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931.
The impacts of plastic debris on the marine environment have gained the attention of the global community. Although the plastic debris problem presents in the oceans, the failure to control land-based plastic waste is the primary cause of these marine environmental impacts. Plastics in the ocean are mainly a land policy issue, yet the regulation of marine plastic debris from land-based sources is a substantial gap within the international policy framework. Regulating different plastics at the final product level is difficult to implement. Instead, the Montreal Protocol may serve as a model to protect the global ocean common, by reducing the production of virgin material within the plastics industry and by regulating both the polymers and chemical additives as controlled substances at a global level. Similar to the Montreal Protocol, national production and consumption of this virgin content can be calculated, providing an opportunity for the introduction of phased targets to reduce and eliminate the agreed substances to be controlled. The international trade of feedstock materials that do not meet the agreed minimum standards can be restricted. The aim of such an agreement would be to encourage private investment in the collection, sorting and recycling of post-consumer material for reuse as feedstock, thereby contributing to the circular economy. The proposed model is not without its challenges, particularly when calculating costs and benefits, but is worthy of further consideration by the international community in the face of the global threats posed to the ocean by plastics.  相似文献   
932.
Multi-biomarker indexes were analyzed for two piston cores from potential cold seep areas of the South China Sea off southwestern Taiwan. Total organic carbon(TOC) normalized terrestrial(n-alkanes) and marine(brassicasterol, dinosterol, alkenones and iso-GDGTs) biomarker contents and ratios(TMBR, 1/Pmar-aq, BIT) were used to evaluate the contributions of terrestrial and marine organic matter(TOM and MOM respectively) to the sedimentary organic matter, indicating that MOM dominated the organic sources in Core MD052911 and the sedimentary organic matter in Core ORI-_(86)0-22 was mainly derived from terrestrial inputs, and different morphologies were the likely reason for TOM percentage differences. BIT results suggested that river-transported terrestrial soil organic matter was not a major source of TOM of sedimentary organic matter around these settings.Diagnostic biomarkers for methane-oxidizing archaea(MOA) were only detected in one sample at 172 cm depth of Core ORI-_(86)0-22, with abnormally high iso-GDGTs content and Methane Index(MI) value(0.94). These results indicated high anaerobic oxidation of methane(AOM) activities at or around 172 cm in Core ORI-_(86)0-22.However in Core MD052911, MOA biomarkers were not detected and MI values were lower(0.19–0.38), indicated insignificant contributions of iso-GDGTs from methanotrophic archaea and the absence of significant AOM activities. Biomarker results thus indicated that the discontinuous upward methane seepage and insufficient methane flux could not induce high AOM activities in our sampling sites. In addition, the different patterns of TEX_(86) and U_(37)~(K′) temperature in two cores suggested that AOM activities affected TEX_(86)37 temperature estimates with lower values in Core ORI-_(86)0-22, but not significantly on TEX_(86) temperature estimates in Core MD052911.  相似文献   
933.
Here we characterized asphaltic oil occurrences in the Misoa C2 and C3 reservoirs within Area 2 South of the Ceuta Field (Lake Maracaibo Basin, NW Venezuela). To perform the geochemical and petrological characterization of the C2 and C3 sub-units, which cover an interval in which tar-like material was detected, we analyzed core (18) and cutting (123) samples using the Rock-Eval 6 technique in reservoir mode. Samples were studied under fluorescence light and scanning electron microscopy (SEM), showing the presence of two charges of oils and the relationships within silica cements and clay minerals. To evaluate vertical inter-reservoir communication and lateral intra-reservoir continuity, we also studied 12 oil samples from wells in Area 2 South. Biomarkers and isotopic signatures were examined using gas chromatography-mass spectrometry (GC-MS) and isotope ratio mass spectrometry (IRMS). The results suggest that oil and core extracts belongs to a single family derived from two pulses of hydrocarbon generation from the La Luna source rock, which was deposited in a marine reducing environment. The oil samples are a mixture of a paleobiodegraded oil charge and a later fresh, more mature oil recharge. The geochemical analyses also evidence that the formation of heavy oil tar zones can be related to biodegradation and in-reservoir oil mixing, though other formation mechanisms for the tar are also feasible. Finally, the GC fingerprints of the oils are indicative of lateral reservoir continuities across the F-1 and F-2 faults and vertical communication between the Misoa C2 and C3 sub-units in Area 2 South, suggesting that tar occurrences do not act as permeability barriers within the two reservoirs studied.  相似文献   
934.
运用多元统计方法识别浙北海域两个典型港湾的水质状况   总被引:1,自引:0,他引:1  
浙北海域两个典型港湾,杭州湾与象山港的水体污染状况日趋严重。本文运用多元统计方法,对分析了研究海域水体的物理及生物地球化学要素进行了量化分析。结果表明,根据物理及生物地球化学特性,层次聚类分析可将研究海域划分为两个不同的子区域;主成分分析分别在杭州湾和象山港识别出3个潜在的污染源,且陆源径流的输入、沿岸工业排污以及自然演化过程为主要源头。因此,研究海域的生态环境保护刻不容缓,应该立即采取相关措施。  相似文献   
935.
