Preferential embrittlement of graphitic schists during extensional unroofing in the Alps: the effect of fluid composition on rheology in low-permeability rocks   总被引：3，自引：0，他引：3  

J. SELVERSTONE 《Journal of Metamorphic Geology》2005,23(6):461-470

Interlayered graphitic and non‐graphitic schists from the Tauern Window, Eastern Alps, record contrasting mechanical behaviour during extensional exhumation. Graphitic schists contain mesoscale extension fractures, pervasive microcracks in garnet, and abundant secondary fluid inclusion planes; all three types of structures are oriented perpendicular to the stretching lineation. Crack spacings in garnet from graphitic samples are tightly clustered around a mean of 180 μm. Non‐graphitic schists have fewer and more randomly oriented microcracks and fluid inclusion planes and maintained strain compatibility via crystal plasticity. The presence or absence of graphite appears to have exerted a fundamental control on rheology during unroofing. Calculations for a model graphitic rock at 500 °C and f_O2 = 10^?24 MPa show that the equilibrium metamorphic fluid evolves from X_CO2 = 0.07 to 0.38 during decompression from 700 to 400 MPa, in agreement with microcrack fluid inclusion data that show a change from X_CO2 < 0.1 to 0.45 in graphitic samples over the same pressure interval. This compositional shift results in >60% expansion of the pore fluid during decompression. H₂O‐rich fluid in non‐graphitic rocks expands <15% over the same pressure interval. The greater pore fluid expansion in low‐permeability graphitic horizons likely promoted tensile failure during unroofing. These results suggest that microcracking should be an inevitable consequence of decompression in many graphitic schists, whereas rocks that lack graphite are less likely to undergo microcracking. Microseismicity is predicted to be more common in graphitic than non‐graphitic rocks during unroofing of mountain belts.  相似文献   

对羟基苯甲酸异丙酯合成的研究     

谢宗波姜国芳  张玉玲吴志清 《华东地质学院学报》2005,28(1):91-92

以浓硫酸为催化剂，研究了对羟基苯甲酸和异丙醇合成对羟基苯甲酸异丙酯的工艺条件。对影响产率的因素进行了探讨：实验表明，在以7％的浓硫酸为催化剂，反应温度为120℃，醇酸摩尔比为4：1，反应时间为5h的最佳条件下，合成了羟基苯甲酸异丙脂，通过多次重结晶的方法纯化产品，产率可达85．5％，并通过熔点仪、红外光谱等手段对产品加以表征，验证了产品具有较高的纯度。该法简单、快速、产率高、纯度好，具有较高的实用价值。  相似文献   

Assimilation and Fractional Crystallization Controlled by Transport Process of Crustal Melt: Implications from an Alkali Basalt-Dacite Suite from Rishiri Volcano, Japan   总被引：2，自引：0，他引：2  

KURITANI  TAKESHI; KITAGAWA  HIROSHI; NAKAMURA  EIZO 《Journal of Petrology》2005,46(7):1421-1442

Mechanisms of fractional crystallization with simultaneous crustalassimilation (AFC) are examined for the Kutsugata and Tanetomilavas, an alkali basalt–dacite suite erupted sequentiallyfrom Rishiri Volcano, northern Japan. The major element variationswithin the suite can be explained by boundary layer fractionation;that is, mixing of a magma in the main part of the magma bodywith a fractionated interstitial melt transported from the mushyboundary layer at the floor. Systematic variations in SiO₂ correlatewith variations in the Pb, Sr and Nd isotopic compositions ofthe lavas. The geochemical variations of the lavas are explainedby a constant and relatively low ratio of assimilated mass tocrystallized mass (‘r value’). In the magma chamberin which the Kutsugata and Tanetomi magmas evolved, a strongthermal gradient was present and it is suggested that the marginalpart of the reservoir was completely solidified. The assimilantwas transported by crack flow from the partially fused floorcrust to the partially crystallized floor mush zone throughfractures in the solidified margin, formed mainly by thermalstresses resulting from cooling of the solidified margin andheating of the crust. The crustal melt was then mixed with thefractionated interstitial melt in the mushy zone, and the mixedmelt was further transported by compositional convection tothe main magma, causing its geochemical evolution to be characteristicof AFC. The volume flux of the assimilant from the crust tothe magma chamber is suggested to have decreased progressivelywith time (proportional to t^–1/2), and was about 3 x 10^–2m/year at t = 10 years and 1 x 10^–2 m/year at t = 100years. It has been commonly considered that the heat balancebetween magmas and the surrounding crust controls the couplingof assimilation and fractional crystallization processes (i.e.absolute value of r). However, it is inferred from this studythat the ratio of assimilated mass to crystallized mass canbe controlled by the transport process of the assimilant fromthe crust to magma chambers. KEY WORDS: assimilation and fractional crystallization; mass balance model; magma chamber; melt transport; Pb isotope  相似文献   

