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81.
Anhydrite pseudomorphs and the origin of stratiform Cu–Co ores in the Katangan Copperbelt (Democratic Republic of Congo) 总被引:1,自引:1,他引:0
Ph. Muchez P. Vanderhaeghen H. El Desouky J. Schneider A. Boyce S. Dewaele J. Cailteux 《Mineralium Deposita》2008,43(5):575-589
The stratiform Cu–Co ore mineralisation in the Katangan Copperbelt consists of dispersed sulphides and sulphides in nodules
and lenses, which are often pseudomorphs after evaporites. Two types of pseudomorphs can be distinguished in the nodules and
lenses. In type 1 examples, dolomite precipitated first and was subsequently replaced by Cu–Co sulphides and authigenic quartz,
whereas in type 2 examples, authigenic quartz and Cu–Co sulphides precipitated prior to dolomite and are coarse-grained. The
sulphur isotopic composition of the copper–cobalt sulphides in the type 1 pseudomorphs is between −10.3 and 3.1‰ relative
to the Vienna Canyon Diablo Troilite, indicating that the sulphide component was derived from bacterial sulphate reduction
(BSR). The generation of during this process caused the precipitation and replacement of anhydrite by dolomite. A second product of BSR is the generation
of H2S, resulting in the precipitation of Cu–Co sulphides from the mineralising fluids. Initial sulphide precipitation occurred
along the rim of the pseudomorphs and continued towards the core. Precipitation of authigenic quartz was most likely induced
by a pH decrease during sulphide precipitation. Fluid inclusion data from quartz indicate the presence of a high-salinity
(8–18 eq. wt.% NaCl) fluid, possibly derived from evaporated seawater which migrated through the deep subsurface. 87Sr/86Sr ratios of dolomite in type 1 nodules range between 0.71012 and 0.73576, significantly more radiogenic than the strontium
isotopic composition of Neoproterozoic marine carbonates (87Sr/86Sr = 0.7056–0.7087). This suggests intense interaction with siliciclastic sedimentary rocks and/or the granitic basement.
The low carbon isotopic composition of the dolomite in the pseudomorphs (−7.02 and −9.93‰ relative to the Vienna Pee Dee Belemnite,
V-PDB) compared to the host rock dolomite (−4.90 and +1.31‰ V-PDB) resulted from the oxidation of organic matter during BSR. 相似文献
82.
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84.
文章通过详细的野外地质调查和系统的岩石化学、稀土元素、微量元素及硅、氧同位素等研究,探讨了羊蹄子山-磨石山钛矿区无矿白色硅质岩和富钛硅质岩的成因及形成地质构造环境。研究结果表明,呈厚层状产出的无矿白色硅质岩具较高的SiO2、Al2O3含量及Al/(Al Fe Mn)、Al2O3/(Al2O3 Fe2O3)比值,稀土元素总量很低,其北美页岩标准化配分模式为向右倾的曲线,无明显铈异常和铕异常,表明其形成于受陆源影响的大陆边缘构造环境;赋矿岩系中薄层状富钛硅质岩的TiO2、Fe2O3、Cu、V含量较高,但Al/(Al Fe Mn)、Al2O3/(Al2O3 Fe2O3)比值较低,稀土元素总量较高,北美页岩标准化曲线为明显左倾型-平坦型,具弱的负铈异常,表明其形成于洋脊及附近环境。两种硅质岩的δ30Si值为变化较小的负值,与热水沉积和某些生物成因硅质岩的硅同位素组成相似,两者的δ18O值范围和平均值均相似。两类硅质岩的成因及形成构造环境不同,富钛硅质岩的地球化学特征表明,该矿床的形成与本区元古宙海底火山热液喷流作用有关。 相似文献
85.
广西大厂拉么锌铜多金属矿床成岩成矿作用年代学研究 总被引:20,自引:1,他引:19
本文对广西大厂矿田拉么矿区内出露的酸性侵入岩和矿石进行了精细的年代学研究,分别获得龙箱盖含斑黑云母花岗岩锆石原位SHRIMP UPb和全岩RbSr等时线年龄为94±4Ma(95%可信度)和98.6±1.9Ma(95%可信度),矽卡岩成矿期锌铜矿石中石英矿物RbSr等时线年龄为98.6±6Ma(95%可信度)。上述测定结果表明,拉么锌铜多金属矿床的成矿年龄与相关岩体的成岩年龄接近,均形成于早白垩世晚期。 相似文献
86.
