Surface chemical analysis in coal preparation research: complementary information from XPS and ToF-SIMS     

A. N. Buckley  R. N. Lamb 《International Journal of Coal Geology》1996,32(1-4)

The application of X-ray photoelectron spectroscopy (XPS) to coal surface characterisation for preparation research is described. Progress towards the acquisition of complementary surface chemical information by time-of-flight secondary ion mass spectrometry (ToF-SIMS) is also discussed. Surface-based beneficiation techniques such as flotation are assuming greater importance as the proportion of fines in raw coal increases due to the proliferation of high capacity mining methods. A necessary condition for the floatability of a coal particle is adequate hydrophobicity, and the degree of hydrophobicity of the flotation concentrate is one factor influencing the ease with which its dewatering can be affected. The hydrophobicity of a coal is very difficult to measure directly because of microporosity, and it is often necessary to deduce the degree of hydrophobicity from a knowledge of the surface chemistry. XPS is able to provide sufficient analytical data to allow relative levels of hydrophobicity to be estimated. In principle, ToF-SIMS should be able to supply additional information enabling refinement of such estimates; however, there are insufficient data at present to allow the ionic fragments detected to be related to specific functional groups at the coal surface.  相似文献   

Conceptually-based shot noise modeling of streamflows at short time interval     

Federico Murrone  Fabio Rossi  Pierluigi Claps 《Stochastic Environmental Research and Risk Assessment (SERRA)》1997,11(6):483-510

A conceptual-stochastic approach to short time runoff data modelling is proposed, according to the aim of reproducing the hydrological aspects of the streamflow process and of preserving as much as possible the dynamics of the process itself. This latter task implies preservation of streamflow characteristics at higher scales of aggregation and, within a conceptual framework, involves compatibility with models proposed for the runoff process at those scales. At a daily time scale the watershed response to the effective rainfall is considered as deriving from the response of three linear reservoirs, respectively representing contributions to streamflows of large deep aquifers, with over-year response lag, of aquifers which run dry by the end of the dry season and of subsurface runoff. The surface runoff component is regarded as an uncorrelated point process. Considering the occurrences of effective rainfall events as generated by an independent Poisson process, the output of the linear system represents a conceptually-based multiple shot noise process. Model identification and parameter estimation are supported by information related to the aggregated runoff process, in agreement to the conceptual framework proposed, and this allows parameter parsimony, efficient estimation and effectiveness of the streamflow reproduction. Good performances emerged from the model application and testing made with reference to some daily runoff series from Italian basins.  相似文献   

Scattering Properties of Atmospheric Aerosols over Lanzhou City and Applications Using an Integrating Nephelometer   总被引：2，自引：0，他引：2  

张武  胡波  陈长和  杜萍  张镭  冯广泓 《大气科学进展》2004,21(6):848-856

The data, measured by a three-wavelength Integrating Nephelometer over Lanzhou City during the winters of 2001/2002 and 2002/2003 respectively, have been analyzed for investigating the scattering properties of atmospheric aerosols and exploring their relationship and the status of air pollution. The aerosol particle volume distribution is inverted with the measured spectral scattering coefficients. The results show that the daily variation of the aerosol scattering coefficients is in a tri-peak shape. The average ratio of backscattering coefficient to total scattering coefficient at 550 nm is 0.158; there exists an excellent correlation between the scattering coefficients and the concentration of PM10. The average ratio of the concentration of PM10 to the scattering coefficients is 0.37 g m-2, which is contingent on the optical parameters of aerosol particles such as the size distribution, etc.; an algorithm is developed for inverting the volume distribution of aerosol particles by using the histogram and Monte-Carlo techniques, and the test results show that the inversion is reasonable.  相似文献   

A Simple Parameterisation for Flux Footprint Predictions   总被引：9，自引：6，他引：9  

N. Kljun  P. Calanca  M. W. Rotach  H. P. Schmid 《Boundary-Layer Meteorology》2004,112(3):503-523

Flux footprint functions estimate the location and relative importance of passive scalar sources influencing flux measurements at a given receptor height. These footprint estimates strongly vary in size, depending on receptor height, atmospheric stability, and surface roughness. Reliable footprint calculations from, e.g., Lagrangian stochastic models or large-eddy simulations are computationally expensive and cannot readily be computed for long-term observational programs. To facilitate more accessible footprint estimates, a scaling procedure is introduced for flux footprint functions over a range of stratifications from convective to stable, and receptor heights ranging from near the surface to the middle of the boundary layer. It is shown that, when applying this scaling procedure, footprint estimates collapse to an ensemble of similar curves. A simple parameterisation for the scaled footprint estimates is presented. This parameterisation accounts for the influence of the roughness length on the footprint and allows for a quick but precise algebraic footprint estimation.  相似文献   

颗粒分析用量筒的规格标准和计量标定     

杨斌娟  马骏  刘燕 《上海国土资源》2004,(4):19-22

文章讨论了国内外用于密度计法颗粒分析用量筒的计量标准的规定，提出了相应的建议和标定方法。  相似文献   

Analysis of parameters of ground vibration produced from bench blasting at a limestone quarry     

