改进的卡洛斯管溶样等离子体质谱法测定地质样品中低含量铂族元素及铼的含量   总被引：8，自引：1，他引：7  

漆亮  周美夫  严再飞  皮道会  胡静 《地球化学》2006,35(6):667-674

报道了一个改进的卡洛斯管溶样等离子体质谱法测定地质样品中铂族元素及Re含量的新方法。将封闭的卡洛斯管置于高压釜中,然后在高压釜中加水,密封在高压釜中的水在高温下产生的外压将会抵消卡洛斯管中由酸产生的内压,这样就可以避免传统的卡洛斯管在高温高压下可能发生爆炸的危险。由此可以加大取样量,降低铂族元素测定过程中的块金效应及检出限,使超低含量铂族元素的测定成为可能。12g样品在75mL卡洛斯管中用35mL王水于320℃溶解15h,基本上可以使各种地质样品中的铂族元素矿物完全溶解。一次溶样可以测定全部铂族元素及Re,全流程空白值极低,国际标样测定结果稳定可靠。  相似文献   

有机质热演化过程中地层压力的作用与影响     

王兆明  罗晓容  陈瑞银  宋海明  周波  郑大海 《地球科学进展》2006,21(1):39-48

压力对有机质演化的影响长期以来争论不断,共有3种不同意见：压力对有机质演化没有影响,压力促进有机质的演化,压力抑制有机质的演化。通过对前人所做实验的实验设备、实验样品及实验结果的分析对比发现：不同实验结果主要是由于不同实验条件引起的,特别是实验系统和加压方式的不同,对实验结果影响最大,所代表的地质意义也不同。综合分析结果表明,当压力的增加表现为沉积有机质受到的有效应力增加时可以促进有机质生烃;当压力的增加表现为孔隙流体压力增加时,有机质生烃过程将受到抑制;另外,这两种情况都可能使干酪根的镜质组反射率降低,易使人得出压力增加抑制有机质演化的结论。进一步对压力影响有机质演化的成因机制进行了分析,发现在有机质演化的不同阶段因异常压力的增压机制不同,压力在有机质演化过程中所表现出来的作用也有差异。  相似文献   

利用毛管压力曲线分形分维方法研究流动单元   总被引：3，自引：0，他引：3  

师永民  张玉广  何勇  郑海飞  吕文忠  郑红军 《地学前缘》2006,13(3):129-134

利用取心井铸体薄片获得的图像资料和毛管压力曲线,通过图像分形几何学方法以分维数的形式定量地表征出了复杂的微观孔隙喉道结构特征,发现能够很好地划分和评价孔隙岩石中油、气、水的渗流差异,可以用于储层微观流动单元表征。文中阐述了岩石微观孔隙喉道结构分形的理论基础、计算方法和应用于表征流动单元的依据。建立了中国西部砾岩低渗透油藏微观孔隙喉道分维数与孔隙度、渗透率之间计算图版,据此在油藏中利用常规测井资料获得的孔隙度、渗透率参数计算微观孔隙喉道分维数,开展全油藏流动单元划分与评价,取得了良好的效果。研究结果表明,利用毛管压力曲线分形分维方法研究储层微观流动单元是一种很有效的途径。  相似文献   

波浪作用下成层海床孔隙水压力响应的简化分析     

刘占阁  栾茂田  王忠涛 《地震工程与工程振动》2006,26(2):156-160

采用不排水条件下孔隙水压力发展模式,作为Terzagh i一维固结方程中考虑波浪循环作用所引起的孔隙水压力源项,对于成层海床建立了推广的一维动力固结方程,运用数理方程中的分离变量法与G reen函数求解了成层海床在波浪作用下残余孔隙水压力的发展规律,进而对成层海床的液化势进行了评判。对比计算与分析表明,海床表层土的渗透性及其厚度对于海床的整体抗液化性能具有显著的影响,低渗透性的表层导致海床孔隙水压力的显著积累,此时表层置换法是防治液化的有效途径。  相似文献   

喜马拉雅超高压变质作用     

张金凤  张泽明 《地质科技情报》2006,25(4):69-73

喜马拉雅超高压变质带主要由表壳岩石组成,其中的长英质变质岩已经全部退变质,只在基性的榴辉岩中保留有某些超高压变质矿物.这些超高压变质矿物在锆石、石榴石及其他一些化学和机械性质稳定的矿物中以微米级的包裹体形式产出.到目前为止,已经在Tso Morari结晶穹隆和上Kaghan谷高喜马拉雅结晶岩中发现了超高压指示矿物柯石英和多晶石英假像.这2个地区同属一个超高压变质带,具有相似的构造背景、岩石组成及变质年龄.Kaghan谷超高压变质岩形成条件为700～770°C和2.7～3.2 GPa,相当于90～110 km 的上地幔深度,形成年龄为(46.2±0.7) Ma.Tso Morari结晶穹隆中超高压变质岩的形成条件约为750°C和3.9 GPa,形成年龄为(48±1) Ma.上述超高压变质带在其折返过程中普遍经历了强烈的水化和角闪岩相退变质作用.研究表明,印度大陆地壳俯冲的垂向速率为1.1～1.4 cm/a,水平速率为4.5 cm/a,俯冲到约100 km深度时的平均俯冲角度为14～19°.  相似文献   

