Latitudinal variation of measured O3 photolysis frequencies J(O1D) and primary OH production rates over the Atlantic Ocean between 50° N and 30° S     

A. Hofzumahaus  T. Brauers  U. Platt  J. Callies 《Journal of Atmospheric Chemistry》1992,15(3-4):283-298

The latitudinal variation of the photolysis frequency of ozone to O(¹D) atoms, J(O¹D), was measured using a filter radiometer during the cruise ANT VII/1 of the research vessel Polarstern in September/October 1988. The J(O¹D) noon values exhibited a maximum of 3.6×10^-5 s^-1 (2 sr) at the equator and decreased strongly towards higher latitudes. J(O¹D) reached highest values for clean marine background air with low aerosol load and almost cloudless sky. The J(O¹D) data, measured under these conditions and a temperature of 295 K, can be expressed by: % MathType!MTEF!2!1!+-% feaafiart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGaamOsaiaacI% cacaqGpbWaaWbaaSqabeaaiiaacqWF8baFaaGccaqGebGaaeykaiaa% bccacqWF9aqpcaqGGaGaaeyzaiaabIhacaqGWbGaaeiiaiaabUhacq% GHsislcaaI4aGaaiOlaiaaicdacaaIYaGaeyOeI0IaaGioaiaac6ca% caaI4aGaaiiEaiaaigdacaaIWaWaaWbaaSqabeaacqGHsislcaaIZa% aaaOGaaeiiaiaabIhacaqGGaGaam4uaiabgUcaRiaaiodacaGGUaGa% aGinaiaacIhacaaIXaGaaGimamaaCaaaleqabaGaeyOeI0IaaGOnaa% aakiaadofadaahaaWcbeqaaiaaikdaaaGccaGG9bGaaeikaiaaboha% daahaaWcbeqaaiabgkHiTiaaigdaaaGccaGGPaaaaa!5EE9!\[J({\text{O}}^| {\text{D) }} = {\text{ exp \{ }} - 8.02 - 8.8x10^{ - 3} {\text{ x }}S + 3.4x10^{ - 6} S^2 \} {\text{(s}}^{ - 1} )\] where S represents the product of the overhead ozone column (DU) and the secant of the solar zenith angle. The meridional profile of the primary OH radical production rate P(OH) was calculated from the J(O¹D) measurements and simultaneously recorded O₃ and H₂O mixing ratios. While the latitudinal distribution of J(O¹D) and water vapour was nearly symmetric to the equator, high tropospheric ozone levels up to 40 ppb were observed in the Southern Hemisphere, SH, resulting in higher P(OH) in the SH.  相似文献   

青藏高原腹地湖泊沉积对第四纪晚期古季风变化的响应   总被引：2，自引：0，他引：2  

胡东生  张华京  徐冰  李炳元  孔照辰  温景春 《干旱区地理》2006,29(4):483-489

通过对青藏高原腹地的综合科学考察和对中心钻孔岩芯剖面的最新研究,用层序地层学与年代地层学和气候地层学相结合的方法,分辨出可可西里地区湖泊沉积记录(孔深7.25 m)的第四纪晚期距今3万余年以来的古气候变化,沉积物磁化率等因子综合表征的高原古季风变化是波动发展的,发生在仙女木期地质环境事件中的季风活动具有强烈暴发的特点,是高原季风发展中的突变事件,而且地表热点效应对其起到了激发作用。综合分析的研究成果表明,它的变化频谱与激变因子及其运行机制是伴随着青藏高原地质效应的演变而发展的,为研究第四纪冰消期以来的气候变化提供了新的信息。  相似文献   

Effect of some additives on synthesis of zeolite from coal fly ash   总被引：3，自引：0，他引：3  

Deyi Wu  Bohua Zhang  Li Yan  Hainan Kong  Xinze Wang 《International Journal of Mineral Processing》2006,80(2-4):266-272

Hydrothermal conversion of fly ash into zeolites was conducted and the effects of the addition of sodium halide and waste solutions produced after zeolitization of fly ash, as well as the adjustment of the Si/Al ratio prior to synthesis process on the formation and cation exchange capacity (CEC) of zeolite product were evaluated. Both the addition of NaCl and NaF ameliorated the crystallinity and CEC of synthesized zeolite, but NaF had a better improvement effect. Na⁺ was considered to enhance the crystallization of zeolite, while F⁻ favored the dissolution of fly ash. The type of zeolite formed depended on the Si/Al ratio of the starting material prior to the nucleation and crystallization of zeolite. The adjustment of the Si/Al ratio of fly ash by addition of Na₂SiO₄ and Al(OH)₃ changed the type and CEC of zeolite. Waste solutions contained large amount of Si and little Al due to the formation of a zeolite named NaP1 in zeolite terminology with the Joint Committee of Powder Diffraction Standard (JCPDS) code of 39-0219. The alkalinity decreased largely. As a result, the CEC value of zeolite products synthesized with waste solution as alkali source decreased. The supplementation of new alkali to adjust the alkalinity of waste solution could enhance the CEC of synthesized product. It was concluded that: (1) addition of sodium halide and adjustment of the Si/Al ratio prior to synthesis can improve the quality of zeolite; (2) waste solutions produced following the zeolitization of fly ash can be reused as an alkali source in the activation of fly ash; zero-emission of waste solution in the synthesis of zeolite from fly ash is possible.  相似文献   

