The enrichment characteristics of mercury in the sediments of Dongjiu and Xijiu, Taihu lake catchment, in the past century   总被引：7，自引：0，他引：7  

YanHong Wu  XueZhong Jiang  EnFeng Liu  ShuChun Yao  YuXin Zhu  ZhaoBin Sun 《中国科学D辑(英文版)》2008,51(6):848-854

The concentration and the enrichment factors of mercury (Hg) in the sediment cores of Dongjiu and Xijiu, Taihu Lake catchment, were studied. The accumulation fluxes, anthropogenic input concentration and anthropogenic accumulation fluxes of Hg in recent 100 years were also analyzed based on the 210Pb dating. The results indicate that the increasing concentrations of Hg in the sediments are influ-enced by natural factors and anthropogenic input simultaneously. Generally, about 2/3 of the Hg in the sediment was from anthropogenic sources. In the early 20th century, the anthropogenic input was owing to the urban development and fossil fuel consumptions surrounding the Taihu Lake and the worldwide atmospheric deposition of Hg since the industrial revolution. The concentration and an-thropogenic fluxes of Hg increased with the industrial development in the catchment since the 1930s. It reached the maximum during the middle 1970s and middle 1990s, and decreased since the middle 1990s with constraints on high pollution industries.  相似文献   

土壤样品中痕量价态金石墨炉原子吸收光谱法的测定及分离方法实验研究     

赵学沛  王明军  沙艳梅  袁波  焦万里 《岩石矿物学杂志》2019,38(3):424-430

在前人研究泡塑吸附金分离的基础上,用聚氨酯泡沫塑料吸附,利用石墨炉原子吸收法测定了痕量价态金的含量,探讨了溶矿介质、解脱时间、吸附温度、Fe~(3+)加入量等对测定结果的影响,确定了最佳测定条件,详细讨论了Fe~(3+)在溶矿和吸附过程中的作用,并将该方法用于土壤中痕量价态金的测定。方法检出限为0. 01 ng/g,测定范围为0. 03～300 ng/g,价态金回收率分别是Au~(3+)97. 3%、Au~+95. 8%、Au098. 9%,价态金分离精密度(RSD,n=12)为7. 3%～18. 8%。用石墨炉原子吸收光谱法测定价态金,不但有效地抑制了共存元素的干扰,而且能降低检出限,提高灵敏度和准确度,自动化进样减少了劳动强度,提高了分析测试效率,适合大批量样品的测试。  相似文献   

Geological Factors Controlling the Accumulation and High Yield of Marine-Facies Shale Gas: Case Study of the Wufeng-Longmaxi Formation in the Dingshan Area of Southeast Sichuan,China     

FAN Cunhui  ZHONG Cheng  ZHANG Yu  QIN Qirong  HE Shun 《《地质学报》英文版》2019,93(3):536-560

The main geological factors controlling the accumulation and yield of marine-facies shale gas reservoirs are the focus of the current shale gas exploration and development research. In this study, the Wufeng-Longmaxi Formation in the Dingshan area of southeast Sichuan was investigated. Shale cores underwent laboratory testing, which included the evaluation of total organic carbon(TOC), vitrinite reflectance(Ro), whole-rock X-ray diffraction(XRD), pore permeability,and imaging through field emission scanning electron microscopy(FE-SEM). Based on the results of natural gamma ray spectrum logging, conventional logging, imaging logging, and seismic coherence properties, the exploration and development potential of shale gas in the Dingshan area have been discussed comprehensively. The results showed that(1)layer No. 4(WF2-LM4) of the Wufeng-Longmaxi Formation has a Th/U ratio 2 and a Th/K ratio of 3.5–12. Graptolites and pyrite are relatively abundant in the shale core, indicating sub-high-energy and low-energy marine-facies anoxic reducing environments.(2) The organic matter is mainly I-type kerogen with a small amount of II1-type kerogen. There is a good correlation among TOC, Ro, gas content, and brittle minerals; the fracturing property(brittleness) is 57.3%. Organic and inorganic pores are moderately developed. A higher pressure coefficient is correlated with the increase in porosity and the decrease in permeability.(3) The DY1 well of the shale gas reservoir was affected by natural defects and important latestage double destructive effects, and it is poorly preserved. The DY2 well is located far from the Qiyueshan Fault. Large faults are absent, and upward fractures in the Longmaxi Formation are poorly developed. The well is affected by low tectonic deformation intensity, and it is well preserved.(4) The Dingshan area is located at the junction of the two sedimentary centers of Jiaoshiba and Changning. The thickness of the high-quality shale interval(WF2-LM4) is relatively small, which may be an important reason for the unstable production of shale gas thus far. Based on the systematic analysis of the geological factors controlling high-yield shale gas enrichment in the Dingshan area, and the comparative analysis with the surrounding typical exploration areas, the geological understanding of marine shale gas enrichment in southern China has been improved. Therefore, this study can provide a useful reference for shale gas exploration and further development.  相似文献   

