重金属污染胁迫下盐肤木的生化效应及波谱特征   总被引：11，自引：1，他引：10  

李庆亭  杨锋杰  张兵  张霞  周广柱 《遥感学报》2008,12(2):284-290

利用遥感生物地球化学的原理和方法,分析了德兴铜矿的重金属污染状况和植物盐肤木的生物地球化学效应,对盐肤木生物地球化学效应的波谱特征进行了系统的提取和分析.研究发现酸、铜、镉等是德兴铜矿地区主要的环境污染因子,野外调查及样品的化验分析表明盐肤木对铜元素呈现一定的富集作用和很强的位移效应,是适合铜矿复垦的植被.利用导数光谱、包络线去除、红边效应、植被指数等光谱信息处理方法对盐肤木的野外波谱分析表明,随着叶片中Cu等金属元素含量的增大,其产生的毒化效应的波谱特征越明显,盐肤木叶片光谱反射率明显升高,波形蓝移,红边陡坡斜率增大,叶绿素吸收深度变浅,吸收中心稍有蓝移,水的吸收深度变浅,吸收中心位置红移,绿度指数变化明显.对波谱特征及其与重金属含量的相关关系综合分析后认为,红边特征、植被指数NDVI、叶绿素吸收深度与叶片铜含量关系显著,可以作为植被铜污染遥感图像特征提取的参考.  相似文献   

西湖茶园茶叶铅污染铅同位素示踪     

郦逸根  路远发 《物探与化探》2008,32(2):180-185

通过对西湖茶园的植物和土壤样品进行一系列的调查,以着力寻找茶叶的铅污染源。利用铅同位素技术对西湖茶园的土壤、茶叶和城区的燃煤、大气气溶胶、汽车尾气进行铅同位素示踪研究。研究表明,茶园土壤铅物质的可溶相具同源性和残查态偏于多源性。清洗后的茶叶铅含量显著降低,但其同位素组成不发生明显改变,显示出茶叶中的铅与叶面空气沉降物中的铅同源。不同介质铅同位素对比值平均值呈现表土、大气(气溶胶)、煤的w(²⁰⁶Pb)/w(²⁰⁷Pb)与茶叶趋于相近,汽油低之;表土、大气(气溶胶)、汽油的w(²⁰⁸Pb)/〔w(²⁰⁶Pb)+w(²⁰⁷Pb)〕与茶叶趋于相近,煤略高之。不同区域茶叶铅物质具同源性,与种植的农业地质背景无关。在煤燃烧、气化过程中,Pb进入大气,通过大气沉降或被茶树吸收或附着在茶叶叶面;汽车尾气的排放是茶树铅污染的重要原因之一。  相似文献   

广饶县河流污染带地下水水质现状评价与污染分析   总被引：1，自引：0，他引：1  

赵金香  王兆林  张淑芳 《地下水》2008,30(3):43-47

多年来由于接纳上游和境内工业、生活污废水,淄河、阳河、织女河三条河流大部分时间水质为劣V类,沿河两测形成2km左右的浅层地下水污染带。对污染带内地下水水质现状进行评价与分析、应用模糊综合评价法进行污染程度评价。得出的结论是河流两岸浅层地下水水质由以优良或良好为主变为以较差或极差为主,污染和微污染的地下水井占81．2％,石油类、亚硝酸盐氮、氨氮、挥发酚、硝酸盐氮、高锰酸盐指数等主要污染参数超标率均在30％以上。  相似文献   

黑色页岩与土壤重金属污染   总被引：6，自引：1，他引：5  

余昌训  彭渤  唐晓燕  谢淑容  吴甫成  尹春艳  杨广  涂湘林 《矿物岩石地球化学通报》2008,27(2)