Multi‐year water balance assessment of a newly constructed wetland,Fort McMurray,Alberta          下载免费PDF全文

Erin M. Nicholls  Sean K. Carey  Elyn R. Humphreys  M. Graham Clark  Gordon B. Drewitt 《水文研究》2016,30(16):2739-2753

Oil sands mining in Alberta transforms the boreal landscape of forests and wetlands into open pits, tailings ponds and overburden piles. Whereas reclamation efforts have primarily focused on upland forests, rebuilding wetland systems has recently become a motivation for research. Wetland creation and sustainability in this region is complicated by the sub‐humid climate and salinity of underlying mining material. In 2012, Syncrude Canada Ltd. completed the construction of the Sandhill Fen Watershed (SFW), a 52‐ha upland‐wetland system to evaluate wetland reclamation strategies on soft tailings. SFW includes an active pumping system, upland hummocks, a fen wetland and underdrains. To evaluate the influence of management practices on the hydrology of the system, this study reports the water balance from January 2013 to December 2014, the first 2 years after commissioning. A semi‐distributed approach was taken to examine the fluxes and stores of water in uplands and lowlands. Natural and artificial inputs and outputs were measured using a series of precipitation gauges and pumps, and evapotranspiration was quantified using three eddy covariance towers. A series of near surface wells recorded water table position. Both 2013 and 2014 were normal rainfall years, with 2013 having more and 2014 less snow than normal. In 2013, inflow/outflow from pumping was the predominant hydrological fluxes, resulting in considerable variability in water table position and storage changes throughout the summer. In 2014, the artificial addition of water was negligible, yet the water table remained near the surface in lowland locations, suggesting that wetland conditions could be maintained under current conditions. Evapotranspiration rates between uplands and lowlands were similar between years and sites, ranging from 2.2 ± 1.8 to 2.5 ± 1.2 mm/day and were largely controlled by climate. These rates were less than nearby older upland systems, suggesting that water balance partitioning will change as vegetation develops. Comparison between years and with natural systems provides insight on how management practices influence hydrologic dynamics and the overall water balance of the SFW. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

Pixel‐oriented land use classification in energy balance modelling          下载免费PDF全文

Giuseppina Scavone  Vito Telesca  Vicente Caselles  Vito A. Copertino  Vittoria Pastore  Enric Valor 《水文研究》2014,28(1):25-36

Mass and energy transfer between soil, vegetation and atmosphere is the process that allows to maintain an adequate energy and water balance in the earth–atmosphere system. However, the evaluation of the energy balance components, such as the net radiation and the sensible and latent heat fluxes, is characterized by significant uncertainties related to both the dynamic nature of heat transfer processes and surfaces heterogeneity. Therefore, a detailed land use classification and an accurate evaluation of vegetation spatial distribution are required for an accurate estimation of these variables. For this purpose, in the present article, a pixel‐oriented supervised classification was applied to obtain land use maps of the Basilicata region in Southern Italy by processing three Landsat TM and ETM+ satellite images. An accuracy analysis based on the overall accuracy index and the agreement Khat of Cohen coefficient showed a good performance of the applied classification methodology and a good quality of the obtained maps. Subsequently, these maps were used in the application of a simplified two‐source energy balance model for estimating the actual evapotranspiration at a regional scale. The comparison between the simulations made by applying the simplified two‐source energy balance model and the measurements of evapotranspiration at a lysimetric station located in the study area showed the applicability and the validity of the proposed methodology. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

Deducing the spatial variability of exchange within a longitudinal channel water balance          下载免费PDF全文