西南典型矿业城市土壤及近地表大气尘中重金属污染特征及评价——以攀枝花市为例     

刘睿  黄艺  王丽  李祥  赵浩任 《矿物岩石》2019,39(3):111-119

以攀枝花市为研究区域,分别采用富集因子法、潜在生态危害系数法和单因子指数-内梅罗综合污染指数法有针对性地对土壤和近地表大气尘中As,Cd,Cr,Cu,V,Zn和Ni七种重金属污染状况进行了综合性评价。结果表明,攀枝花宝鼎煤矿区和攀钢片区土壤及近地表大气尘中的重金属含量较高,均超过四川省土壤背景值。富集因子指数分析表明,研究区重金属污染受到人为活动的影响较大,污染也较为严重,其中Zn和Cd的富集情况较为显著,Cd,V,Zn,Cu为主要污染因子。潜在生态危害系数结果表明,在各元素中,绝大多数元素处于轻微生态危害,Cd 8个点位处于强生态危害,7个点位处于很强生态危害,处于中等生态危害的占5%,处于强生态危害的占47%,处于很强生态危害的占41%,土壤中Cd元素的潜在生态危险最高,其余元素处于轻微生态危险状态。单因子指数-内梅罗综合污染指数分析结果表明,Cd,Cr和Ni元素在宝鼎煤矿区和攀钢片区都存在重度污染,Cd(7.70),Cr(3.38),Cu(4.49),V(3.62),Zn(3.68)和Ni(5.80)存在重度污染,As(2.07)存在中度污染。  相似文献   

西安白鹿塬黄土渗透性与含水条件   总被引：6，自引：0，他引：6  

赵景波  邵天杰  牛俊杰 《地理研究》2009,28(5):1188-1196

为查明黄土与古土壤入渗特征和地下水富集条件,对西安白鹿塬中更新世黄土与古土壤进行了10个层位30余个实验点的入渗实验、孔隙度、磁化率与CaCO₃含量的测定。结果表明,黄土层含水空间发育好,入渗率较大,利于构成含水层;黄土层与古土壤层入渗率与含水空间的差别主要是当时气候与成壤作用不同决定的。CaCO₃结核具有致密的结构,常常是非常好的隔水层。将任家坡剖面渗水实验数据用三种入渗公式分别进行拟合得出,经常采用的三个经验公式中考斯加可夫能普遍适用于描述50万年来发育的黄土和古土壤层的入渗规律,计算结果为水文和农业部门应用黄土入渗经验公式提供了重要参考值。本文的研究拓宽了第四纪气候变化理论应用的新领域,表明更新世气候变化在黄土地层土壤水和地下水资源富集条件、富集规律和水资源开发利用研究中有重要应用价值。  相似文献   

豫冀鲁不同级序旋扭构造体系和油气富集规律   总被引：1，自引：1，他引：0  

李红南  刘伟  蔡传强  刘泽蓉 《地质力学学报》2009,15(4):385-395

新华夏系第二沉降带华北沉降区受郯庐断裂中新生代应力方式及应力场的影响,广泛发育了不同级序旋扭构造体系,控制了不同级序复式油气聚集区带的形成分布。油气主要富集在内旋回层和撒开端,弧形断裂内侧和构造运动活跃期形成的低级序扭动构造中,对指导油气勘探开发有重要意义。   相似文献   