松辽盆地古龙凹陷青山口组生排烃扩张微米孔/缝的发现及其意义     

何文渊  白雪峰  张金友  赵莹  刘召  钟建华  孙宁亮 《地质论评》2024,70(3):1159-1191

笔者等通过电子背散射、二次成像和能谱分析,结合薄片和反射显微镜观察,发现松辽盆地古龙凹陷青山口组页岩中发育了大量由生排烃扩张形成的微米孔和微米缝。生排烃高压扩张微米孔的特点有：①一般只发育在超高压的页岩油储层中;②一般只发育在黏土质长英页岩中,纯黏土岩少见;③多为近圆形或半圆形,直径多在0. 5 μm到数微米,一般1~2 μm,最大可达8 μm;④孔缘一般为以绿泥石为主的黏土,形成不连续的圈环;圈环上缘的黏土多呈弧形或眉状,绿泥石化明显,在背散射图像中呈亮色;⑤孔内多有自生的纳米级葡萄状或豆渣状黏土,是构成封存油气的物质基础;⑥生排烃高压扩张微米孔可以组合成4种类型：即垂向联结成垂直的排烃烟囱型、垂向联结成倾斜的排烃烟囱型、水平联结成顺层的排烃管型和竖面上联结成更大的片状大孔型。排烃烟囱直或微曲,直立或倾斜;宽1~3 μm,最宽可达200 μm;高十几到30 μm,最大可达1500 μm;顶部多与顺层微米缝（或毫米缝）联结,是排烃烟囱的最终泄压和泄油气的总库;生排烃扩张微米孔孔隙度变化大,面孔率一般在5%~6%,局部面孔率最高可达39. 66%。生排烃高压扩张微米缝的特点有：①一般只发育在超高压的页岩油储层中;②一般只发育在黏土质长英页岩中,纯黏土岩少见;③多以顺页理为主的微米缝为主;④略曲的张性缝,多呈锯齿状,绕过刚性矿物;⑤宽度多在0. 5 μm到数十微米;最宽可达150 μm;⑥多与黄铁矿、白云石、磷灰石等自生矿物伴生;⑦多与生排烃扩张微米孔和排烃烟囱相连。生排烃扩张微米孔缝的形成动力主要有两种：一种是烃类流体的高压扩张力;第二种是烃类流体的化学溶蚀力。笔者等计算了形成这种生排烃微米孔和微米缝的压力,形成生排烃扩张微米孔从1500 m的44. 74 MPa到2500 m深的74. 81 MPa;形成生排烃扩张微米缝的排烃压力稍大,在相同深度比形成生排烃扩张微米孔大3 MPa。生排烃扩张微米孔缝与其他孔缝相连构成了一个储运网络,使储层的储集能力和渗透性大幅增加,是可动用储量的主要贡献者,为古龙页岩油的开发创造了有利条件。生排烃扩张微米孔缝的发现对于古龙页岩油的勘探开发具有重要意义,同时对于页岩油储层的研究具有启发作用。  相似文献   

围压与轴压共同作用对恐龙化石应力场的影响          下载免费PDF全文

陈军  杜圣贤  张尚坤  贾超  刘凤臣  杨斌 《山东国土资源》2019,35(5)

包括恐龙化石在内的古生物化石是重要的地质遗迹,是研究生物进化的最重要资料。该文从物理力学角度,通过数值试验模拟分析围压和轴压作用下对恐龙化石强度和破坏特性的影响效果。试验结果表明:不同埋深时围压对含有不同角度裂隙化石应力影响较大,随着埋深增加,含有裂隙化石的应力大幅增大。在围压与轴压共同作用时,埋深对开裂角的影响较小,而随埋深增大时极限载荷也随之增大。同时,在不同埋深下开裂角随裂隙角度的变化趋势一致,均随着裂隙角度的增大而减小;而极限载荷随裂隙角度的变化趋势一致。  相似文献   

Two belts of HTLP sub-regional metamorphism in the New England Orogen,eastern Australia: occurrence and characteristics exemplified by the Wongwibinda Metamorphic Complex     