A reassessment of models for hydrocarbon generation in the Khibiny nepheline syenite complex, Kola Peninsula, Russia   总被引：2，自引：0，他引：2  

B. Beeskow  P.J. Treloar  A.H. Rankin  T.W. Vennemann  J. Spangenberg 《Lithos》2006,91(1-4):1-18

Although hydrocarbon-bearing fluids have been known from the alkaline igneous rocks of the Khibiny intrusion for many years, their origin remains enigmatic. A recently proposed model of post-magmatic hydrocarbon (HC) generation through Fischer-Tropsch (FT) type reactions suggests the hydration of Fe-bearing phases and release of H₂ which reacts with magmatically derived CO₂ to form CH₄ and higher HCs. However, new petrographic, microthermometric, laser Raman, bulk gas and isotope data are presented and discussed in the context of previously published work in order to reassess models of HC generation. The gas phase is dominated by CH₄ with only minor proportions of higher hydrocarbons. No remnants of the proposed primary CO₂-rich fluid are found in the complex. The majority of the fluid inclusions are of secondary nature and trapped in healed microfractures. This indicates a high fluid flux after magma crystallisation. Entrapment conditions for fluid inclusions are 450–550 °C at 2.8–4.5 kbar. These temperatures are too high for hydrocarbon gas generation through the FT reaction. Chemical analyses of rims of Fe-rich phases suggest that they are not the result of alteration but instead represent changes in magma composition during crystallisation. Furthermore, there is no clear relationship between the presence of Fe-rich minerals and the abundance of fluid inclusion planes (FIPs) as reported elsewhere. δ¹³C values for methane range from − 22.4‰ to − 5.4‰, confirming a largely abiogenic origin for the gas. The presence of primary CH₄-dominated fluid inclusions and melt inclusions, which contain a methane-rich gas phase, indicates a magmatic origin of the HCs. An increase in methane content, together with a decrease in δ¹³C isotope values towards the intrusion margin suggests that magmatically derived abiogenic hydrocarbons may have mixed with biogenic hydrocarbons derived from the surrounding country rocks.  相似文献   

A Review of Studies Dealing with Tree Rings and Rockfall Activity: The Role of Dendrogeomorphology in Natural Hazard Research   总被引：1，自引：0，他引：1  

M. Stoffel 《Natural Hazards》2006,39(1):51-70

Over the last few years, rockfall research has increasingly focused on hazard assessment and risk analysis. Input data on past rockfall activity were gathered from historical archives and lichenometric studies or were obtained through frequency–volume statistics. However, historical records are generally scarce, and lichenometry may only yield data with relatively low resolutions. On forested slopes, in contrast, tree-ring analyses may help, generally providing annual data on past rockfall activity over long periods. It is the purpose of the present literature review to survey the current state of investigations dealing with tree-ring sequences and rockfall activity, with emphasis on the extent to which dendrogeomorphology may contribute to rockfall research. Firstly, a brief introduction describes how dendrogeomorphological methods can contribute to natural hazard research. Secondly, an account is provided of the output of dendrogeomorphological studies investigating frequencies, volumes or spatial distributions of past rockfall activity. The current and potential strengths of dendrogeomorphology are then presented before, finally, the weaknesses of tree rings as natural archives of past rockfall activity are discussed and promising directions for further studies outlined.  相似文献   

Assessing the Vibrational Frequencies of the Cathedral of Cologne (Germany) by Means of Ambient Seismic Noise Analysis   总被引：1，自引：0，他引：1  

Andreas Fäcke  Stefano Parolai  Sandra M. Richwalski  Lothar Stempniewski 《Natural Hazards》2006,38(1-2):229-236

Ambient seismic noise measurements were conducted inside the Cathedral of Cologne (Germany) for assessing its frequencies of vibration and for checking whether these occur in the range where soil amplification is expected. If this is the case, damages may increase in case of an earthquake due to an increased structural response of the building. Analysis of the ratio between the horizontal and vertical components of the spectra recorded at stations located inside the building as well as the ratio between the corresponding components of the spectra recorded simultaneously inside the building and at a reference station placed in the basement of the cathedral indicated several modes of vibration. Facilitated by these results an assessment of the seismic vulnerability was attempted for a 2D ground motion scenario using the finite element method.  相似文献   

Control of dust emissions by geomorphic conditions, wind environments and land use in northern China: An examination based on dust storm frequency from 1960 to 2003   总被引：9，自引：1，他引：9  

