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71.
The aim of this interdisciplinary study is to examine a component of the hydrological cycle in Galapagos by characterizing
soil properties. Nine soil profiles were sampled on two islands. Their physical and hydrodynamic properties were analyzed,
along with their mineralogical composition. Two groups of soils were identified, with major differences between them. The
first group consists of soils located in the highlands (>350 m a.s.l.), characterized by low hydraulic conductivity (<10−5 m s−1) and low porosity (<25%). These soils are thick (several meters) and homogeneous without coarse components. Their clay fraction
is considerable and dominated by gibbsite. The second group includes soils located in the low parts of the islands (<300 m
a.s.l.). These soils are characterized by high hydraulic conductivity (>10−3 m s−1) and high porosity (>35%). The structure of these soils is heterogeneous and includes coarse materials. The physical properties
of the soils are in good agreement with the variations of the rainfall according to the elevation, which appears as the main
factor controlling the soil development. The clayey alteration products constrain soils physical and hydrodynamic properties
by reducing the porosity and consequently the permeability and also by increasing water retention. 相似文献
72.
M. I. Holloway F. Bussy T. W. Vennemann 《Contributions to Mineralogy and Petrology》2008,155(1):111-121
Migmatites produced by low-pressure anatexis of basic dykes are found in a contact metamorphic aureole around a pyroxenite–gabbro
intrusion (PX2), on Fuerteventura. Dykes outside and inside the aureole record interaction with meteoric water, with low or
negative δ18O whole-rock values (+0.2 to −3.4‰), decreasing towards the contact. Recrystallised plagioclase, diopside, biotite and oxides,
from within the aureole, show a similar evolution with lowest δ18O values (−2.8, −4.2, −4.4 and −7.6‰, respectively) in the migmatite zone, close to the intrusion. Relict clinopyroxene phenocrysts
preserved in all dykes, retain typically magmatic δ18O values up to the anatectic zone, where the values are lower and more heterogeneous. Low δ18O values, decreasing towards the intrusion, can be ascribed to the advection of meteoric water during magma emplacement, with
increasing fluid/rock ratios (higher dyke intensities towards the intrusion acting as fluid-pathways) and higher temperatures
promoting increasing exchange during recrystallisation.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
73.
Almeev Renat; Holtz Francois; Koepke Jurgen; Haase Karsten; Devey Colin 《Journal of Petrology》2008,49(1):25-45
Phase equilibria simulations were performed on naturally quenchedbasaltic glasses to determine crystallization conditions priorto eruption of magmas at the Mid-Atlantic Ridge (MAR) east ofAscension Island (7–11°S). The results indicate thatmid-ocean ridge basalt (MORB) magmas beneath different segmentsof the MAR have crystallized over a wide range of pressures(100–900 MPa). However, each segment seems to have a specificcrystallization history. Nearly isobaric crystallization conditions(100–300 MPa) were obtained for the geochemically enrichedMORB magmas of the central segments, whereas normal (N)-MORBmagmas of the bounding segments are characterized by polybariccrystallization conditions (200–900 MPa). In addition,our results demonstrate close to anhydrous crystallization conditionsof N-MORBs, whereas geochemically enriched MORBs were successfullymodeled in the presence of 0·4–1 wt% H2O in theparental melts. These estimates are in agreement with direct(Fourier transform IR) measurements of H2O abundances in basalticglasses and melt inclusions for selected samples. Water contentsdetermined in the parental melts are in the range 0·04–0·09and 0·30–0·55 wt% H2O for depleted and enrichedMORBs, respectively. Our results are in general agreement (within±200 MPa) with previous approaches used to evaluate pressureestimates in MORB. However, the determination of pre-eruptiveconditions of MORBs, including temperature and water contentin addition to pressure, requires the improvement of magma crystallizationmodels to simulate liquid lines of descent in the presence ofsmall amounts of water. KEY WORDS: MORB; Mid-Atlantic Ridge; depth of crystallization; water abundances; phase equilibria calculations; cotectic crystallization; pressure estimates; polybaric fractionation 相似文献
74.
