Trace gas exchange at the air/water interface: Measurements of mass accommodation coefficients     

W. Kirchner  F. Welter  A. Bongartz  J. Kames  S. Schweighoefer  U. Schurath 《Journal of Atmospheric Chemistry》1990,10(4):427-449

A liquid jet of 90 m diameter and variable length has been utilized to determine absorption rates and, hence, mass accommodation coefficients , of atmospheric trace gases. The compounds investigated are HCl (0.01), HNO₃ (0.01), N₂O₅ (0.005), peroxyacetyl nitrate (>0.001), and HONO (0.005). It is concluded that the absorption of these trace gases by liquid atmospheric water is not significantly retarded by interfacial mass transport. The strengths and limitations of the liquid jet technique for measuring mass accommodation coefficients are explored.  相似文献   

Performance of Mortar and Chemical Grout Injection into Surrounding Soil When Slurry Pipe-jacking Method is Used   总被引：1，自引：0，他引：1  

Hideki Shimada  Takashi Sasaoka  Saeid Khazaei  Yasuhiro Yoshida  Kikuo Matsui 《Geotechnical and Geological Engineering》2006,24(1):57-77

Small-diameter shallow tunnels are often being built by using the slurry pipe-jacking method. This system involves the pushing or thrusting of a drivage machine and concrete pipes into the ground. Chemical grout injection into the surrounding soil around the tunnel is carried out after the drivage and pushing processes are finished. The purpose of the chemical grout injection is to maintain permanent stability of the surrounding soil. However, the behavior of the chemical grouting material in the surrounding soil around the tunnel and the amount of optimum injection is not clearly understood. From these points of view, this paper discusses the performance of the chemical grouting material, when it is injected into the surrounding soil around the tunnel, by means of 2-D Eulerian–Lagrangian seepage analysis. Moreover, the effectiveness of the chemical grout injection was evaluated by using the non-linear finite element method. This investigation show when the range of the grouted zone is designed; it is necessary that the relationship between Young’s modulus of the soil/grouted zone and the confining stress be taken into consideration in order to establish effective, economical and safe chemical grout injection system. Understanding the performance of the seepage/dispersion behavior of the chemical grout and the characteristics of soil/ grouted zone is also important.  相似文献   

Spectral Simulation and Conditioning to Local Continuity Trends in Geologic Modeling     

Tingting Yao  Craig Calvert  Tom Jones  Glen Bishop  Yuan Ma  Lincoln Foreman 《Mathematical Geology》2006,38(1):51-62

Spectral simulation has gained application in building geologic models due to the advantage of better honoring the spatial continuity of petrophysical properties, such as reservoir porosity and shale volume. Distinct from sequential simulation methods, spectral simulation is a global algorithm in the sense that a global density spectrum is calculated once and the inverse Fourier transform is performed on the Fourier coefficient also only once to generate a simulation realization. The generated realizations honor the spatial continuity structure globally over the whole field instead of only within a search neighborhood, as with sequential simulation algorithms. However, the disadvantage of global spectral simulation is that it traditionally cannot account for the local information such as the local continuity trends, which are often observed in reservoirs and hence are important to be accounted for in geologic models. This disadvantage has limited wider application of spectral simulation in building geologic models. In this paper, we present ways of conditioning geologic models to the relevant local information. To account for the local continuity trends, we first scale different frequency components of the original model with local-amplitude spectrum ratios that are specific to the local trend. The sum of these scaled frequency components renders a new model that displays the desired local continuity trend. The implementation details of this new method are discussed and examples are provided to illustrate the algorithm.  相似文献   

绕坝渗流地下水位的时空分布模型研究   总被引：5，自引：0，他引：5       下载免费PDF全文

郑东健  王建 《水科学进展》2005,16(5):730-734

许多大坝的失事是由于高地下水位引起坝肩失稳所致。绕坝渗流是影响坝肩高地下水位的主要因素。为此通常将大坝基础防渗帷幕延伸到坝肩岸坡内一定距离,以减小绕坝渗流影响。而防渗帷幕运行性态随时间变化,为了评价坝肩防渗帷幕和地下水位的运行性态,首先分析了地下水位观测资料和水位、降水、温度、时效等时空影响因素及其表达式,随后基于岸坡地下水位观测资料,利用最小二乘法建立了大坝岸坡地下水位的时空分布模型。通过比较模型剩余标准差和测点的剩余标准差,可以确定坝肩地下水位的异常测点,分析岸坡防渗薄弱部位,掌握坝肩岸坡渗流场时空分布规律,监控绕坝渗流的性态。  相似文献   

三峡深水高土石围堰工程的渗流研究          下载免费PDF全文

戴会超  王玲玲 《水科学进展》2005,16(6):849-852

为了对三峡工程二期高土石围堰防渗设施的布置方案及其阻渗效果进行比较,采用有限元法对二期高土石围堰在不利的运行工况下的渗流场进行数值分析.比较了双排混凝土防渗墙方案、单排塑性混凝土低防渗墙加土工膜斜墙和单排厚塑性混凝土防渗墙等3种方案,分别采用恒定与非恒定模型计算,对立面二维和三维绕渗及防渗墙局部开裂等不利工况分别进行了数值模拟.结果表明:三方案均可有效抑制渗流场,双排混凝土防渗墙的防渗效果最好;墙体的局部开裂仅对局部区域的流场有影响.非恒定数值分析表明,堰体、基础不均匀沙石料及基坑抽水速度对渗流场影响极大,为保证堰体稳定,应限制基坑水位降落速度小于2 m/d.  相似文献