吉林省典型城市大气颗粒物主要排放源成分谱对比研究   总被引：3，自引：0，他引：3  

房春生  孟赫  田雷  钟宇红  王菊 《吉林大学学报(地球科学版)》2010,40(5):1149-1156

为建立吉林省典型城市大气颗粒物排放源源成分谱数据库,保障源解析结果的准确性,采用X射线荧光光谱分析技术对典型城市大气颗粒物主要排放源（道路尘、扬尘、建筑尘、土壤风沙尘、燃煤锅炉尘）的无机化学组分进行分析。结果表明：吉林市、白城市、通化市和四平市4个城市排放源成分谱组分含量虽有不同,但主量成分均为地壳组分;SiO₂含量在土壤风沙尘中最高,道路尘中最低,Ca含量在建筑尘中最高。元素富集因子分析表明：人类活动对道路尘元素Pb的富集贡献较大,主要来自汽车尾气排放;扬尘元素Pb、Zn、As有较高富集,具有道路尘、燃煤锅炉尘特征;建筑尘元素Ca富集显著;土壤风沙尘受人类活动影响较小,主要为自然源贡献;燃煤锅炉尘中元素As富集因子＞60,属极强扰动。  相似文献   

双硫腙改性氧化石墨烯/壳聚糖复合微球固相萃取在线富集-原子荧光光谱法测定地质样品中痕量汞     

周慧君  帅琴  黄云杰  汤志勇  曾梦 《岩矿测试》2017,36(5):474-480

汞可以指示矿床或矿化存在,是一种重要的地质过程示踪元素,因此汞的测定是十分重要的。由于汞在地质矿床中丰度较低,直接测定存在困难,需要进行预分离富集处理。目前采用的分离富集手段大多数是离线,自动化程度较低。本文将合成的双硫腙改性氧化石墨烯/壳聚糖复合微球制成固相萃取小柱,考察了溶液pH、吸附剂种类和体积对汞的吸附效果的影响,优化了固相萃取在线采样/洗脱时间和速率对汞的吸附/洗脱效果的影响,建立了固相萃取在线富集-原子荧光光谱法测定地质样品中痕量汞的分析方法。结果表明:溶液pH=3.0时,以5 mL/min的采样速率进样5 min,汞的吸附率大于90%;用20 g/L硫脲-1.0mol/L硝酸混合溶液作洗脱液,以1 mL/min的洗脱速度洗脱1 min,洗脱率大于95%。汞含量在0.050~5.0μg/L范围内线性关系良好,富集因子为22,检出限为0.0019μg/L。采用本方法测定了土壤和沉积物国家标准物质样品,Hg的测定值与参考值的相对误差小于±13%。与离线分析相比,本方法具有灵敏度高、操作简单快速等特点。  相似文献   

湖北渔塘坝硒矿床中次生自然硒的特征与意义   总被引：1，自引：0，他引：1  

刘家军  冯彩霞  李志明  王建平  刘世荣  周国富 《现代地质》2005,19(4):531-537

在湖北渔塘坝硒矿床氧化矿石及地表松散堆积物中存在大量罕见的次生自然硒。自然硒呈柱状、板状和它形粒状。它的形成一方面与硒矿石的风化作用有关,另一方面系当地居民用石煤烧石灰过程中导致硒的蒸发而发生次生富集的结果。矿床中大量次生自然硒的发现,不仅对硒的矿物学、矿床地球化学、环境地球化学研究具有重要价值,而且对解决或改进含碳硒矿石或岩石中硒的冶炼回收工艺流程具有一定的启迪意义。  相似文献   

西安市城市灰尘微量元素环境异常研究   总被引：7，自引：0，他引：7  

田晖  杜佩轩  梅琳 《地质力学学报》2005,11(4):361-369

通过对西安市城市灰尘中部分微量元素背景值和富集程度的研究,圈定了环境异常区.对各异常区元素特点进行分析,指出异常区城市灰尘中主要污染元素为Hg、Ag、Sb、Zn,其余元素在不同异常地段也有不同程度的富集.在此基础上,分别对不同异常地段中微量元素的分布状况作了评价.   相似文献