Noah M. Schmadel  Bethany T. Neilson  Tamao Kasahara 《水文研究》2014,28(7):3088-3103

Developing an appropriate data collection scheme to infer stream–subsurface interactions is not trivial due to the spatial and temporal variability of exchange flowpaths. Within the context of a case study, this paper presents the results from a number of common data collection techniques ranging from point to reach scales used in combination to better understand the spatial complexity of subsurface exchanges, infer the hydrologic conditions where individual influences of hyporheic and groundwater exchange components on stream water can be characterized, and determine where gaps in information arise. We start with a tracer‐based, longitudinal channel water balance to quantify hydrologic gains and losses at a sub‐reach scale nested within two consecutive reaches. Next, we look at groundwater and stream water surface levels, shallow streambed vertical head gradients, streambed and aquifer hydraulic conductivities, water chemistry, and vertical flux rates estimated from streambed temperatures to provide more spatially explicit information. As a result, a clearer spatial understanding of gains and losses was provided, but some limitations in interpreting results were identified even when combining information collected over various scales. Due to spatial variability of exchanges and areas of mixing, each technique frequently captured a combination of groundwater and hyporheic exchange components. Ultimately, this study provides information regarding technique selection, emphasizes that care must be taken when interpreting results, and identifies the need to apply or develop more advanced methods for understanding subsurface exchanges. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Continuous measurement of whole‐tree water balance for studying urban tree transpiration          下载免费PDF全文

Takashi Asawa  Tomoki Kiyono  Akira Hoyano 《水文研究》2017,31(17):3056-3068

Street and garden trees in urban areas are often exposed to advection of strong vapour pressure deficit (VPD) air that can raise the whole‐tree transpiration rate (E_T), known as the oasis effect. However, urban trees tend to have small soil volume compared with natural conditions, and so they are believed to strongly regulate stomata. E_T characteristics of such urban trees have not been well understood because of a lack of reliable measurement methods. Therefore, we propose a novel weighing lysimeter method and investigate the whole‐tree water balance of an isolated container‐grown Zelkova serrata to examine (a) which biotic and abiotic factors determine E_T and (b) which spatial and temporal information is needed to predict E_T under urban conditions. Whole‐tree water balance and environmental conditions were measured from 2010 to 2012. Although leaf area substantially increased in the study period, daily E_T did not vary much. E_T increased with VPD almost linearly in 2010 but showed saturation in 2011 and 2012. Root water uptake lagged E_T by 40 min in 2012. These results suggest that the small planter box interfered with root growth and that hydraulic supply capacities did not increase sufficiently to support leaf area increase. From analysis of water balance, we believe that neglecting soil drought effects on street trees without irrigation in Japan will overestimate E_T over 4–5 sunny days at the longest. This is unlike previous studies of forest.  相似文献   

Understory and small trees contribute importantly to stemflow of a lower montane cloud forest          下载免费PDF全文

Teresa Margarita González‐Martínez  Guadalupe Williams‐Linera  Friso Holwerda 《水文研究》2017,31(5):1174-1183

Stemflow (Sf) measurements in tropical rain and montane forests dominated by large trees rarely include the understory and small trees. In this study, contributions of lower (1‐ to 2‐m height) and upper (>2‐m height and <5‐cm diameter at breast height [DBH]) woody understory, small trees (5 < DBH < 10 cm), and canopy trees (>10‐cm DBH) to Sf per unit ground area (Sf_a) of a Mexican lower montane cloud forest were quantified for 32 days with rainfall (P) during the 2014 wet season. Rainfall, stemflow yield (Sf_y), vegetation height, density, and basal area were measured. Subsequently, stemflow funneling ratios (SFRs) were calculated, and three common methods to scale up Sf_y from individual trees to the stand level (tree‐Sf_y correlation, P‐Sf_y correlation, and mean‐Sf_y extrapolation) were used to calculate Sf_a. Understory woody plants, small trees, and upper canopy trees represented 96%, 2%, and 2%, respectively, of the total density. Upper canopy trees had the lowest SFRs (1.6 ± 0.5 Standard Error (SE) on average), although the lower understory had the highest (36.1 ± 6.4). Small trees and upper understory presented similar SFRs (22.9 ± 5.4 and 20.2 ± 3.9, respectively). Different Sf scaling methods generally yielded similar results. Overall Sf_a during the study period was 22.7 mm (4.5% of rainfall), to which the understory contributed 70.1% (15.9 mm), small trees 10.6% (2.4 mm), and upper canopy trees 19.3% (4.4 mm). Our results strongly suggest that for humid tropical forests with dense understory of woody plants and small trees, Sf of these groups should be measured to avoid an underestimation of overall Sf at the stand level.  相似文献   

