柱撑蛭石吸附去除废水中重金属离子的实验研究   总被引：2，自引：0，他引：2  

刘云  吴平霄  党志 《矿物岩石》2006,26(4):8-13

分别利用有机柱化剂十二烷基磺酸钠(SDS)和无机柱化剂聚羟基铝(HA)对蛭石进行柱撑制得十二烷基磺酸钠柱撑蛭石(SDS-V erm icu lite)和聚羟基铝柱撑蛭石(HA-V erm icu lite),并通过XRD、红外光谱、ZETA电位等表征手段对柱撑蛭石进行表征,同时针对柱撑蛭石对Cu2 ,Cd2 ,C r3 3种重金属离子的吸附进行研究,结果表明:吸附去除率受反应时间、重金属离子的初始浓度、pH值等因素的影响,经柱撑后的蛭石对重金属离子吸附的吸附性能比蛭石原矿要强。柱撑蛭石吸附3种重金属离子的动力学吸附过程可用E lov icb方程和双常数方程进行较好的拟合。  相似文献   

古亚洲与特提斯交汇带盆地群油气资源潜力   总被引：6，自引：1，他引：6  

卢进才  陈践发  郭建军  王洪亮  李玉宏 《西北地质》2006,39(3):39-47

古亚洲与特提斯构造交汇带盆地群发育石炭系、侏罗系(中下统)、白垩系(下统)等多套烃源岩,具有厚度大、分布广、有机质丰度高的特点.石炭系烃源岩有机质进入成熟-过成熟热演化阶段,侏罗系烃源岩有机质已进入大量生油阶段,白垩系烃源岩也处于生油高峰,具有良好的油气成藏的物质基础;区内储集岩发育,石炭-二叠系储集层以低孔隙度、低渗透率为特征,石炭系储集层主要为潮坪-泻湖相沉积的碎屑岩,二叠系储集层为一套河流相粗碎屑岩;侏罗-白垩系储集层物性相对较好,以中孔、中渗,或中孔、高渗为特征,为以河流-三角洲沉积砂体;在石炭-二叠系、中新生代地层中均见到了不同级别的油气显示或获工业油流.存在3种不同的生储盖组合,即①自生自储式组合.②下生上储的间隔式组合.③潜山型组合.预测油气资源量36.85亿t,目前已发现的油气储量仅为1亿t,具较大的勘探潜力.  相似文献   

U-Pb-Hf isotopic data from detrital zircons in late Carboniferous and Mid-Late Triassic sandstones,and also Carboniferous granites from the Tauride and Anatolide continental units in S Turkey: implications for Tethyan palaeogeography     

Timur Ustaomer  Petek Ayda Ustaömer  Alastair H. F. Robertson  Axel Gerdes 《International Geology Review》2020,62(9):1159-1186

ABSTRACT

Zircons from Carboniferous sandstones (three samples) and Mid-Late Triassic sandstones (four samples) from the Tauride and Anatolide continental units were analysed for U-Pb-Hf isotopes. For comparison, zircons were also analysed from Carboniferous granites of the Afyon Zone, Anatolides (three samples). A NE African/Arabian source is inferred for both the Carboniferous sandstones of the Taurides (Alada?) and the Anatolides (Konya Complex). In contrast, the Carboniferous Karaburun Melange is characterised by a NW African provenance. A prominent Devonian population occurs in the Carboniferous Karaburun Melange, characterised by mainly positive ε_Hf(t) values that differ significantly from those of the Devonian granites of the Sakarya continental crustal unit (Pontides). Middle-Late Triassic Tauride sandstones include minor Palaeozoic and Early Mesozoic zircons. In contrast, Devonian and Carboniferous zircons are relatively abundant in Late Triassic sandstones of the Karaburun Peninsula. The Hf isotopic compositions of 25 Carboniferous-aged zircons from three samples of Mid-Late Triassic sandstone and one of Late Carboniferous age (one sample) overlap with the ε_Hf(t) values of Carboniferous arc-type granites in the Anatolides. Taking account of the available U-Pb and Lu-Hf isotopic data from comparative crustal units, the Devonian zircon populations from the melanges in the Karaburun Peninsula and the Konya Complex are inferred to have a westerly source (e.g. granitic rocks of Aegean region or central Europe). A tectonic model is proposed in which Palaeozoic Tethys sutured during the late Carboniferous in the west (Aegean region westwards), leaving an eastward-widening oceanic gulf in which sandstone turbidites accumulated, including Devonian zircons.  相似文献   

