青藏高原北部活动层土壤热力特性的研究   总被引：3，自引：0，他引：3       下载免费PDF全文

李韧  赵林  丁永建  焦克勤  王银学  乔永平  杜二计  刘广岳  孙琳婵  肖瑶 《地球物理学报》2010,53(5):1060-1072

利用2003年10月～2004年9月期间高原北部可可西里(QT01)、北麓河(QT02)、开心岭(QT05)、通天河(QT06)等地活动层土壤温度梯度、土壤热通量及土壤水分的观测资料,计算了高原北部活动层土壤的导热率、土壤容积热容量、导温率等土壤热力参数.结果显示,QT02、QT05、QT06三站导热率、导温率夏秋季节较大而冬季较小,容积热容量则相反,表现为秋冬季节大而夏季较小;QT01站导热率表现为春季大,夏季较小;表层土壤粒度较小及较低的土壤湿度是冬季导热率较小的可能原因;冻土的热力特征参量可描述为相应深度的温度、体积含冰量及土壤盐度的函数,土壤含水量是融土热特征参数的主要影响因子;土壤水分含量小于某一临界值时,导温率随土壤水分含量的增大而增大,反之则减小.  相似文献   

非饱和土土-水特征曲线的温度效应   总被引：2，自引：1，他引：1  

蔡国庆  赵成刚  刘艳 《岩土力学》2010,31(4):1055-1060

基于热力学的理论,利用van Genuchten的土-水特征曲线表达式,建立了一种能考虑温度影响的土-水特征曲线方程,并给出了推导过程。该表达式综合考虑了温度对表面张力和浸润系数的影响。相对于根据试验数据拟合的表达式,该表达式具有更加坚实的理论基础,更具适用性和一般性。选用MX-80斑脱土和黄土土样的试验结果,将该方程预测结果和试验结果进行了比较;可以看到,所提出的方程能较好地反映非饱和土土-水特征曲线随温度而变化的情况。  相似文献   

Flow of a stratified fluid bounded by walls of finite thermal conductance     

Jae Min Hyun 《地球物理与天体物理流体动力学》2013,107(1-4):109-121

Abstract

A study is made of the behavior of a thermally stratified fluid in a container when the non-horizontal boundaries have finite thermal conductance. The theory of Rahm and Walin is briefly recounted. Numerical solutions to the Navier-Stokes equations for a Boussinesq fluid in a cylinder, adopting a Newtonian heat flux condition at the vertical sidewall, are presented. Results on the details of flow and temperature fields are given over ranges of the Rayleigh number Ra, the container aspect ratio H, and the sidewall conductance S. As S increases, the isotherms in the meridional plane are horizontal at small radii but they diverge at large radii. This creates temperature nonuniformilies in the horizontal direction, and convective motions result. The salient features of the interior temperature profiles are captured by the theoretical model. The velocity field is characterized by two oppositely-directed circulations. As Ra or S varies, the qualitative circulation patterns remain substantially unchanged, but the magnitudes of the convective flows differ by large amounts. The effects of the externally-imposed parameters on the flow and temperature structures are examined.  相似文献   

无机生油假说及其在中国的应用前景   总被引：5，自引：1，他引：4       下载免费PDF全文

袁学诚  李善芳 《中国地质》2012,39(4):843-854

无机生油假说认为,原油和天然气和近地表的生物物质没有根本联系,它们是生成于地幔内的非生物来源的碳氢化合物。因而油气不是一个不可再生资源,而是一个可再生资源。无机生油假说得到地质学、物理学和化学等三个基本学科的支持。在地质观察上,发现全球许多大油田的油气储藏与原始生物物质之间数量上有巨大落差,难于解释它们是由生物生成的。此外,有许多地区在结晶基底或变质基底内,或直接位于其上的沉积岩中发现石油。从生物生油假说来说,也是无法理解的。在化学上,早在二战期间,德国已由人工合成石油(费托合成),并生产了占德国战争中用油的9%的石油。无可争辩地说明,无机可以生成石油。根据化学(物理学)热力学理论分析确认,甲烷是唯一一种在标准温压条件(温度为298.15 K;压力为101325 Pa)下稳定的碳氢化合物,从甲烷形成正常烷属烃只有在压力>3×106kPa、温度>700°C时(相当于地下深度约100 km)才有可能。在地壳内的温压条件下由生物变质形成石油的假说,与化学热力学的基本原则相抵触。从氧化的有机分子,如碳水化合物(C6H12O6)形成较高的碳氢化合物在任何条件下都是不可能的。根据我国长期对深部构造的研究,笔者认为在中国东部及西太平洋蘑菇云岩石圈地幔发育的地区是寻找巨型无机油气田的有利地区,建议在发育蘑菇云岩石圈地幔地区开展无机油气田的勘探,并在无机油气田远景地区布置超深参数钻,以评价含油气远景。另外建议加强物探工作,尤其是研究地震勘探处理基底内三维含油气构造的技术。  相似文献   

Thermodynamic processes of lake ice and landfast ice around Zhongshan Station, Antarctica     