Why asymptotic limit of the acid dissolution capacity can lead to a sharp dissolution front in chemical dissolution of porous rocks?          下载免费PDF全文

Chongbin Zhao  B.E. Hobbs  A. Ord 《国际地质力学数值与分析法杂志》2017,41(15):1590-1602

The use of the asymptotic limit can greatly simplify the theoretical analysis of chemical dissolution front instabilities in fluid‐saturated rocks and therefore make it possible to obtain mathematical solutions, which often play a crucial role in understanding the propagation behavior of chemical dissolution fronts in chemical dissolution systems. However, there has been a debate in recent years that the asymptotic limit of the acid dissolution capacity (i.e., the acid dissolution capacity number approaching zero) alone cannot lead to a sharp dissolution front of the Stefan type in the acidization dissolution system, in which the dissolvable minerals of carbonate rocks are chemically dissolved by the injected acid flow. The acid dissolution capacity number is commonly defined as the ratio of the volume of the carbonate rock dissolved by an acid to that of the acid. In this paper, we use four different proof methods, including (i) direct use of the fundamental concepts; (ii) use of the mathematical governing equations of an acidization dissolution system; (iii) use of the different time scaling approach; and (iv) use of a moving coordinate system approach, to demonstrate that the asymptotic limit of the acid dissolution capacity can indeed lead to sharp dissolution fronts of the Stefan type in acidization dissolution systems on a much larger time scale (than the dissolution time scale). Our new finding is that on the reaction time scale, the condition of the conventional time derivative of porosity approaching zero alone can ensure that the acidization dissolution front has a sharp shape of the Stefan type. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   

Unraveling complex hydrogeological processes in Andean basins in south‐central Chile: An integrated assessment to understand hydrological dissimilarity          下载免费PDF全文

Enrique Muñoz  José Luis Arumí  Thorsten Wagener  Ricardo Oyarzún  Victor Parra 《水文研究》2016,30(26):4934-4943

Groundwater storage, drainage, and interbasin water exchange are common hydrological processes but often difficult to quantify due to a lack of local observations. We present a study of three volcanic mountainous watersheds located in south‐central Chile (~36.9 ° S) in the Chillán volcanic complex (Chillán, Renegado, and Diguillín river basins). These are neighboring basins that are similar with respect to the metrics normally available for characterization everywhere (e.g., precipitation, temperature, and land cover). In a hydrological sense, similar (proportional) behavior would be expected if these catchments would be characterized with this general information. However, these watersheds show dissimilar behavior when analyzed in detail. The surface water balance does not fit for any of these watersheds individually; however, the water balance of the whole system can be explained by likely interbasin water exchanges. The Renegado river basin has an average annual runoff per unit of area on the order of 60–65% less than those of the Diguillín and Chillán rivers, which is contradictory to the hydrological similarity among the basins. To understand the main processes that control streamflow generation, two analyses were performed: (a) basin metrics (land cover, geologic, topographic, and climatological maps) and hydro‐meteorological data analyses and (b) a water balance model approach. The analyses contribute to a plausible explanation for the hydrogeological processes in the system. The soils, topography, and geology of the Chillán–Renegado–Diguillín system favor the infiltration and groundwater movements from the Renegado river basin, mainly to the neighboring Diguillín basin. The interbasin water exchanges affect hydrological similarity and explain the differences observed in the hydrological processes of these three apparently similar volcanic basins. The results highlight the complexity of hydrological processes in volcanic mountainous systems and suggest that a simple watershed classification approach based on widely available data is insufficient. Simple local analyses such as specific flow analysis with a review of the geology and morphology can contribute to a better understanding of the hydrology of volcanic mountainous areas.  相似文献