Ali Kahriman 《Soil Dynamics and Earthquake Engineering》2004,24(11):887-892

The aim of this study is to predict peak particle velocity level at a limestone quarry located in Istanbul, Turkey. The ground vibration components were measured for 73 blast events during the bench blast optimization studies during a long period. In blasting operations; ANFO (blasting agent), gelatine dynamite (priming) and NONEL detonators (firing) were used as explosives at this site. Parameters of scaled distance (charge quantity per delay and the distance between the source and the station) were recorded carefully and the ground vibration components were measured by means of vibration monitors for every event. Then, the data pairs of scaled distance and particle velocity were analyzed. The equation of scaled distance extensively used in the literature was taken into consideration for the prediction of peak particle velocity. At the end of statistical evaluations, an empirical relationship with good correlation was established between peak particle velocity and scale distance for this site. The established relationship and the results of the study are presented.  相似文献   

Investigation of upper crust anisotropy in Ghaen-Birjand region, east-central Iran     

Mohammad-Reza Gheitanchi  Zoya Zarifii 《地震学报(英文版)》2004,17(5):518-525

IntroductionWhenpropagatingthroughananisotropicmedium,ashearwavesplitsintotwo(quasi)shearwaveswithdifferentpropagationspeedsandpolarizedorthogonally.Owingtotherecentdevel-opmentofseismicobservationsystem,detectionofshearwavessplittingwithverysmalldelaytimesbetweenfasterandslowershearwavesbecameavailableandprovidedpowerfulapproachfordetectionofcrustalanisotropy.Crampin(1978)emphasizedtheroleofalignedmicrocracksasacauseofcrustalanisotropyandpointedoutthatforverticallyalignedmicrocracksthedirecti…  相似文献   

北京市春夏季大气气溶胶的单颗粒分析表征   总被引：9，自引：0，他引：9  

肖锐刘成德  梁汉东董树屏 F．Adams 《岩矿测试》2004,23(2):125-131

采集了北京市2000年春夏季大气气溶胶样品5个，采用扫描电镜X射线能谱技术分析大气气溶胶单颗粒约2500个。研究结果表明，沙尘期间，矿物尘是最主要的颗粒物种类，非沙尘期间，北京市大气气溶胶中主要检出矿物尘和含硫颗粒物。夏季随着颗粒物污染的加重，含硫颗粒物的数目百分数增加。是北京市大气颗粒物污染的重要特征。重点讨论了Ca-S颗粒、K-S颗粒和Ca-K-S颗粒三类典型含硫颗粒物的化学组成和粒径分布特征。数目可观的Ca-K-S颗粒以及其他硫酸盐颗粒的生成与相对湿度和云量等气象条件相关，这些颗粒物可能是云中过程的产物。减少SO2排放，减少含硫颗粒物，对于控制北京市的大气颗粒物浓度水平具有重要意义。  相似文献   

采用DPIV技术研究浅水平板岛屿尾流          下载免费PDF全文

梁东方  李玉樑  陈嘉范 《水科学进展》2004,15(6):711-716

人们对于尾流的研究大都针对绕流体在展向非常长的情形,但是在天然环境和水利工程中出现的多为水深相对很浅的流动。由于槽底和自由水面的限制,浅水域中的尾流有着与深水尾流不同的流动规律。采用数字粒子图像测速(DPIV)技术,在长30m、宽3.5m、高1m的水槽中比较系统地量测了浅水中绕平板岛屿的尾流区流场。分析了大尺度旋涡的运动规律,得到了尾流流动形式随尾流稳定性参数的变化规律。目前如此大尺度浅水岛屿尾流的定量实验研究并不多见。  相似文献   

Aeolian abrasion and modes of fine particle production from natural red dune sands: an experimental study   总被引：3，自引：0，他引：3  

Joanna E. Bullard  Grant H. McTainsh†  Christa Pudmenzky† 《Sedimentology》2004,51(5):1103-1125

A series of experiments was conducted to determine the potential for aeolian abrasion of natural dune sands to produce fine particles (< 125 µm) by (1) the release of resident fines; (2) spalling, chipping and breakage of particles; and (3) the removal of grain surface coatings. Parent samples were obtained from the surfaces of four active continental dunes and abraded using a glass ‘test tube’ chamber for up to 120 h. The fine particles produced by this abrasion process were trapped at varying time intervals and subject to detailed particle‐size analyses using a Coulter Multisizer. The abrasion of untreated parent samples produced fine particles in one of two main size classes, < 10 µm and > 50 µm, but when the parent sample was sieved to exclude particles < 250 µm, relatively more material in the range 10–50 µm was produced. For unsieved parent samples, the size range associated with the dominant mode varied according to the length of the abrasion time. The coarsest mode (> 63 µm) was dominant during the first 16 h of abrasion, then became less significant and is thought to be associated with the release of resident fines into suspension. The finest mode (< 10 µm) was absent or very weak during the first 16 h of abrasion, then became more significant and, in some instances, dominated the distribution as abrasion continued. Removal of grain surface coatings is the main source of fine material < 10 µm, and this may be a significant source of fine material in areas where sands are dominated by subrounded and rounded particles. By comparison with previous studies of aeolian particle abrasion, these natural dune sands produced very low quantities of fine material (by weight), but their spatial extent makes them potentially a significant source of dust‐sized particles at the global scale.  相似文献