一氧化氮和过氧化氢对万寿菊不定根形成的影响   总被引：1，自引：0，他引：1  

张美玲  廖伟彪  肖洪浪 《中国沙漠》2012,32(1):105-111

以万寿菊（Tagetes erecta L.）为试材,研究了一氧化氮（NO）和过氧化氢（H2O2）对植物不定根形成中的影响及其相互关系。结果表明,外源NO供体肖普纳（SNP）和H2O2可显著地促进万寿菊外植体不定根的形成,且呈现明显的剂量效应,最适的SNP和H2O2浓度分别为50 μM和200 μM。NO和H2O2共同处理的万寿菊不定根的数量和根长显著高于NO或H2O2单独处理。NO在H2O2诱导万寿菊不定根形成的信号途径中起了重要作用;同时,H2O2包含在NO诱导不定根形成途径中。NO引起万寿菊外植体内源H2O2含量增加,H2O2亦促进内源NO积累。可见,NO和H2O2在万寿菊不定根形成过程中具有协同诱导效应,两者在促进不定根形成过程中可能通过互作反应提高各自的信号水平。  相似文献   

亮绿SF-过氧化氢体系催化动力学光度法测定痕量钒     

陈宗保  谢建鹰 《岩矿测试》2009,28(4):397-398

在硫酸介质中,痕量钒(Ⅴ)能明显催化过氧化氢氧化亮绿SF褪色,通过研究该反应的最佳实验条件和动力学参数,建立了测定痕量钒的新催化动力学光度法。该方法选择性强、操作简便、快速,其线性范围为0.0~40ng/mL,检出限为5.2ng/L。方法用于水样及茶叶中痕量钒(Ⅴ)的测定,结果满意。  相似文献   

过氧化钠碱熔-电感耦合等离子体质谱法测定原生矿石中的锡   总被引：2，自引：2，他引：0  

雷占昌  韩斯琴图  蒋常菊  梁慧贞 《岩矿测试》2019,38(3):326-332

原生锡矿石主要存在的矿床类型有矽卡岩型锡矿、斑岩型锡矿、锡石硅酸盐脉型锡矿、锡石硫化物脉型锡矿、石英脉及云英岩型锡矿。锡矿石一般不溶于盐酸、硝酸及王水体系,采用硫酸、氢氟酸处理时无法全部溶解。苯芴铜分光光度法和碘量法等传统测试方法存在受样品中伴生元素干扰大、稳定性差、检出限高、分析效率低等不足。本文建立了电感耦合等离子体质谱法测定原生矿石中锡元素含量的分析方法,用过氧化钠对样品进行熔融分解处理,热水浸取后用酒石酸-盐酸酸化,采用铑作为内标进行仪器信号漂移校正,同时用高倍稀释的方式来克服基体干扰。方法检出限为0.1μg/g,精密度小于5%,最低检出浓度为0.4μg/g,测试范围为12.5～12700μg/g。本方法操作简便,分析速度和数据质量都优于传统分析方法。  相似文献   

Comparison of the Concentrations of Chemical Components in Cloudwater Samples Collected during Four Different Field Campaigns     

F. Deutsch  P. Hoffmann  H. M. Ortner 《Journal of Atmospheric Chemistry》2001,40(3):295-304

In this study, the results of four different field experiments concerning the speciation of iron and the concentrations of some other chemical compounds in cloudwater samples are compared to one-another. Hydrogen peroxide concentrations were higher during campaigns, conducted at sites not much influenced by anthropogenic emissions as compared to those conducted at more polluted areas. In contrast, percentages of S(IV) in the cloudwater were lowest at the rural sites and highest at the sites polluted by human activities, indicating a consumption of hydrogen peroxide in the oxidation reaction with S(IV). The concentration of dissolved iron was observed to correlate with the percentage of S(IV), which may be an essential point for the reductive dissolution of oxidic iron compounds of the aerosol particles. As far as the speciation of the dissolved iron is concerned, it became obvious that the percentage of Fe(III) is anticorrelated to the concentration of dissolved iron. This clearly shows the important effect of the chemical and/or photo reductive ways of dissolving the iron(III)-compounds from the aerosol particles. However, a correlation between the pH-value and hydrogen peroxide was observed.  相似文献   

Hydrogen peroxide measurements in the marine atmosphere     

P. Jacob  D. Klockow 《Journal of Atmospheric Chemistry》1992,15(3-4):353-360

Hydrogen peroxide, one of the key compounds in multiphase atmospheric chemistry, was measured on an Atlantic cruise (ANT VII/1) of the German research vessel Polarstern from 15 September to 9 October 1988, in rain and ambient air by a chemiluminescence technique. For gas phase H₂O₂ cryogenic sampling was employed. The presented results show an increase of gas-phase mixing ratios of about 45 pptv per degree latitude between 50° N and 0°, and a maximum of 3.5 ppbv around the equator. Generally higher mixing ratios were observed in the Southern Hemisphere, with a clear diurnal variation. The H₂O₂ mixing ratio is correlated to the UV radiation intensity and to the temperature difference between air and ocean surface water.  相似文献   