Origin of Fe-Ti Oxide Ores in Mafic Intrusions: Evidence from the Panzhihua Intrusion, SW China 总被引:12,自引:0,他引:12
Pang Kwan-Nang; Zhou Mei-Fu; Lindsley Donald; Zhao Donggao; Malpas John 《Journal of Petrology》2008,49(2):295-313
Economic concentrations of Fe–Ti oxides occur as massive,conformable lenses or layers in the lower part of the Panzhihuaintrusion, Emeishan Large Igneous Province, SW China. Mineralchemistry, textures and QUILF equilibria indicate that oxidesin rocks of the intrusion were subjected to extensive subsolidusre-equilibration and exsolution. The primary oxide, reconstructedfrom compositions of titanomagnetite in the ores and associatedintergrowths, is an aluminous titanomagnetite (Usp40) with 40wt % FeO, 34 wt % Fe2O3, 16·5 wt % TiO2, 5·3 wt% Al2O3, 3·5 wt % MgO and 0·5 wt % MnO. This compositionis similar to the bulk composition of the oxide ore, as inferredfrom whole-rock data. This similarity strongly suggests thatthe ores formed from accumulation of titanomagnetite crystals,not from immiscible oxide melt as proposed in earlier studies.The occurrence of oxide ores in the lower parts of the Panzhihuaintrusion is best explained by settling and sorting of densetitanomagnetite in the ferrogabbroic parental magma. This magmamust have crystallized Fe–Ti oxides relatively early andabundantly, and is likely to have been enriched in Fe and Tibut poor in SiO2. These features are consistent with fractionationof mantle-derived melts under relatively high pressures (10kbar), followed by emplacement of the residual magma at 5 kbar.This study provides definitive field and geochemical evidencethat Fe–Ti oxide ores can form by accumulation in ferrogabbro.We suggest that many other massive Fe–Ti oxide depositsmay have formed in a similar fashion and that high concentrationsof phosphorus or carbon, or periodic fluctuation of fO2 in themagma, are of secondary importance in ore formation. KEY WORDS: ELIP; Fe–Ti oxide ore; layered intrusion; Panzhihua; QUILF 相似文献
87.
Klauea historical summit lavas have a wide range in matrix 18OVSMOWvalues (4·9–5·6) with lower values in rockserupted following a major summit collapse or eruptive hiatus.In contrast, 18O values for olivines in most of these lavasare nearly constant (5·1 ± 0·1). The disequilibriumbetween matrix and olivine 18O values in many samples indicatesthat the lower matrix values were acquired by the magma afterolivine growth, probably just before or during eruption. BothMauna Loa and Klauea basement rocks are the likely sources ofthe contamination, based on O, Pb and Sr isotope data. However,the extent of crustal contamination of Klauea historical magmasis probably minor (< 12%, depending on the assumed contaminant)and it is superimposed on a longer-term, cyclic geochemicalvariation that reflects source heterogeneity. Klauea's heterogeneoussource, which is well represented by the historical summit lavas,probably has magma 18O values within the normal mid-ocean ridgebasalt mantle range (5·4–5·8) based on thenew olivine 18O values. KEY WORDS: Hawaii; Klauea; basalt; oxygen isotopes; crustal contamination 相似文献
88.
Summary Left in place pillars of abandoned mines are subject to weathering (e.g action of water, bacteria) that degrades their mechanical
strength and eventually leads to collapse. A simple weathering model is proposed, that is governed by two parameters: the
rate of progression of weathered front and the rate of degradation of the compressive strength with time. Both plane strain
and axisymmetric analyses are performed and closed form solutions of the variation with time of the bearing capacity of the
pillar are given. Experimental data of the tests conducted on gypsum and anhydrite specimens attacked by water are presented.
It is shown that in order to fit the experimental data a third parameter must be introduced. New closed form solutions are
given and the data are used for estimating the time to failure of abandoned gypsum mines in Northern Italy.
Authors’ address: Dr. Riccardo Castellanza, Research Assistant, Department of Structural Engineering, Milan University of
Technology (Politecnico), Piazza Leonardo da Vinci 32, 20133 Milan, Italy 相似文献
89.
90.
An increasingly utilized strategy for expanding conservation in the developing world has been the promotion of protected areas
that supersede national borders. Alternatively known as transfrontier biosphere reserves, transfrontier or transboundary conservation
areas, or Peace Parks, these protected areas are aggressively advanced by conservation agencies for their purported ecological
and economic benefits. This article provides a comparative assessment of two case studies to understand the various impacts
of transboundary conservation. The Great Limpopo Transfrontier Park, which unites protected areas in South Africa, Mozambique
and Zimbabwe, is contrasted with efforts to protect jaguars along the United States–Mexico border. We argue that while these
cases are promising for the purposes of biodiversity protection, they demonstrate that transboundary conservation can minimize
political context, contributes to the hegemony of international conservation agendas, and remains closely linked to economic
neoliberalism and decentralization in the developing world.
相似文献
Brian KingEmail: |