珠江流域碳酸盐岩与硅酸盐岩风化对大气CO_2汇的效应   总被引：6，自引：0，他引：6  

覃小群  蒋忠诚  张连凯  黄奇波  刘朋雨 《地质通报》2015,34(9):1749-1757

对珠江流域11个测站的河水1个水文年4次取样进行水化学和同位素测试分析,揭示无论是碳酸盐岩区还是硅酸盐岩区,岩石风化均使河流的离子成分以HCO3-、Ca2+、Mg2+为主,碳酸盐岩风化溶蚀速率和由碳酸盐岩风化溶蚀引起的大气CO2消耗量分别为27.60 mm/ka和540.21x103mol/(km2·a-1),是硅酸盐岩风化速率和由硅酸盐岩风化引起的大气CO2消耗量的10.8倍和6.7倍,说明碳酸盐岩风化是流域碳汇过程及效应的主体。由于有利的水热条件和高的碳酸盐岩面积比例,珠江流域平均岩石风化速率和由岩石风化作用引起的大气CO2消耗量分别为30.15mm/ka和620.36×103mol/(km2·a-1),为全球60条河流平均值的2.6倍。  相似文献   

Nutrient distributions in an estuary: Evidence of chemical precipitation of dissolved silicate and phosphate     

A.W. Morris  A.J. Bale  R.J.M. Howland 《Estuarine, Coastal and Shelf Science》1981,12(2):205-216

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A shrinking particle—shrinking core model for leaching of a zinc ore containing silica     

Vida Safari  Gilnaz Arzpeyma  Fereshteh Rashchi  Navid Mostoufi   《International Journal of Mineral Processing》2009,93(1):79-83

A new mathematical model was developed for leaching of zinc ores containing silicates such as hemimorphite which produce a gel during leaching with sulfuric acid. This model is based on the shrinking core model in which the particle size and the reacting core shrink simultaneously. It was shown that the actual dissolution time of the ore particles is longer than the time corresponding to the dissolution of chemical zinc oxide itself. It was suggested that because of the existence of silicates in the ore, a gelatinous layer was formed around the reacting core. Since the gel product is soft, it breaks apart when the particles collide and as a result, the particles shrink. However, a thin gelatinous layer always covers the reacting core which increases the mass transfer resistance and increases the leaching time. This model was applied to leaching of a zinc-rich tailing containing hemimorphite and the thickness of the gelatinous layer as well as the diffusion coefficient in this layer was determined.  相似文献   

3D打印技术在岩石物理力学试验中的应用     

刘泉声  何璠  邓鹏海  田永超 《岩土力学》2019,40(9):3397-3404

3D打印技术在岩土工程领域的应用还处于初步探索阶段,但其可重复制造含复杂内部结构的试样是常规室内试验无法实现的。现阶段制约3D打印技术在岩石物理力学试验中应用的主要因素在于3D打印试样强度偏低,延性较强。初步探讨了3D打印后干燥时间、打印胶水浓度对试样强度的影响,在此基础上提出了最优化打印方案,使打印试样在强度和脆性方面均有很大提升;通过改变打印方向模拟了天然层状节理岩石的各向异性特征。研究结果表明,随着打印倾斜角度的增加,3D打印试样的单轴抗压强度先减小后增大,呈"U"型变化趋势,抗拉强度也随打印方向的改变出现明显的各向异性特征,这与天然层状节理岩石相关研究成果相似。研究成果可为3D打印技术在岩土工程领域的推广和室内试验研究提供参考。  相似文献   

钠基蒙脱土水合演化机制     

张云龙  项伟  黄伟  刘清秉  DAO Minh huan 《岩土力学》2019,40(11):4391-4400

为了查明钠基蒙脱土的水合演化过程,以天然钠基蒙脱土为研究对象,开展在相对湿度（ ）为0～0.98区间的水汽等温吸-脱附试验,通过吸附速率曲线、BET曲线界定钠基蒙脱土各水合阶段及相应的水合主控因素;通过测定晶层 值变化规律,从吸附水影响黏土矿物晶层厚度的角度探讨钠基蒙脱土的水合演化特征;基于傅里叶红外光谱,从水分子结构伸缩振动信息角度对钠基蒙脱土水合演化过程进行定性定量验证;通过热重/差热分析,以吸附水相变所需能量与吸附水重量变化的角度解释钠基蒙脱土的吸附水特征与其水合机制的关系。试验结果表明：在较低相对湿度下（0 0.15）,以钠基蒙脱土矿物外表面吸附为主,形成表面吸附水;0.15 0.40为钠基蒙脱土层间阳离子水合阶段;0.40 0.98,为晶层内外表面水合阶段,水分子逐步完整的包裹蒙脱土,形成多层吸附层。钠基蒙脱土的水合演化过程受控于层间钠离子与晶层基面,层间钠离子的水合能影响了钠基蒙脱土水合演化的起始顺序。  相似文献   