本文利用ICP—MS等技术分析了湘中地区黑色页岩及其相应土壤的重金属含量,在对分析结果进行统计分析的基础上,探讨了黑色页岩与土壤重金属污染的关系。研究表明,黑色页岩是富集多种重金属元素的特殊岩石。以黑色页岩岩系为母岩的土壤,不仅明显富集Cu、Cd、Cr、Co、Pb、Zn、Mo、Ni、V、U、Sn、Sb、T1、Th等多种重金属元素,而且受到Mo、Sb、Cd、U、Tl、Cu、V、Sn、Th等重金属的污染,其中以Mo、Cd、Sb、U、Tl等的污染尤为严重。黑色页岩土壤重金属污染在一些地方已产生明显的负面环境效应,值得关注。  相似文献   

天然水铬污染与其同位素组成的相关性研究     

李理  马腾  刘存富  高永娟 《地球学报》2008,29(6):790-794

Cr(Ⅵ)作为水体中重要的污染物质,其同位素组成对水体环境变化具有较强的敏感性.铬在氧化还原过程中产生明显的同位素分馏作用,根据水体中铬的同位素组成可指示水环境中Cr(Ⅵ)的还原程度.笔者以黄石某无机盐厂周围污染水体为例,对天然水体中的铬污染及其同位素组成的相关性进行了分析研究.  相似文献   

Radiocarbon redating of contaminated samples from a tropical volcano: the Mansion ‘Series’ of St Kitts,West Indies     

D. D. Harkness  M. J. Roobol  A. L. Smith  J. J. Stipp  P. E. Baker 《Bulletin of Volcanology》1994,56(5):326-334

Heavy rainfall and dense vegetation on tropical volcanoes produce abundant carbonized wood in pyroclastic deposits, in addition to easy contamination of this wood by root systems and soluble humic material. Because the physical nature of the charcoal varies, some samples are more prone to contamination. Two independent studies of the same volcano, Mt Liamuiga on St Kitts in the Lesser Antilles, sometimes using samples from the same carbonized tree, yielded a systematic difference in radiocarbon ages. An exchange of samples and a re-investigation of three physically distinct types of charcoal yielded the following results. Rare, hard, dense charcoal, lacking contamination, which had yielded a spurious age of 2860 years bp, was redated at 1845±58 years bp. Common soft, friable charcoal with good cellular structure proved to be susceptible to contamination. A field decontamination technique utilized by one group seems significant as it yields older ages than when only routine laboratory pre-treatment was used, indicating that the latter technique only partly removes the dried and hard residue produced by the decomposition of modern plant rootlets. A previous date of 24870 years bp obtained from powdery charcoal in a horizon beneath the Mansion Series contradicted ages older than 41000 years bp from common friable charcoal in the lower Mansion Series. The soft powdery charcoal was re-investigated using a sample collected a few centimeters from the original, although field decontamination of this sample was not possible, more extensive laboratory treatment yielded an age of ca. 43000 years bp, again proving that routine laboratory pretreatments are inadequate. A revised geochronology for the Mansion Series is described and a cautionary discussion is presented for the benefit of investigators using radiocarbon ages to date volcanic deposits.  相似文献   

Geochemistry and petrogenesis of the post-orogenic bimodal dyke swarms in NW Sinai, Egypt: constraints on the magmatic–tectonic processes during the late Precambrian     

