same tectonic setting as sinistral slip faults in southern Mongolia and thrusts in West Qinling to the southwest Ordos Block in the same period, which is the remote far-field response to the India-Eurasia collision. Thirdly, the tectonic thermal event existed in the late Cenozoic(since ~10 Ma), thermal modeling shows that several samples began their denudation from upper region of partial annealing zone(PAZ), and the denudation may have a great relationship with the growth of Qinghai-Tibetan Plateau to the northeast. In addition, the AFT ages of Langshan indicate that the main body of the Langshan may be an upper part of fossil PAZ of the Late Cretaceous(~70 Ma). The fossil PAZ were destroyed and deformed by tectonic events repeatedly in the Cenozoic along with the denudation.  相似文献   

卫境岩体磷灰石裂变径迹年代学与华北北缘晚白垩世剥露事件及铀成矿   总被引：1，自引：0，他引：1  

聂逢君  张进  严兆彬  王艳楠  李满根  夏菲  朱成华  王思力  胡鉴 《地质学报》2018,92(2):313-329

中蒙边境地区的海西至燕山期卫境复式花岗岩体属于蒙古-鄂霍茨克大洋关闭后加厚地壳伸展结果的产物。该岩体的磷灰石裂变径迹年龄介于76.7~53.8 Ma之间,结合热模拟分析,卫境岩体在晚白垩世经历了一次快速的剥露事件,而在整个新生代期间则处于非常稳定的低速剥露环境中,没有明显的构造变动。卫境岩体的晚白垩世构造热事件对应于其北部和东部广大早白垩世断陷盆地内(如二连盆地、海拉尔盆地、松嫩盆地等)下白垩统和上白垩统之间的角度不整合,该不整合代表了一次构造反转事件。华北北缘在晚白垩世曾遭受过比较强烈的构造事件的影响,该事件与Izanagi板块快速向东亚之下俯冲有重要关系。综合区域低温热年代学资料,晚白垩世构造事件影响的范围可至卫境岩体以西、满都拉以东地区。模拟结果显示,卫境岩体的剥露速率约为0.1~0.2mm/a。目前华北北缘东部地貌很可能是新生代以来形成的,而非中生代早中期。铀成矿研究表明,二连盆地内晚白垩世二连组湖相泥岩中赋存超大型的同生沉积成岩铀矿化,早白垩世晚期的赛汉组中也赋存了大型的古新世-始新世时期形成的铀矿化,这些铀矿化的形成均在盆地西缘晚白垩世隆起事件之后,富含铀的卫境花岗岩遭受淋滤,铀在含铀含氧流体中不断被搬运至盆地赋矿地层中。由此可见,卫境岩体的抬升剥露是控制盆地内铀成矿的重要条件,抬升时间与二连盆地中铀矿形成的时代基本一致。  相似文献