Xunming Wang  Zijiang Zhou  Zhibao Dong 《Geomorphology》2006,81(3-4):292-308

The degree to which dust emissions are controlled by geomorphic conditions, wind environments and land use was investigated using the dust storm frequency (DSF) and data from more than 300 meteorological stations throughout northern China. Our analysis showed that most dust emissions originated in gobi deserts that developed in piedmont alluvial fans of the Kunlun, Qilian and Helan mountains. Dust emissions are low from other gobi desert regions, such as the northern Gurbantunggut and eastern Taklimakan, where high vegetation coverage restrained dust emissions or where dust-size particles are not abundant after a long period of strong wind erosion. Sandy deserts with relatively high vegetation coverage or an extensive cover by mobile sands are not a major dust source. Although the highest dust emissions did not appear in regions with the highest wind energy, DSF trends in each region from 1960 to 2003 were closely related to local wind activity. DSF was low in regions with high levels of human activity, where the mean DSF from 1960 to 2003 did not exceed 4 days/year; even from the 1960s to the early 1970s, the period with the greatest DSF, frequency did not exceed 8 days/year, which indicates that extensive land use did not contribute to DSF. The low DSF in these areas might result from the fact that although land use could produce abundant fine soil fractions, vegetation coverage and soil moisture remained higher than in the gobi deserts of arid China, thereby decreasing dust-storm occurrence.  相似文献   

Flood seasonality and generating conditions in the Tay catchment, Scotland from 1200 to present   总被引：1，自引：0，他引：1  

Lindsey J McEwen 《Area》2006,38(1):47-64

The new maximum recorded river flows in Scotland since 1988 have triggered widespread interest in whether floods are becoming more frequent and in the conditions that generate floods of different magnitudes and frequencies. There are questions about the longer-term variability in flood-generating characteristics, and whether there are past analogues for present hydroclimatic variability. The present paper builds on previous work reconstructing a detailed historic flood chronology for the Tay, the largest catchment in Scotland, and its tributaries over the past 800 years, extending the gauged discharge record (1952 onwards). It categorizes flood-generating factors in the Tay catchment and analyses the hydro-meteorological conditions that have generated extreme and moderate floods over a historical period. This work is placed in a broader literature context of historical 'climaxes of storminess', periods of higher storm frequency, flood patterns observed in Scotland and Europe during the Little Ice Age and longer-term rainfall and temperature patterns. The paper concludes that the variability in flood-generating characteristics is highly dependent on the timescale of observation. Inevitably the relative dominance of winter and early spring flooding can vary from year to year and within specific time-periods, but so can the level of augmentation of the flood series with summer and autumn floods to produce notable 'flood years' and flood clusters. The Tay provides a good 'all-Scotland surrogate' for historical flood patterns, reflecting its gathering areas in eastern and western Scotland. The value of a historical approach to the assessment of flood seasonality and generating characteristics is clearly demonstrated.  相似文献   

Documentary Evidence of an Economic Character as a Source for the Study of Meteorological and Hydrological Extremes and their Impacts on Human Activities   总被引：1，自引：0，他引：1  

Rudolf Brázdil  Hubert Valá&#;ek  Kate&#;ina Chromá 《Geografiska Annaler: Series A, Physical Geography》2006,88(2):79-86

This paper deals with documentary evidence of an economic character as a proxy for direct study of meteorological and hydrological extremes. Taxation records and reports of those who administrated domains and estates are described with respect to information about meteorological and hydrological extremes. Based on data from eight domains or estates from Moravia (in the Czech Republic), frequency series of floods and convective storms (including hailstorms) were developed for the period 1650–1849. One example of disastrous weather, which took place on 10 August 1694 in the Pern?tejn domain, is used to demonstrate the potential for such studies of the intensity of extremes and their impact on human activities. The importance of economic evidence in the instrumental period is shown through tax rebate data contingent upon hailstorm damage in Moravia (1896–1906). The benefits of employing documentary economic evidence for historical climatology and the study of the impact of meteorological and hydrological extremes on human activities are discussed.  相似文献   

模糊理论在公路边坡稳定性分析中的应用   总被引：7，自引：0，他引：7  

许江  李克钢 《中国地质灾害与防治学报》2006,17(2):61-64

边坡工程是一个复杂的系统工程。边坡的稳定与否直接关系到其防护工作的程度。因此,如何有效、合理地判断边坡的稳定性对整个工程的经济与社会效益极为重要。影响边坡稳定的因素众多,判断其稳定与否应考虑各因素的综合效果。论文运用模糊理论中的多因素综合评判模型对某高速公路边坡的稳定性进行研究。通过全面考虑影响因素,建立相应的评判因素集及单因素评判矩阵,运用专家评判法和判断矩阵法确定出各因素的权重。最后通过多层次模糊评判得到该边坡的稳定性评判结果。研究证明,该法在边坡稳定性分析评判中是切实可行的。  相似文献