M.M El-Sayed   《Chemie der Erde / Geochemistry》2006,66(2):129-141

The study area in the northwest Sinai represents one of the most significant regions in the Egyptian basement intensely invaded by post-orogenic calc-alkaline dyke swarms. Two post-orogenic dyke swarms have been recognized in NW Sinai namely: (1) mafic dykes of basalt, basaltic andesite and andesite composition and (2) felsic dykes of dacite, rhyodacite and rhyolite composition. These basaltic to rhyolitic dykes intruded contemporaneously and shortly after the intrusion of the post-orogenic leucogranite. The mafic and felsic dykes are enriched in incompatible elements, especially in the large ion lithophile elements (e.g. K, Rb, Ba) and depleted in high field strength elements with negative P, Ti and Nb anomalies. Major and trace element geochemistry indicates that investigated mafic and felsic magma types are not related via fractional crystallization. The protoliths of the mafic and felsic dykes appear to have evolved from different parental magmas. The incompatible trace element patterns favour a derivation of the mafic dykes from melting of a garnet peridotite source followed by fractional crystallization of olivine, clinopyroxene amphibole and zircon. The felsic dykes, on the other hand, could be generated by melting of garnet-free source modified subsequently by fractional crystallization of plagioclase, apatite and titanomagnetite. This implies variable source characteristics at the end of the Pan-African in the NW Sinai.The mafic and felsic dykes can be related to an intracontinental setting and that this was accompanied by a chemical evolution of the subcontinental lithosphere. Magma generation and ascent in the area was favoured by extensional movements, which is already known from other areas in NE Africa.  相似文献   

Permeable Reactive Barrier for the treatment of contaminated surface water in Katedan industrial development area, Hyderabad, India     

Savitri Tripathi Vandana Parth Phani Homeshwari M. Vittal Babu N. Murthy N.N. Sorlie J.E. Govil P.K. 《中国地球化学学报》2006,25(B08):117-118

Permeable Reactive Barrier （PRB） is an emplacement of inert material （s） in the subsurface, designed to intercept a contaminated plume, provides a preferential flow path through the reactive media, and transforms the contaminant into environmentally acceptable forms to attain concentration remediation goals at the discharge of the barrier. The phenomena, which help in remediation within PRB, are adsorption/sorption, precipitation, oxidation/reduction and biodegradation. Various materials like zero-valent iron, zero-valent bi-metals, natural zeolites, organic carbon, fly ash, zeolites, limestone, activated alumina, apatites, etc. have been tried by many researchers to remove organic and inorganic contaminants. In USA, Canada, and many European countries commercial full-scale and pilot scale PRBs are successfully working. The design and installation of full scale PRBs needs laboratory treatability and dynamic flow column experiments？ The concept of PRB is being applied to treat contaminated surface water in the Katedan industrial area, Hyderabad, India. National Geophysical Research Institute （NGRI）, Hyderabad, India, conducted systematic studies in collaboration with Norwegian Geotechnical Institute （NGI）, Norway, to develop PRB technique to decontaminate the surface water pollution due to industrial effluent. A site assessment study in the Katedan Industrial Area, were carried out and water, soil and sediment from the lakes of the area were found to be polluted with high concentrations of heavy metals like As, Pb, Cr, Cd, Ni, etc. Adsorption studies at NGRI with synthetic samples and in-situ industrial effluent using different reactive media for removing contaminants like arsenic, chromium, cadmium, copper, nickel, lead and zinc have been carried out and yielded satisfactory results. The performance of zero-valent iron and limestone is encouraging in removing As,  相似文献   

Heavy metal contamination in the sediment of the Second Songhua River   总被引：1，自引：0，他引：1  

Chunye LIN Mengchang HE Baixing YAN Xiangchun QUAN Yuxiang ZHOU Wei GUO Zhifeng YANG 《中国地球化学学报》2006,25(B08):118-119

The Second Songhua River was subjected to a large amount of untreated effluent from petrochemical industries in Jilin City in the 1960s to the 1970s. The objectives of this study were to investigate the mercury and other heavy metal contamination in the sediment of the river. The river bottom sediment was sampled from the river segment between Jilin City to Haerbin City in 2005. Total concentrations of Hg, Cd, Cu, Cr, Pb, Zn, Ni, As, Sc, and major cations （A1, Fe, Mg, Ca, K, Na） in the sediment were measured by atomic fluorescence spectrometer, ICP-MS, and ICP-OES, respectively, following digestion with various acids. We found the concentrations of most elements in the uncontaminated sediment were significantly correlated to those of Sc.  相似文献   

Metal contamination in southern Brazil vineyard softs     

《中国地球化学学报》2006,25(B08):120-120

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