藕塘古滑体在三峡水库形成后的稳定性分析   总被引：2，自引：0，他引：2  

杨家岭  朱维申  罗晓东  张玉军 《岩土力学》1998,(2)

采用极限平衡和三维弹塑性有限元分析方法,对藕塘古滑体在三峡水库形成后的稳定性进行了计算分析。计算中考虑了水库水位变化、渗透压力、建筑荷载以及地震等诸多因素对滑体稳定性的影响,并给出了滑体失稳的临界破坏条件,为库区移民迁建新址的勘察工作提供了量化的论证。  相似文献   

云南永平县水泄辉长岩锆石U- Pb年代学、地球化学及地质意义     

李赛赛  王洋  张洪瑞  刘兴源  王秋宇  杨澍 《地质学报》2023,97(4):1157-1177

滇西地区二叠纪—三叠纪岩浆岩展布还不清楚,导致相关古特提斯构造演化模型还存在争议。本文对兰坪-思茅盆地西缘水泄地区的辉长岩开展了LA-ICP-MS锆石U-Pb定年、锆石Hf同位素、全岩主微量元素及Sr-Nd同位素分析,探讨了岩石成因及地质意义。水泄辉长岩2件样品的锆石U-Pb年龄分别为237.8±3.4 Ma和240.8±3.3 Ma,代表其结晶年龄,属于中三叠世。样品具有较高的Na₂O/K₂O(3.81～49.14),明显富集Ba、Rb、Th、U等大离子亲石元素,相对亏损Nb、Ta等高场强元素,稀土元素弱分馏,轻稀土弱富集,δEu值为0.87～1.07,无明显的Eu异常。锆石ε_Hf(t)值全为正值,主要介于+5.67～+15.75,全岩初始⁸⁷Sr/⁸⁶Sr比值为0.70453～0.70776,ε_Nd(t)值全为正值,介于+4.9～+5.2。地球化学特征显示水泄辉长岩来源于亏损地幔的部分熔融,在岩浆演化过程中发生了镁铁质矿物和铁钛矿物的分离结晶作用。水泄...  相似文献   

滇西三江地区中生代盆—山动力学耦合初论   总被引：4，自引：0，他引：4  

杨鑫  刘燕红  孙国强  刘兴旺  王保忠  郑建京 《地质论评》2010,56(2):196-204

盆地和相邻造山带在动力学机制上的耦合关系是当前大陆动力学研究的热点,滇西三江地区中—新生代盆山格局是开展这一研究的典型实例。晚三叠世思茅盆地从前陆盆地向裂谷盆地的转换过程,与造山带演化的主碰撞阶段和后碰撞阶段相关,是研究的切入点。通过分析研究区中—新生代盆—山耦合过程及其沉积响应、地球物理和岩浆岩地球化学特征来探讨其深部动力学过程的一致性和连续性。研究表明三江地区中—新生代盆山演化经历了"盆转山"(T1—T2)、"山控盆"(T3—E1)以及盆—山共变(E2—Q)三个阶段;思茅陆相断陷湖盆通过盆地内沉积相迁移、层序建造、基底变形,尤其是沉积旋回来响应深部动力学过程;岩石圈速度结构剖面揭示出思茅盆地的下地壳和岩石圈地幔P波速度增大,莫霍面加深;结合思茅盆地两侧中生代岩浆岩活动期次和地球化学特征,底侵作用、拆沉作用和俯冲板片断离作用可能是盆山动力学耦合的深部作用模式。  相似文献   

二叠纪—三叠纪古气候研究进展——泛大陆巨型季风气候:形成、发展与衰退   总被引：2，自引：0，他引：2  

钱利军  时志强  欧莉华 《海相油气地质》2010,15(3)