LEI RuiBo  LI ZhiJun  ZHANG ZhanHai  CHENG YanFeng 《极地研究(英文版)》2011,(3):143-152

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Predict C2H6 Concentration in Aqueous Solution Equilibrium with Its Hydrate in the Absence of Vapor     

GENG Lantao  SUN Rui  LU Wanjun 《《地质学报》英文版》2013,87(Z1):991-992

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Thermodynamically constrained averaging theory approach for modeling flow and transport phenomena in porous medium systems: 4. Species transport fundamentals     

Cass T. Miller  William G. Gray 《Advances in water resources》2008

This work is the fourth in a series of papers on the thermodynamically constrained averaging theory (TCAT) approach for modeling flow and transport phenomena in multiscale porous medium systems. The general TCAT framework and the mathematical foundation presented in previous works are built upon by formulating macroscale models for conservation of mass, momentum, and energy, and the balance of entropy for a species in a phase volume, interface, and common curve. In addition, classical irreversible thermodynamic relations for species in entities are averaged from the microscale to the macroscale. Finally, we comment on alternative approaches that can be used to connect species and entity conservation equations to a constrained system entropy inequality, which is a key component of the TCAT approach. The formulations detailed in this work can be built upon to develop models for species transport and reactions in a variety of multiphase systems.  相似文献   

Thermodynamically constrained averaging theory approach for modeling flow and transport phenomena in porous medium systems: 6. Two-fluid-phase flow     

Amber S. Jackson  Cass T. Miller  William G. Gray 《Advances in water resources》2009

This work is the sixth in a series of papers on the thermodynamically constrained averaging theory (TCAT) approach for modeling flow and transport phenomena in multiscale porous medium systems. Building upon the general TCAT framework and the mathematical foundation presented in previous works, the limiting case of connected two-fluid-phase flow is considered. A constrained entropy inequality is developed based upon a set of primary restrictions. Formal approximations are introduced to deduce a general simplified entropy inequality (SEI). The SEI is used along with secondary restrictions and closure approximations consistent with the SEI to produce a general functional form of a two-phase-flow model. The general model is in turn simplified to yield a hierarchy of models by neglecting common curves and by neglecting both common curves and interfaces. The simplest case considered corresponds to a traditional two-phase-flow model. The more sophisticated models including interfaces and common curves are more physically realistic than traditional models. All models in the hierarchy are posed in terms of precisely defined variables that allow for a rigorous connection with the microscale. The explicit nature of the restrictions and approximations used in developing this hierarchy of models provides a clear means to both understand the limitations of traditional models and to build upon this work to produce more realistic models.  相似文献   

钛白废液的治理与综合利用硫酸钾溶解平衡的热力学研究     

谭龙华  钟辉  陈鹰  苏庆平  麦建新 《矿物岩石》2000,20(4):92-94

本文应用热力学基本原理和方法研究硫酸钾溶解平衡,结果表明,硫酸钾在纯水中的溶解度随温度变化符合前人总结的实验规律,而在４３℃的钛白废水液液中硫酸钾有反常深 现象,这为确定硫酸钾结晶析出的最佳温度提供了热力学依据,通过热力学计算,论证了硫酸钾溶解平衡符合势学基本原理。  相似文献   

A thermodynamic model for Ca–Na clinoamphiboles in Na₂O–CaO–FeO–MgO–Al₂O₃–SiO₂–H₂O–O for petrological calculations     

J. DALE  R. POWELL  R. W. WHITE  F. L. ELMER  T. J. B. HOLLAND 《Journal of Metamorphic Geology》2005,23(8):771-791

A calibration is presented for an activity–composition model for amphiboles in the system Na₂O–CaO–FeO–MgO–Al₂O₃–SiO₂–H₂O–O (NCFMASHO), formulated in terms of an independent set of six end‐members: tremolite, tschermakite, pargasite, glaucophane, ferroactinolite and ferritschermakite. The model uses mixing‐on‐sites for the ideal‐mixing activities, and for the activity coefficients, a macroscopic multicomponent van Laar model. This formulation involves 15 pairwise interaction energies and six asymmetry parameters. Calibration of the model is based on the geometrical constraints imposed by the size and shape of amphibole solvi inherent in a data set of 71 coexisting amphibole pairs from rocks, formed over 400–600 °C and 2–18 kbar. The model parameters are calibrated by combining these geometric constraints with qualitative consideration of parameter relationships, given that the data are insufficient to allow all the model parameters to be determined from a regression of the data. Use of coexisting amphiboles means that amphibole activity–composition relationships are calibrated independently of the thermodynamic properties of the end‐members. For practical applications, in geothermobarometry and the calculation of phase diagrams, the amphibole activity–composition relationships are placed in the context of the stability of other minerals by evaluating the properties of the end‐members in the independent set that are in internally consistent data sets. This has been performed using an extended natural data set for hornblende–garnet–plagioclase–quartz, giving the small adjustments necessary to the enthalpies of formation of tschermakite, pargasite and glaucophane for working with the Holland and Powell data set.  相似文献