Global Correlations of Ocean Ridge Basalt Chemistry with Axial Depth: a New Perspective 总被引:4,自引:0,他引:4
The petrological parameters Na8 and Fe8, which are Na2O andFeO contents in mid-ocean ridge basalt (MORB) melts correctedfor fractionation effects to MgO = 8 wt%, have been widely usedas indicators of the extent and pressure of mantle melting beneathocean ridges. We find that these parameters are unreliable.Fe8 is used to compute the mantle solidus depth (Po) and temperature(To), and it is the values and range of Fe8 that have led tothe notion that mantle potential temperature variation of TP= 250 K is required to explain the global ocean ridge systematics.This interpreted TP = 250 K range applies to ocean ridges awayfrom hotspots. We find no convincing evidencethat calculated values for Po, To, and TP using Fe8 have anysignificance. We correct for fractionation effect to Mg# = 0·72,which reveals mostly signals of mantle processes because meltswith Mg# = 0·72 are in equilibrium with mantle olivineof Fo89·6 (vs evolved olivine of Fo88·1–79·6in equilibrium with melts of Fe8). To reveal first-order MORBchemical systematics as a function of ridge axial depth, weaverage out possible effects of spreading rate variation, local-scalemantle source heterogeneity, melting region geometry variation,and dynamic topography on regional and segment scales by usingactual sample depths, regardless of geographical location, withineach of 22 ridge depth intervals of 250 m on a global scale.These depth-interval averages give Fe72 = 7·5–8·5,which would give TP = 41 K (vs 250 K based on Fe8) beneathglobal ocean ridges. The lack of Fe72–Si72 and Si72–ridgedepth correlations provides no evidence that MORB melts preservepressure signatures as a function of ridge axial depth. We thusfind no convincing evidence for TP > 50 K beneath globalocean ridges. The averages have also revealed significantcorrelations of MORB chemistry (e.g. Ti72, Al72, Fe72,Mg72, Ca72, Na72 and Ca72/Al72) with ridge axial depth. Thechemistry–depth correlation points to an intrinsic linkbetween the two. That is, the 5 km global ridge axial reliefand MORB chemistry both result from a common cause: subsolidusmantle compositional variation (vs TP), which determines themineralogy, lithology and density variations that (1) isostaticallycompensate the 5 km ocean ridge relief and (2) determine thefirst-order MORB compositional variation on a global scale.A progressively more enriched (or less depleted) fertileperidotite source (i.e. high Al2O3 and Na2O, and low CaO/Al2O3)beneath deep ridges ensures a greater amount of modal garnet(high Al2O3) and higher jadeite/diopside ratios in clinopyroxene(high Na2O and Al2O3, and lower CaO), making a denser mantle,and thus deeper ridges. The dense fertile mantle beneath deepridges retards the rate and restricts the amplitude of the upwelling,reduces the rate and extent of decompression melting, givesway to conductive cooling to a deep level, forces melting tostop at such a deep level, leads to a short melting column,and thus produces less melt and probably a thin magmatic crustrelative to the less dense (more refractory) fertile mantlebeneath shallow ridges. Compositions of primitive MORB meltsresult from the combination of two different, but geneticallyrelated processes: (1) mantle source inheritance and (2) meltingprocess enhancement. The subsolidus mantle compositional variationneeded to explain MORB chemistry and ridge axial depth variationrequires a deep isostatic compensation depth, probably in thetransition zone. Therefore, although ocean ridges are of shalloworigin, their working is largely controlled by deep processesas well as the effect of plate spreading rate variation at shallowlevels. KEY WORDS: mid-ocean ridges; mantle melting; magma differentiation; petrogenesis; MORB chemistry variation; ridge depth variation; global correlations; mantle compositional variation; mantle source density variation; mantle potential temperature variation; isostatic compensation 相似文献
75.
Gregory P. Marchildon Suren Kulshreshtha Elaine Wheaton Dave Sauchyn 《Natural Hazards》2008,45(3):391-411
Agriculture in the southern Great Plains of Canada has been particularly vulnerable to prolonged episodes of drought. Using
climate data and a precipitation minus potential evapotranspiration index, the extent of the region’s exposure to drought
is examined. Between 1914 and 1917, the Dry Belt was particularly vulnerable to drought, whereas after 1928, a much larger
region known as the Palliser Triangle covering most of southern Alberta and Saskatchewan was much more exposed to drought.
These droughts provoked major institutional adaptation, in particular the establishment of the Special Areas Board by the
Government of Alberta, and the creation of the Prairie Farm Rehabilitation Administration by the Government of Canada. Both
organizations have proved to be relatively permanent public adaptations to the natural hazard of drought in the region. Moreover,
these earlier experiences with prolonged drought as well as institution-building may be of value in helping the residents
of the Palliser Triangle adapt to predicted climate changes in the future as well as anticipate some of the barriers to effective
institutional adaptation. 相似文献
76.
