盐酸羟胺-盐酸体系提取黄土中游离氧化铁     

孙玉兵  谢巧勤  陈天虎 《海洋地质与第四纪地质》2007,27(3):133-136

黄土中游离氧化铁是指示夏季风的替代性气候指标之一。使用经典的CBD法提取游离氧化铁实验过程烦琐,而且实验条件不同对浸提结果影响很大。本实验采用盐酸羟胺-盐酸体系在不同的温度下浸提黄土中的游离氧化铁。实验结果表明:温度对实验结果影响最大,盐酸浓度次之。与经典的CBD法进行对比,在一定的条件下可以代替CBD法,从而简化试验。  相似文献   

南黄海陆架中部沉积物反射率光谱的影响因素分析     

王昆山  石学法  程振波  王国庆  葛淑兰 《海洋科学进展》2007,25(1):46-53

利用Minolta CM-2002光谱光度计对南黄海陆架136个短柱样品20~25cm段的沉积物进行了颜色反射率数据测量,通过化学元素、粒度、磁化率等来确定影响沉积物颜色反射率变化的成分和因素,介绍了反射率光谱的一阶导数和因子分析的方法。分析结果表明,南黄海陆架沉积物颜色反射率受控于沉积物中的铁氧化物、有机质以及粘土矿物和钙质生物碎屑含量。主因子F1指示氧化环境,并与陆源物质相关,F2指示弱氧化环境,F3指示弱还原环境,主因子的波长范围分别是405~445 nm和495~595 nm,605~695 nm,445~485 nm。  相似文献   

单体褶牡蛎(Crassostrea sp.)的研究     

王昭萍  王如才  徐从先  仇宝志  姜福正  张祝绪 《中国海洋大学学报(自然科学版)》1992,(2)

采用肾上腺素(EPI)和去甲肾上腺素(NE)诱导、颗粒固着基和先固着后脱基三种方法,对褶牡蛎的眼点幼虫进行处理,产生单体蛎苗。EPI和NE诱导的最适浓度为10~(-4)M,最适处理时间为3h,幼虫的不固着变态率分别达47.7％和46.6％。处理时间延长,变态率增加不明显。EPI和NE的诱导效果差别不明显,其诱导作用对稚贝的生长无明显副作用。颗粒固着基以贝壳粉为佳,最适颗粒的规格为幼虫的壳长。幼虫先固着后脱基而形成单体蛎苗,以可弯曲的灰色塑料板效果最好,固着的小贝可通过来回弯曲塑料板而从上面脱落下来,小贝长至1～2cm大小时,脱基最容易。  相似文献   

氧化锰矿物的生物成因及其性质的研究进展   总被引：5，自引：0，他引：5  

刘凡  冯雄汉  陈秀华  邱国红  谭文峰  贺纪正 《地学前缘》2008,15(6):66

土壤中的氧化锰矿物是原生矿物风化和成土过程的产物,是最具反应活性的一类矿物,决定着环境中许多物质的形态、迁移和转化,在元素生物地球化学循环中起着重要的作用,其形成机制和环境效应备受关注。已有的研究表明,环境中氧化锰的形成与微生物作用紧密相关,微生物作用可使自然环境中的Mn(Ⅱ)氧化速率提高105倍。参与Mn(Ⅱ)氧化的微生物在环境中广泛存在,已知的典型锰氧化细菌分布在变形菌门、放线菌门或厚壁菌门,它们均通过胞外聚合物中的多铜氧化酶来催化氧化Mn(Ⅱ)。细菌氧化Mn(II)成Mn(Ⅳ)是酶催化的两个连续的快速单电子传递过程,Mn(Ⅲ)在溶液中以与酶结合的瞬时中间态出现。生物形成氧化锰的最初形态为层状锰矿物,与δ-MnO2或酸性水钠锰矿很类似,且结晶弱,粒径小,锰氧化度高,结构中的八面体空穴多,因而比化学形成的氧化锰具有更强的吸附、氧化等表面活性。环境中Mn(Ⅱ)微生物氧化及形成的Mn(Ⅲ)中间体与碳、氮、硫等生命元素的地球化学循环的关系令人关注。  相似文献   