碳酸氢钠冷却结晶动力学          下载免费PDF全文

蒋士姣 《盐湖研究》2021,29(2):50-57

碳酸氢钠(NaHCO_3)俗称小苏打,其产品质量取决于颗粒的大小,晶体的形貌和样品的纯度等诸多因素。本论文基于连续稳态MSMPR结晶器原理,研究了不同停留时间下,碳酸氢钠从碳酸钠溶液中冷却结晶过程动力学。利用实验数据建立了NaHCO_3的结晶动力学操作模型。实验和计算结果表明,随停留时间的增加,NaHCO_3过饱和度降低,晶体生长速率和成核速率均减小,相应的平均粒径增加,细颗粒含量减小;适当延长停留时间是制取高品质小苏打产品的有效途径。冷却结晶过程可有效增加小苏打产量,小苏打收率维持在55%左右。此外,一定Na_2CO_3存在下冷却结晶碳酸氢钠晶体形态由细长的针状变为规整的片状。  相似文献   

市场经济体制执行地质勘探规范的有关问题讨论     

殷友东  刘振红 《化工矿产地质》1997,19(2):135-138

市场经济体制下地质勘探工作的资金投入一般要由开采单位负担,而这部分资金属于前期投入,需要贷款来解决,现行的地质勘探规范已难适应地质工作的需要。在有一定工作基础的中小型矿山地质勘探工作中,对矿体的控制、水文地质、矿石可选性试验等工作程度,高级储量比例,勘查周期等方面,宜根据实际情况,合理的加以确定。  相似文献   

银量法测定化学试剂氯化钠中氯化钠纯度的不确定度评定     

冉广芬  朱广琴  王波 《盐湖研究》2018,26(2):43-47

针对银量法测定化学试剂氯化钠中氯化钠纯度,讨论了氯化钠纯度测定结果的测量不确定度的来源及评定方法,当K=2,氯化钠纯度测定结果的扩展不确定度为(99.70±0.64)%。  相似文献   

Mixing and chemical interdiffusion of trachytic and latitic magma in a subvolcanic complex of the Tertiary Westerwald (Germany)     

Ulrich Schreiber  Dirk Anders  Joachim Koppen 《Lithos》1999,46(4):263-714

A special kind of magma mixing is extraordinarily well exposed in the Bittersberg subvolcanic complex in the Tertiary volcanic field of the German Westerwald: A trachytic melt has been penetrated by a latitic dyke which has been dispersed within the host magma as small spherical enclaves (globules). Whole rock analyses of the globules show a change in composition that cannot be explained by a simple mechanical mixing between the endmembers. The most evolved globules have a phonolitic composition. Microprobe measurements in the microlithic matrix of the host rock and the guest indicate a diffusive motion of the alkalis from the host into the globules. On the other hand, an opposite trend can be observed for Ca, Mg, Fe and Ti, which are impoverished in the globules. The trace elements and the middle rare earth elements (MREE) has also been involved in the diffusive exchange. The REE-pattern of the most evolved (phonolitic) globules shows a characteristic trough in the area of the MREE which is almost identical to the REE-pattern of many phonolites. The phonolites and the alkali-rich trachytes of the Westerwald show similar globular textures as the Bittersberg volcanics. Therefore, generation of these rocks involving diffusive element exchange during mixing processes in a magma reservoir situated on a deeper crustal level may be possible.  相似文献   

Using the applied element method for modelling calcium silicate brick masonry subjected to in‐plane cyclic loading          下载免费PDF全文

Daniele Malomo  Rui Pinho  Andrea Penna 《地震工程与结构动力学》2018,47(7):1610-1630

The response of calcium silicate unreinforced masonry construction to horizontal cyclic loading has recently become the focus of experimental and numerical research, given its extensive use in some areas of the world that are now exposed to induced earthquakes (eg, north of the Netherlands). To assess the seismic behaviour of such construction, a relatively wide range of modelling methodologies are available, amongst which the discrete elements approach, which takes into account the intrinsic heterogeneity of a brick‐mortar assembly, can probably be deemed as the most appropriate computational procedure. On the other hand, however, since discrete elements numerical methods are based on a discontinuum domain, often they are not able to model every stage of the structural response adequately, and because of the high computational burden required, the analysis scale should be chosen carefully. The applied element method is a relatively recent addition to the discrete elements family, with a high potential for overcoming the aforementioned limitations or difficulties. Initially conceived to model blast events and concrete structures, its use in the earthquake engineering field is, of late, increasing noticeably. In this paper, the use of the applied element method to model the in‐plane cyclic response of calcium silicate masonry walls is discussed and scrutinised, also through the comparison with experimental results of in‐plane cyclic shear‐compression tests on unreinforced masonry walls.  相似文献