巨型季风是指二叠纪—三叠纪期间泛大陆上存在的强烈季节风,它的形成与泛大陆的形状、海陆分布及大陆的纬向分布密切相关。从晚石炭世泛大陆的聚合至晚侏罗世—早白垩世泛大陆裂解,巨型季风经历了形成、发展到衰退的过程。在三叠纪,泛大陆很大且几乎关于赤道对称,巨型季风达到最大强度。它对古气候、古环境、古生物及沉积等都产生了深刻的影响,使泛大陆低纬度地区呈现出干旱和潮湿交替的气候特征,蒸发岩和红层广泛分布;高纬度地区温暖潮湿,煤层大量分布;科罗拉多高原(美国西部)、西特提斯(欧洲)和东特提斯(中国)等地的二叠纪—三叠纪沉积地层也显示了受巨型季风影响的特征。  相似文献   

苏北地区老井复查测井综合评价技术及方法研究     

徐卫良  马大洪  王安本  卞乃干  杨立东 《上海国土资源》2010,31(Z1)

随着苏北小油田勘探开发程度的提高,非常规储层日益成为重点勘探开发的对象。苏北地区老井测井资料复查,立足现有的常规测井资料,结合测试等资料,通过扎实的基础工作和测井评价技术和分析方法的进步和提高,重点在干、密、水、无中全方位找油,并对以往相对忽视和评价认识手段方法相对不足的低孔渗储层、特殊含灰低孔渗储层与低阻油层作为重点研究分析对象,对测井资料进行全面复查评价,取得了良好的油气成果。  相似文献   

Economic development and energy efficiency in Jilin Province,China     

ZHANG Huimin  QIU Fangdao  WEI Qiang  TONG Lianjun  YE Xinyue  CHENG Yeqing 《地理学报》2014,24(5):875-888

The relationship between economic development and energy consumption is revealed by employing cointegration theory, the index decomposition method, and a log-linear regression approach based on a case study of Jilin Province, China. The results suggest: 1) the economic development and energy consumption are interdetermined, whose relationship is positive and long-term. The economic development is highly depending on the energy in Jilin Province. 2) Under the condition of other unchanged factors, the change of industrial energy efficiency contributes to the energy saving, while that of industrial structure increases the energy consumption. 3) The industrial structure change enhances the energy intensity, but the energy utility efficiency change lowers it. From the view of contribution to the energy consumption, the contribution of industrial structure was more than that of the energy utility efficiency in 2000-2011. 4) In 2000-2011, the comprehensive energy intensity change and hydroelectricity energy intensity change were related to all industrial structures' change, and the influencing factors about structure of oil energy intensity change were more than those of coal energy intensity change; from the impact degree, agricultural proportion decreased exerted an positive and greater effect on lowering the energy intensity of comprehensive energy and hydroelectricity, and industrial one did on coal and natural gas. Some conclusions can be drawn as follows: the major way to promote the coordinated development of the industrial economy and energy consumption is to optimize the industrial structure by increasing the proportion of the tertiary industry and low energy consumption industrial sectors and to enhance the energy utility efficiency.  相似文献   

老工业区产业结构转型与用地结构转型互动机制及优化路径——以上海市宝山区为例   总被引：1，自引：0，他引：1  

尚勇敏  曾刚 《地域研究与开发》2014,(5)

尝试理清老工业区产业结构转型与用地结构转型内涵,提出其转型效率的函数表达,分析二者间的互动关系;并运用改进的动态变化度及偏离系数,对上海市宝山区进行实证研究。结果表明:(1)宝山区产业结构与用地结构变化度逐渐增加,工业和第三产业动态度分别由1996年的2.48%和5.36%上升至2012年的4.75%和5.51%,用地结构动态度由11.16%上升至13.53%;(2)宝山区三次产业结构总体趋于优化,但产业内部并未优化,仍以重化工业和传统服务业为主导;(3)宝山区用地结构与产业结构不协调并处于加剧的状态。老工业区产业结构与用地结构存在较强的互动关系,改进的动态变化度及偏离系数方法为老工业区产业结构转型与用地结构转型问题提供了一种研究思路。提出宝山区产业结构转型与用地结构转型的优化路径。  相似文献