Laboratory study of the rates and products of the phototransformations of naphthalene adsorbed on samples of titanium dioxide,ferric oxide,muscovite, and fly ash     

Chantal Guillard  Hervé Delprat  Can Hoang-van  Pierre Pichat 《Journal of Atmospheric Chemistry》1993,16(1):47-59

The photodegradation of naphthalene (NPH), chosen as a model of polynuclear aromatic pollutants, has been studied in the presence of a layer of four water-insoluble inorganic solids which can be found in the troposphere (TiO₂, Fe₂O₃, muscovite, and a fly ash sample). Direct photolysis of NPH is negligible at >340 nm. Dark adsorption of NPH on TiO₂ (mainly anatase, nonporous, 50 m² g^–1) at 293 K corresponds to a surface coverage ofca. 50% at equilibrium. Under these conditions (saturated surface), the stationary-state photocatalytic degradation reaches 0.4 molecule nm^–2 h^–1 (>340 nm, radiant fluxca. 22 mW cm^–2). Dioxygen is required and its partial pressure in air is such that the degradation is zero order in O₂. Water vapor markedly increases the rate. The other particulates have also an effect, less important than that of TiO₂, however quite noticeable with respect to surface area unit for the fly ash sample which contains 3.2% Fe₂O₃. Apart from 1,4-naphthoquinone, which is the main intermediate product in all cases, 2-naphthol, phthalide, phthaldialdehyde, phthalic acid, acetophenone, benzaldehyde, benzoic acid are also formed on dry TiO₂. Depending on their volatility, these compounds are transferred to the gas phase or remain principally adsorbed on the solid particles where they are further transformed. For instance, phthalic acid (or anhydride) and benzoic acid are generated from 1,4-naphthoquinone. Degradation mechanisms are briefly discussed.  相似文献   

Kinetics of redox cycling of iron coupled with fulvic acid     

Yiwei Deng  Werner Stumm 《Aquatic Sciences - Research Across Boundaries》1993,55(2):103-111

The kinetics of conversion of iron(III) (hydr)oxides to ferrous iron mediated by fulvic acid have been investigated in order to improve the understanding of the redox cycling of iron at the oxic-anoxic boundary in natural waters. Under the conditions similar to natural waters, fulvic acid is able to reduce the iron(III) (hydr)oxide. The kinetics of the reaction depend on the reactivity of iron(III) (hydr)oxides and the reducing power of the fulvic acid. The rate of reaction is 60 nm/h obtained under following conditions: total concentration of Fe(III) 1.0 × 10^–4 M, pH 7.5, fulvic acid 5 mg/L. The rate is considered as a net result of reduction and oxidation in the > Fe^III-OH/Fe(II) wheel coupled with fulvic acid. In a real natural water system, reductants other than fulvic acid may be of importance. The results obtained in the laboratory, however, provide evidence that the Fe(OH)₃(s)/Fe(II) redox couple is able to act as an electron-transfer mediator for the oxidation of natural organic substances, such as fulvic acid by molecular oxygen either in the absence of microorganisms or as a supplement to microbial activity.  相似文献   

钾霞石制备体系碱性滤液的利用技术     

路华龙  霍光祥  段永华  勾明雷  刘军娜  刘晨 《岩石矿物学杂志》2024,43(1):125-130

为处理钾长石水热制备钾霞石所产生的碱性滤液,本文采用水热法,考察了氢氧化铝溶解时间、晶化时间、晶化温度、水碱比对钾霞石产率和白度的影响,并对合成钾霞石物相进行了表征。结果表明,合成钾霞石的最佳条件为,氢氧化铝溶解时间为1.5 h,晶化时间为4 h,晶化温度280℃,水碱比为1.8。XRD结果表明,产物为钾霞石粉体。傅里叶变换红外光谱表明,Al(OH)₃中的Al在水热条件下进入到Si—O骨架中形成了Si—O—Al官能团,从而印证了钾霞石的合成。差热分析结果表明,合成钾霞石具有良好的热稳定性。氮气吸附结果表明,合成钾霞石比表面积为5.18 m²/g,平均孔径为32.98 nm。实现了钾长石水热制备钾霞石所剩碱性滤液的资源化利用,并为钾长石水热制备钾霞石提供了一种母液循环的思路,使水热制备钾霞石工业化成为一种可能。  相似文献   