渤海及北黄海河流悬浮颗粒碳氮同位素时空分布及源解析   总被引:2,自引:0,他引:2  
于靖  张华 《海洋科学》2017,41(5):93-102
选择流入渤海和北黄海的36条主要河流为研究对象,对比了平水期、丰水期和枯水期水体中悬浮颗粒物和河流表层沉积物的碳和氮稳定同位素的地球化学特征,并对颗粒物有机质碳和氮来源进行分析。结果表明,水体悬浮有机质碳同位素总体上表现为δ13C平水期δ13C丰水期δ13C枯水期的特点,δ15N值呈δ15N丰水期δ15N平水期δ15N枯水期的特点。渤海和北黄海的主要入海河流悬浮颗粒物有机质的来源具有明显的季节性差异,悬浮颗粒有机质碳平水期(春秋季)来源以C3植物、土壤有机质和水生藻类为主,丰水期(夏季)碳的各来源中浮游植物的贡献率明显增大,枯水期(冬季)则表现为陆源C3植物分解和水源性有机质的混合来源;悬浮颗粒态氮的来源与季节性降水量、生活污水、合成化肥及河流内源性水生植物密切相关。  相似文献   
936.
甘肃石油河流域地下水补给来源与演化特征分析   总被引:1,自引:0,他引:1  
针对石油河流域所包含的赤金盆地与花海盆地,综合利用地下水水化学指标与稳定同位素技术系统地研究了地下水的补给来源与演化规律。其中赤金盆地地下水化学演化受控于溶滤作用,方解石、白云石、石膏等不断地溶解进入低矿化度的地下水中导致Mg2++Ca2+与HCO3-+SO42-沿1∶1等量线分布;而花海盆地高矿化度地下水中的Na+与SO42-、Na+与Cl-均有较好线性关系且多数矿物饱和指数>1,表明芒硝溶解控制了地下水中主要离子成分且地下水演化过程转由蒸发浓缩作用主导。赤金、花海盆地地下水氢氧同位素沿祁连山大气降水线分布或于右下方,二者特征相似,但后者更为富集重同位素,反映研究区地下水主要补给来源为祁连山大气降水或石油河河水;此外,两盆地间水力联系紧密,前者补给后者,因此在水资源开发利用时应将两盆地作为整体进行统筹管理,避免不合理开采造成环境地质问题。  相似文献   
937.
陶玲  曹田  吕莹  张文杰  任珺 《中国沙漠》2017,37(2):276-280
由于具有提高沙土的稳定性和保水性等特征,复合高吸水性固沙材料在荒漠化土地治理方面具有一定的潜力和应用前景。研究了蓝藻结皮在不同比例凹凸棒基高分子固沙材料中的生长状态和生理特性。结果表明:蓝藻结皮与经4 mol·L-1硫酸改性后的凹凸棒基高分子固沙材料以1∶3质量比配比生长情况最佳;比较了复配材料喷洒量为400、500g·m-2处理下蓝藻叶绿素a、丙二醛、可溶性蛋白及可溶性糖含量等生理指标,喷洒量为500 g·5m-2的蓝藻结皮与经4 mol·L-1硫酸改性后的凹凸棒基高分子固沙材料生理特性较好。  相似文献   
938.
Five new biotite reference materials were calibrated at the SwissSIMS laboratory (University of Lausanne) for oxygen isotope determination by secondary ion mass spectrometry (SIMS) and are available to the scientific community. The oxygen isotope composition of the biotites, UNIL_B1 to B5, was determined by laser‐heating fluorination to be 11.4 ± 0.11‰, 8.6 ± 0.15‰, 6.1 ± 0.04‰, 7.1 ± 0.05‰ and 7.6 ± 0.04‰, respectively. SIMS analyses on spots smaller than 20 μm gave a measurement repeatability of 0.3‰ (2 standard deviation, 2s). The matrix effect due to solid solution in natural biotite could be expressed as a linear function of XMg and XF for biotite. No effect was found for different crystallographic orientations. SIMS analysis allows the oxygen isotope composition of biotite to be measured with a measurement uncertainty of 0.3–0.4‰ (2s) for biotites with similar major element compositions. A measurement uncertainty of 0.5‰ (2s) is realistic when F poor biotites (lower than 0.2% m/m oxides) within the compositional range of XMg of 0.3–0.9 were compared from different sessions. The linear correlation with F content offers a reasonable working curve for F‐rich biotites, but additional reference materials are needed to confirm the model.  相似文献   
939.
A potential zircon reference material (BB zircon) for laser ablation‐inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS) U‐Pb geochronology and Hf isotope geochemistry is described. A batch of twenty zircon megacrysts (0.5–1.5 cm3) from Sri Lanka was studied. Within‐grain rare earth element (REE) compositions are largely homogeneous, albeit with some variation seen between fractured and homogeneous domains. Excluding fractured cathodoluminescence bright domains, the variation in U content for all analysed crystals ranged from 227 to 368 μg g?1 and the average Th/U ratios were between 0.20 and 0.47. The Hf isotope composition (0.56–0.84 g/100 g Hf) is homogeneous within and between the grains – mean 176Hf/177Hf of 0.281674 ± 0.000018 (2s). The calculated alpha dose of 0.59 × 1018 g?1 for a number of BB grains falls within the trend of previously studied, untreated zircon samples from Sri Lanka. Aliquots of the same crystal (analysed by ID‐TIMS in four different laboratories) gave consistent U‐Pb ages with excellent measurement reproducibility (0.1–0.4% RSD). Interlaboratory assessment (by LA‐ICP‐MS) from individual crystals returned results that are within uncertainty equivalent to the TIMS ages. Finally, we report on within‐ and between‐grain homogeneity of the oxygen isotope systematic of four BB crystals (13.16‰ VSMOW).  相似文献   
940.
以三门峡尖草地铝土矿床为对象,在研究矿床地质特征的基础上,分析了成矿物质来源、控矿因素,并刻画了成矿演化模式.三门峡尖草地铝土矿床赋矿层位为本溪组,是在沉积间断面、沉积古地理、古构造等多个条件的耦合作用下形成的.该地层后期抬升遭受剥蚀,再沉积形成局部堆积型的铝土矿床.其成矿演化模式在豫西地区具有典型找矿意义.  相似文献   
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