硫化物氧化过程中金的富集实验研究   总被引：1，自引：0，他引：1  

张海祥  王玉荣  阚小风 《矿床地质》1999,18(3):285-290

室温条例上将海绵金用王水溶解形成金氯酸溶液,再用纯净的不含金黄铁矿吸附溶液中的金,粉干后用过氧化氢溶液将其分解,发现溶液中出现粒状、片状及壳皮状金。对溶液中金和铁的含量测定结果表明,随着黄铁矿的分解溶液中铁含量增加,金含量也随之增加,但当溶注保出现小金粒或金片后,溶液中的金含量急剧下降,并保持相对稳定。  相似文献   

Concentration of Peroxides and Formaldehyde in Air and Rain and Gas-Rain Partitioning     

O. Largiuni  M. C. Giacomelli  G. Piccardi 《Journal of Atmospheric Chemistry》2002,41(1):1-20

Rain and air of Florence have been collected in a continuous way andanalysed by flow analysis spectrofluorimetric methods for formaldehydeand hydrogen peroxide. Diurnal and seasonal variations were observed;the mean/maximum concentrations of all data (as gm^–3) are 3.3/23.4 for HCHO and 0.4/4.93 forH₂O₂. The effect of external sources and ofphotochemical reactions produces periods of positive and negativecorrelations for these compounds. The mean/maximum rain concentration ofall data are 98/443 g l^–1 for HCHO and 84/685 g l^–1 for H₂O₂. Concentrationratios rain/air and discrepancies to Henry's Law equilibrium arediscussed.  相似文献   

以苄基三乙基氯化铵为增敏剂催化光度法测定痕量铁     

赵仑  王晓菊  郭锦泉  高红伟 《岩矿测试》2006,25(4):345-347

在增敏剂苄基三乙基氯化铵存在下,Fe(Ⅲ)对H2O2氧化溴甲酚绿具有催化作用,据此建立了一种测定痕量Fe(Ⅲ)的新方法。考察该反应的最佳条件,测定反应动力学参数。催化反应的表观活化能Ea为61.14 kJ/mol。方法的检出限为2.8×10-8g/L,线性范围0~600μg/L。用于河水、自来水等样品中铁的测定结果满意,相对标准偏差(RSD,n=6)小于5%。  相似文献   

Subsurface formation of oxidants on Mars and implications for the preservation of organic biosignatures     

Alfonso F. Davila  Alberto G. Fairn  Luis Gago-Duport  Carol Stoker  Ricardo Amils  Rosalba Bonaccorsi  Jhony Zavaleta  Darlene Lim  Dirk Schulze-Makuch  Christopher P. McKay 《Earth and Planetary Science Letters》2008,272(1-2):456-463

Hydrogen peroxide can form through the interaction of pyrite and anoxic water. The oxidation of pyrite results in the precipitation of sulfates and iron oxides, high redox potentials (~ 1000 mV) and acidic pH (3–4). The oxidative potential of the resultant solution may be responsible for the oxidation of organic compounds, as observed in the subsurface of the Rio Tinto Mars analog. On Mars subsurface migration of groundwater interacting with volcanogenic massive pyrite deposits would have mobilized acidic and oxidizing fluids through large portions of the crust, resulting in the widespread deposition of sulfates and iron oxides. This groundwater could have leached substantial volumes of aquifer material and crustal rocks, thereby erasing any organic compounds possibly down to depths of hundreds of meters. Therefore, the preservation of organic biosignatures must have been severely constrained in the portions of the ancient Martian crust that were exposed to aqueous processes, calling for a redefinition of the future targets in the search for biomolecular traces of life on Mars.  相似文献   

一种新的褐藻胶寡糖制备方法--氧化降解法   总被引：8，自引：0，他引：8  

杨钊  LiJin-ping  张真庆  管华诗 《海洋科学》2004,28(7):19-22

建立了一种新的褐藻胶寡糖的制备方法,即氧化降解法。通过褐藻胶来源的聚甘露糖醛酸(PM)在不同浓度的过氧化氢、不同温度和不同反应时间下降解优选降解条件。以包含3～11糖单体的寡糖混合物为目标产物,以相应的降解产物的平均分子质量为1500u为选择标准,获得氧化降解法的最佳条件：过氧化氢浓度5％,反应温度90℃,降解时间2h。以该条件降解PM获得的降解产物经圆二色谱、紫外光谱及红外光谱测定表明,制备的寡糖保持了甘露糖醛酸的结构特点。提示该方法可用于褐藻胶寡糖的制备。  相似文献