量子化学方法研究氯代苯酚类化合物对水生物毒性的构效关系     

许旋  罗一帆  李华祥 《广东海洋大学学报》1992,(2)

对20个氯代苯酚类化合物进行了CNDO/2量子化学计算,讨论了化合物电子结构与其对水生物翻车鱼(Bluegill)、花鳉鱼(Guppy)、和虾(Shrimp)半致死量之间的关系,分别获得了表示其构效关系的三个线性方程,它们的显著性均远高于α=0.01水平。结果表明:氯代苯酚化合物苯环上碳原子的兀电荷之和(∑Qπ_R)越大苯环上碳原子的净电荷之和(∑Q_R)越大,或LUMO轨道能(E_(LUMO))越低,均使化合物对Bluegill和Guppy水生物的毒性增大;而化合物苯环上羟基邻位的碳原子的兀电荷布居(P_3)越大,同时HOMO轨道能E_(HOMO)越高,则化合物对Shrimp毒性也越大。据此,可预测氯代苯酚类化合物对上述三种水生物的毒性。  相似文献   

重力插值方法研究     

向文 《大地测量与地球动力学》1997,(2)

为了根据离散观测数据构制连续空间重力变化图像，分析和讨论了３种数值插值方法，计算结果表明多面函数方法插值精度最高。由于逐步回归分析筛选核函数中心点的计算繁琐，文中提出根据分形理论和Ｓｈａｎｎｏｎ取样定理来确定核函数中心点。对滇西试验场进行模拟试算，插值精度可达到４～５（１０－８ｍｓ－２）。  相似文献   

PROPAGATION OF 30—60 DAY LOW FREQUENCY OSCILLATIONS AND THEIR INFLUENCE UPON THE SUBTROPICAL WESTERLIES JET STREAM DURING NORTHERN HEMISPHERE WINTER          下载免费PDF全文

史玉光  李清泉 《Acta Meteorologica Sinica》1996,(2)

Based on daily ECMWF gridpoint data of two winters during 1981—1983 including an ENSOyear,propagation of low frequency oscillations(LFO)during Northern Hemisphere winters andtheir influences upon 30—60 day oscillations of the subtropical jet stream are studied with the sta-tistical methods as complex empirical orthogonal function(CEOF)and so on.Results show that inthe winter of a normal year(1981—1982),30—60 day oscillations in the subtropical zone aremainly in the northern and southern flanks of exit region of jet stream.In the ENSO year(1982—1983),they are mainly in the vicinity of entrance and exit regions of jet stream.Intraseasonalchanges of subtropical jet stream manifested themselves as latitudinal fluctuation or longitudinalprogression or regression of about 40 day period.There are marked differences between propagat-ing passages of low frequency modes responsible for changes of subtropical jet stream in the normalyear(1981—1982)and in the ENSO year(1982—1983).Changes of oscillation amplitude showobvious phases.In general,the one in late winter is stronger than that in early winter,strongestone occurs in February.  相似文献   

Numerical calculations in the orbital determination of an artificial satellite for a long arc     

Lin Liu  Xinhao Liao 《Celestial Mechanics and Dynamical Astronomy》1994,59(3):221-235

Numerical methods are usually used for the computation of ephemerides with perturbations for the precise orbital determination of an artificial satellite. But their numerical stability will be encountered in a long arc. In this case the use the improved Encke special perturbation methods has been suggested. The results of this paper show that Encke's method does indeed have a certain effectiveness, but cannot yet completely resolve the numerical stability, and the more efficient method is to use the energy integral or its variational relation to control the growth of the along-track error in general numerical calculations so that the aim of stabilization can be achieved.  相似文献   

Particle-mesh simulations of the Lyα forest     

Avery Meiksin  Martin White 《Monthly notices of the Royal Astronomical Society》2001,324(1):141-148

We have analysed short-exposure high-resolution images obtained on the William Herschel Telescope (WHT), Big Telescope Azimuthal (BTA) and CanadaFranceHawaii Telescope (CFHT) in order to investigate mechanical vibrations that are capable of reducing the high angular resolution allowed by speckle-interferometric methods. After filtering the photon noise we have computed power spectra of the image centres of gravity. In these spectra we have found vibration features that differ from one telescope to another and that vary in particular with the zenith angle. In the case of the WHT we discuss these results in terms of possible causes and in terms of degradation of the transfer function. We present some means to improve the data.  相似文献   

雅砻江流域主汛期降水长期预报的一种方法     

赵守尧 《成都信息工程学院学报》1994,(1)

本文使用天气学方法，从影响雅砻江区域主汛期降水量的长期预报有关因子出发，再运用数理统计方法反复筛选，仅取３个主要因子：西部青藏高原８个站冬春积温，北部冬季极涡面积指数，南部冬季印缅槽平均强度，建立逐步回归预报方程。结果显示：对主汛期６～９月降水量预报拟合准确率为１６／１７即约９４％。回归分析中发现：尽管西太平洋副热带高压对盆地西部降水有很大影响，盛夏且与高原积温有较密切相关，但由放大范围长时段的青藏高原积温，对于雅砻江区域主汛期降水量的影响超过西太平洋副热高压，因而在逐步回归过程中，副高因子仍被剔除．  相似文献   

Urban tourism research methodology     

Tao Wei  Zhong Wen-hui  Hong Yan 《中国地理科学(英文版)》2005,15(2):173-178

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Systematic uncertainties in the analysis of star cluster parameters based on broad-band imaging observations     

R. de Grijs  P. Anders  H. J. G. L. M. Lamers  N. Bastian  U. Fritze-v. Alvensleben  G. Parmentier †  M. E. Sharina  S. Yi 《Monthly notices of the Royal Astronomical Society》2005,359(3):874-894

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A note on turbulent perturbations of salinity in a partially mixed estuary     

J.R. West  K. Shiono 《Estuarine, Coastal and Shelf Science》1985,20(1):55-78

Measurements of salinity perturbations in a partially mixed estuary have been used to evaluate the usefulness of an inductive salinometer and to determine some of the characteristics of the salinity perturbations. The salinometer performed satisfactorily under most conditions. Although internal wave like effects were present, the turbulence fluctuations were dominant. The salinity fluctuations and the turbulent fluxes $\text{sw}$ and $\text{su}$ were found to behave in a manner similar to the density fluctuations in a thermally stratified atmospheric boundary layer and a laboratory open channel flow. A quadrant analysis suggested that the contribution of each quadrant to the turbulent flux changed with Ri. The turbulence parameters ν and c_γ were found to decrease and increase respectively as Ri increases.  相似文献   

太阳活动区磁场观测的一种新方法     

崔连竖  季国平  方成 《中国天文和天体物理学报》1986,(3)

在太阳活动区的物理研究中,特别是在二维动力学光谱分析中,迫切需要相应活动区的磁图资料。本文介绍了在太阳光谱仪的入射狭缝后安装一种新型偏振器进行活动区二维磁场观测的新方法。这种方法不仅能获得日面上任一点的磁场强度,且可快速获得活动区的纵向场磁图。除此之外,还可利用多条谱线的同时观测,获得有关磁力线管结构等方面的资料。  相似文献