塔里木克拉通东北缘二叠纪镁铁质岩浆氧化物与硫化物成矿条件对比     

徐文博  张铭杰  包亚文  满毅  李思奥  王鹏 《地质学报》2022,96(12):4257-4274

塔里木克拉通东北缘坡北、磁海等地二叠纪幔源岩浆活动形成了镍钴硫化物矿床和铁钴氧化物矿床，两者赋矿镁铁 超镁铁岩体的年龄相近(290~260 Ma)，主、微量元素和Sr Nd Hf同位素组成相似，分配系数接近的微量元素比值分布于相同趋势线，揭示两者岩浆源区相同，可能为俯冲板片流体交代的亏损地幔或软流圈地幔。两类矿床镁铁 超镁铁质岩中Co与Ni含量正相关，Co主要富集在基性程度高的岩石中；块状硫化物与磁铁矿矿石中Co与Ni相关性差，Co和Ni具有不同的富集机制，Co热液富集作用明显。北山镁铁 超镁铁杂岩体是地幔柱相关软流圈上涌，诱发俯冲板片交代的亏损岩石圈地幔发生部分熔融，形成的高镁母岩浆演化过程中经历壳源混染、硫化物饱和富集镍钴形成铜镍钴硫化物矿床，富铁母岩浆氧逸度高、富水，岩浆分离结晶磁铁矿、叠加热液作用富集钴，形成铁钴氧化物矿床。  相似文献   

A multivariate statistical and geostatistical study on the geochemistry of allochtonous karst bauxite deposits in Hungary     

Bárdossy  George  Kovács  Ó. 《Natural Resources Research》1995,4(2):138-153

A geochemical evaluation of the Szc-Halimba-Kisld area, Hungary, covering an area of more than 200 km² is presented using different statistical and geostatistical methods. The study area is a representative example of allochtonous karst bauxite accumulation. The three groups of deposits studied here have been explored and mined since 1950. Several thousand boreholes have been drilled, and bauxite cores were analyzed for the five main chemical components. A total of 80,000 pleces of analytical data were processed, followed by a geological examination of borehole logs and of mining excavations.The quantitative geochemical evaluation of the data set led to both geochemical and practical results: The geochemical behavior of the allochtonous, clastic karst bauxite deposits differs essentially from that of the autochtonous and parautochtonous ones, as well as that of the lateritic bauxite deposits. The deposits of the study area can be split into several subsequent geochemical-sedimentological units, each representing an event of bauxite transport and accumulation. Clear regional patterns can be revealed in the composition of these units. The geostatistically measured chemical variability of the geochemical units is rather different, the lowest units showing the smallest variability. The interrelations of the main chemical components are weaker and more irregular in the studied deposits than in the autochtonous lateritic bauxite deposits. Additional local genetic features, such as transport routes, can be delineated by the methods applied. Within each deposit, local changes of chemical composition and of its variability can be determined more precisely. These results can be used in bauxite prospecting and exploration, because areas of high or low bauxite quality can be predicted.  相似文献   

Speciation of adsorbed arsenate on the surface of hydrous iron oxide     

Yongfeng JIA Xin WANG George Demopoulos 《中国地球化学学报》2006,25(B08):35-35

Adsorption of arsenate on hydrous iron oxide is an important process controlling geochemical cycling of arsenic in environment as well as the fate of arsenic-bearing mining wastes. The widely accepted view on the mechanism of adsorption is that arsenate is adsorbed via bidentate binuclear inner-sphere complexation. In this study, we characterized the arsenate-hydrous iron oxide sorption solids synthesized at pH=3-8 using Fourier transformed infrared spectroscopy （FTIR） and X-ray diffraction （XRD）. It has been determined that poorly crystalline ferric arsenate developed on the surface of iron oxide when arsenate was sorbed at acidic pH, while at alkaline pH the adsorption of arsenate was via bidentate complexation.  相似文献