K. Jessop  N. R. Daczko  S. Piazolo 《Australian Journal of Earth Sciences》2020,67(4):479-507

Abstract

Two north–south-trending belts of high-temperature–low-pressure (HTLP) sub-regional metamorphism have been identified in the New England Orogen of eastern Australia. Metamorphic complexes in the ～1300?km long Early-Permian Inland belt have ages ca 300–290?Ma, and those of the ～400?km long Mid-Permian Coastal belt ca 275–270?Ma. These periods correspond to the beginning and end of an extended (early–mid Permian) phase of subduction rollback and crustal thinning in eastern Australia. This paper describes and incorporates recent work on the Wongwibinda Metamorphic Complex in the southern New England Orogen as a basis for comparison with thirteen other HTLP sub-regional occurrences within the orogen. These are described in as much detail as is currently available. Some outcrops of HTLP rocks in difficult terrain have been subject to limited study and only conditional comparisons can be made. However, a significant number of characteristics shared between the complexes including: their location at the higher-temperature end of broad areas of very low-grade to greenschist facies metamorphic rocks, indicative of tilted crustal blocks; their association with major shear zones; the presence of migmatite at the high-temperature end of a steep metamorphic field gradient; the presence of two-mica granite formed by the melting of the local sedimentary pile; and temporal association with S-type granites; imply a common extension-related mechanism of formation for these HTLP belts. The connection with major faults and shear zones suggests the belts trace major crustal-scale extensional structures that migrated eastwards from ca 300 to 270?Ma.

1. KEY POINTS

2. Two previously undocumented belts of HTLP subregional metamorphism are identified within the NEO.

3. Available dating indicates that metamorphism occurred along the belts at the beginning and end of a major early–mid Permian extensional phase in eastern Gondwana/Australia.

4. The characteristics of the HTLP complexes including their association with shear zones indicates they may delineate major loci of extension.

  相似文献   

One-dimensional self-weight consolidation with continuous drainage boundary conditions: Solution and application to clay-drain reclamation     

Jianxue Feng  Pengpeng Ni  Guoxiong Mei 《国际地质力学数值与分析法杂志》2019,43(8):1634-1652

Traditional consolidation theories cannot provide good predictions of consolidation settlement in land reclamation because of their assumptions that the influence of soil's self-weight is often neglected, and the drainage boundary is considered as fully pervious/impervious. In view of these limitations, an analytical solution is derived for one-dimensional self-weight consolidation problems with a continuous drainage boundary using the finite Fourier sine transform method. Following the classical Terzaghi's small strain theory, the soil's self-weight is considered to produce consolidation settlement in dredged materials with a constant coefficient of consolidation. The continuous drainage boundary can essentially describe the time-dependent variation of drainage capacity at the interface between two adjacent soil layers. By reducing the interface parameters, the effectiveness of the calculation is demonstrated against the Terzaghi's solution. The influence of interface parameters and soil's self-weight stress coefficient on self-weight consolidation is discussed. As expected, the rate of consolidation considering the self-weight stress is faster, although the dependency of consolidation rate on the material property of void ratio is neglected. Moreover, the plane of maximum excess pore-water pressure is estimated as a function of time factor, based on which a design chart is developed to optimize the layout of horizontal drains in land reclamation.  相似文献   

Relation between mean stress,thermodynamic, and lithostatic pressure     

Evangelos Moulas  Stefan M. Schmalholz  Yury Podladchikov  Lucie Taj manov  Dimitrios Kostopoulos  Lukas Baumgartner 《Journal of Metamorphic Geology》2019,37(1):1-14

Pressure is one of the most important parameters to be quantified in geological problems. However, in metamorphic systems the pressure is usually calculated with two different approaches. One pressure calculation is based on petrological phase equilibria and this pressure is often termed thermodynamic pressure. The other calculation is based on continuum mechanics, which provides a mean stress that is commonly used to estimate the thermodynamic pressure. Both thermodynamic pressure calculations can be justified by the accuracy and applicability of the results. Here, we consider systems with low‐differential stress (<1 kbar) and no irreversible volumetric deformation, and refer to them as conventional systems. We investigate the relationship between mean stress and thermodynamic pressure. We discuss the meaning of thermodynamic pressure and its calculation for irreversible processes such as viscous deformation and heat conduction, which exhibit entropy production. Moreover, it is demonstrated that the mean stress for incompressible viscous deformation is essentially equal to the mean stress for the corresponding viscous deformation with elastic compressibility, if the characteristic time of deformation is five times longer than the Maxwell viscoelastic relaxation time that is equal to the ratio of shear viscosity to bulk modulus. For typical lithospheric rocks, this Maxwell time is smaller than c. 10,000 years. Therefore, numerical simulations of long‐term (>10 kyr) geodynamic processes, employing incompressible deformation, provide mean stress values that are close to the mean‐stress value associated with elastic compressibility. Finally, we show that for conventional systems the mean stress is essentially equal to the thermodynamic pressure. However, mean stress and, hence, thermodynamic pressure can be significantly different from the lithostatic pressure.  相似文献