运用3DEEMs及荧光偏振方法研究pH、离子强度及浓度效应对腐殖酸荧光光谱特性的影响 总被引:6,自引:0,他引:6
利用三维荧光激发.发射光谱(3DEEMs)及荧光偏振法研究了3例腐殖酸和1例湖泊溶解有机物(DOM)在不同腐殖酸浓度、离子强度和pH条件下的荧光光谱特性.实验结果表明,随着浓度增大,各腐殖酸样的荧光强度增大,其中垃圾渗滤液腐殖酸和Pahokee泥炭腐殖酸的荧光峰出现红移.随着浓度进一步增大,腐殖酸的荧光偏振值增大,由此推断在此浓度范围内腐殖酸由于分子间的排斥作用使其构型出现伸展.离子强度增大导致腐殖酸及阿哈湖DOM的荧光强度降低.随着氯化钾(KCI)浓度增大,Fluka腐殖酸的荧光峰A蓝移,荧光峰B的荧光偏振值出现减小,推测是由于静电中和作用使其荧光基团发生卷曲造成的.离子强度对其余腐殖酸样和阿哈湖DOM的其他荧光特性没有明显的影响.总的来说,pH值的变化对腐殖酸和湖泊DOM的荧光特征的影响是很明显的.随着pH值增大,腐殖酸和湖泊DOM的荧光强度增强.而pH值减小时,Fluka腐殖酸和Pahokee泥炭腐殖酸的荧光峰(A峰)蓝移,当pH值降到5时,Fhka腐殖酸的荧光峰突然红移到最大,随后又继续蓝移;垃圾渗滤液腐殖酸和阿哈湖DOM的荧光峰位无明显的漂移.所有样品的荧光偏振值都减小(但阿哈湖DOM的A峰变化不大),但在pHi≤5时又增大,这种现象表明随着pH值降低,腐殖酸和湖泊DOM中有机大分子发生卷曲,但在pH≤5时由于羧基的质子化又以平面伸展构型出现在溶液中. 相似文献
77.
The concentrations of twenty four chemical elements in the surface layer of natural desert soils and the cultivated farmland soils were measured at a desert-oasis ecotone in the middle of Heihe river basin, north-west China. Background values were estimated for (a) major elements (Si 335.3 g kg− 1, Al 49.4 g kg− 1, Fe 19.1 g kg− 1, Ca 29.4 g kg− 1, Mg 8.9 g kg− 1, K 20.1 g kg− 1, Na 17.5 g kg− 1 and P 0.338 g kg− 1), (b) heavy metals and non-metals (Cr 55.8 mg kg− 1, Mn 404.8 mg kg− 1, Ni 17.7 mg kg− 1, Cu 5.1 mg kg− 1, Zn 33.7 mg kg− 1, Pb 15.5 mg kg− 1 and As 5.2 mg kg− 1) and (c) other trace elements (Ti 2.0 mg kg− 1, V 55.3 mg kg− 1, Co 5.7 mg kg− 1, Rb 82.4 mg kg− 1, Sr 232.9 mg kg− 1, Y 14.7 mg kg− 1, Zr 194.9 mg kg− 1, Nb 7.8 mg kg− 1 and Ba 720.6 mg kg− 1). After natural desert soil was cultivated for agricultural use, significant changes in element concentrations occurred under tillage, irrigation and fertilisation management. Compared to natural soil, the for the levels of Si, K, Na, Sr, Zr and Ba decreased, and no changes were observed for Rb, while the values of the other 17 elements increase in agricultural soil from 1.2 to 3.5 times. However, their absolute concentrations are still low, suggesting that the arable soil in this region remains comparatively a clean soil. The increased silt, clay and organic carbon content, under long-term irrigation, enriched the fine-grained materials, and application of fertilisers and manure contributed to the accumulation of most elements in arable soil. The accumulation of elements in agricultural soil increased with increasing cultivation years and extent of soil development. 相似文献
78.
实验研究不同盐离子对水分子拉曼效应的影响 总被引:3,自引:0,他引:3
对流体包裹体中常见的几种盐水溶液进行了拉曼光谱分析.采用了频移参数描述水分子拉曼峰的形变强度,并讨论了频移参数与盐度之间的关系.实验分析结果表明,盐度越大,频移参数越大,水分子拉曼峰形变越大.对频移参数曲线斜率分析显示,盐类对水分子拉曼峰偏移程度影响的强弱顺序为NaCl>Na2SO4>NaHCO3>Na2CO3.讨论了不同阳离子和阴离子对水伸缩振动拉曼峰的影响,结果表明,高价阳离子的影响明显高于低价阳离子;而阴离子对水拉曼峰影响的强弱顺序初步确定为Cl-≈SO2-4->HCO-3>CO2-3≈NO-3. 相似文献
79.
土壤酶对碘离子在土壤中吸附行为的影响 总被引:1,自引:0,他引:1
以批式试验法研究了微生物、葡萄糖氧化酶、脲酶、纤维素酶及其催化底物葡萄糖、尿素和纤维素对Ⅰ-在土壤中吸附的影响,结果表明微生物能显著提高Ⅰ-吸附量,但葡萄糖氧化酶、脲酶、纤维素酶及葡萄糖、尿素和纤维素对Ⅰ-吸附并无促进作用.葡萄糖氧化酶及葡萄糖含量在小于100 mg/L时对Ⅰ-吸附无影响,1000 mg/L时与Ⅰ-呈竞争吸附;脲酶及尿素随浓度增大,对Ⅰ-吸附的抑制作用变得明显;1~1000 mg/L范围内,纤维素酶和纤维素对Ⅰ-吸附没有影响;但葡萄糖氧化酶和葡萄糖生成的中间产物可促进土壤对Ⅰ-的吸附.平衡液中溶解性有机碳(DOC)含量随时间增加而逐渐降低,有机质浓度越大,降低趋势越明显. 相似文献
80.