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71.
山西潞安集团司马矿区东高西低,西部延至长治盆地,矿区水系发育。主采3#煤层埋藏较浅,层位稳定。新生界不整合于下伏基岩之上,厚度变化较大,属典型的薄硬岩煤矿区。为准确提供矿区煤炭开采上限的地质依据,采用了综合勘探技术,其中利用三维地震勘探技术追踪新生界底面反射波及第四系"天窗"位置,利用直流电法与瞬变电磁法提供电性分层,并对其解释结果进行相互印证。勘探实例表明,三维地震勘探、电法勘探与钻探的综合运用不仅可解决薄硬岩煤矿区新生界厚度、含水层富水性及第四系缺失等问题,还可提供新生界含水层与基岩含水层之间的水力联系、制约因素等资料。  相似文献   
72.
以太平洋鳕鱼为原料,从鳕鱼脑中分离硫苷脂,确立了提取及纯化的条件,并对硫苷脂的纯度和分子种进行分析。首先,采用氯仿/甲醇(2∶1,v/v)提取总脂。然后,依次采用氯仿/甲醇/水(7∶3∶0.3,v/v/v)洗脱硅胶柱层析,含0.2mol/L乙酸铵的氯仿/甲醇/水(30∶60∶8,v/v/v)洗脱DEAE Sephadex-A25离子交换柱层析,40%甲醇脱盐和100%甲醇洗脱反相C8柱层析,获得硫苷脂纯品。最后,利用500YMC Diol液相色谱柱(3.0mm×250mm,5μm)分离,以正己烷/异丙醇(70∶30,v/v),异丙醇/水/甲酸/氨水(100∶13∶1∶0.14,v/v/v/v)为流动相梯度洗脱,采用负电喷雾电离(ESI)和母离子扫描模式,用液相色谱-串联质谱(LC-MS/MS)法分析了鳕鱼脑硫苷脂的纯度和分子种组成,并比较了其与哺乳动物脑中硫苷脂分子种组成的异同。结果表明,本实验制得的鳕鱼脑硫苷脂纯度为90.74%,与哺乳动物类似,鳕鱼脑硫苷脂的长链碱基以鞘氨醇为主,主要分子种为d18∶1-C24∶1,但脂肪酸的羟基化程度略低,且含少量独特的分子种,如d18∶1-22∶1和d18∶2-25∶2。  相似文献   
73.
An ion chromatographic method with a valve switching facility was developed to determine trace nitrate concentrations in seawater using two pumps, two different suppressors, and two columns. A carbohydrate membrane desalter was used to reduce the high concentrations of sodium salts in samples. In this method, trace nitrate was eluted from the concentrator column to the analytical columns, while the matrix flowed to waste. Neither chemical pre-treatment nor sample dilution was required. In the optimized separation conditions, the method showed good linearity (R〉0,99) in the 0.05 and 50 mg/L concentration range, and satisfactory repeatability (RSD〈5%, n=6). The limit of detection for nitrate was 0.02 mg/L. Results showed that the valve switching system was suitable and practical for the determination of trace nitrate in seawater.  相似文献   
74.
曹蒙  王志章  李冰涛  曲康  裴升杰  贾小玉 《地质论评》2023,69(2):2023020001-2023020001
在油气勘探、评价及开发中,岩性识别和薄片鉴定是十分重要的基础工作,准确的薄片识别结果可以为勘探和开发提供可靠的依据。传统的人工判定方法或实验室分析方法具有主观性强、效率低、自动化程度低等问题。目前基于内容的智能图像识别技术在准确性和具体应用方面还面临着许多难题。论文基于国内外相关研究成果与油气勘探与开发中岩芯薄片图像的特点及要求,设计并研制成功薄片图像自动识别系统和薄片智能鉴定系统。利用图像梯度分布和色彩分析进行火成岩岩石薄片智能分类,对所有像素进行类别划分进而得到整体的鉴定结果,实现了省时、高效、高精度的薄片智能鉴定成果。  相似文献   
75.
76.
金军  秦勇  易同生  高为  颜智华  李耿 《地质论评》2023,69(5):1879-1891
水页1井未压裂煤系高产气流的偶然发现,昭示黔西北威宁及其邻区下石炭统祥摆组可能成为我国西南局部地区煤系气勘查新层系。然而,该区祥摆组前期煤系气地质调查有限,关于资源条件和前景区的认识存在一定差异,且对煤系特点考虑不足。鉴于此,基于近期地质调查进展,结合前人基础地质研究成果,探讨了威宁及其邻区祥摆组煤系气地质条件和勘查前景。结果显示,威宁地区祥摆组是一套典型的薄互层煤系,下段潮坪—潟湖相煤系气显示强烈,但煤系储层总体上具有低孔特低渗的特征。单井研究发现,随埋深加大,祥摆组储层吸附气含量存在一个“临界深度”,一旦超过该深度,煤系页岩吸附甲烷含量快速增高,煤层吸附甲烷含量开始降低但其游离气含量可能增大,导致总含气量可能明显增大。综合分析认为,威宁地区祥摆组在埋深大于1500 m之后可能具有综合开发价值,龙街、羊场、海改地、二都、天星洞、玉龙6个深向斜是下一步勘查的重点构造单元,往东可扩展到黔西地区格目底、晴隆、朗岱等较大规模深向斜构造。同时,逆冲推覆构造对祥摆组煤系气保存条件的影响值得高度关注。基于上述分析,提出了落实祥摆组煤系气勘查战略选区的5条原则性建议。  相似文献   
77.
铀产品中杂质元素的含量测定在核法证学溯源分析或燃料元件厂质量检验中具有重要应用价值,保证测量的准确度主要在于控制流程空白、提高杂质元素的回收率。本文建立了戊基磷酸二戊酯(UTEVA)树脂快速分离铀与杂质元素、电感耦合等离子体质谱法(ICP-MS)测定杂质元素含量的系统流程。结果表明,UTEVA树脂对铀的吸附能力强,铀样品取样量为16.43 mg时,全流程对铀的去污因子大于3×105,9种杂质元素(锰钼镍铜铬铝钛钒镉)的回收率为95.1%~105.1%,国家标准物质GBW04205中杂质元素的分析结果与参考值在不确定度(k=2)范围内一致。本工作建立的分离流程对铀的去污效果好,特别适用于样品量少的情况下铀中杂质元素的分析,为核法证分析最终的归因溯源或燃料质量检验提供了技术支持。  相似文献   
78.
Deep‐water sediments in the Molasse Basin, Austria, were deposited in a narrow foreland basin dominated by a large channel belt located between the steep Alpine fold and thrust belt to the south and the gentler northern slope off the Bohemian Massif. Several gas fields occur outside the channel belt, along the outer bend of a large meander. Accumulation of these overbank sediments reflects a complicated interplay between slope accommodation and debris‐flow and turbidity‐flow interaction within the channel. The tectonically oversteepened northern slope of the basin (ca 2 to 3°) developed a regionally important erosional surface, the Northern Slope Unconformity, which can be traced seismically for >100 km in an east–west direction and >20 km from the channel to the north. The slope preserves numerous gullies sourced from the north that eroded into the channel belt. These gullies were ca 20 km long, <1 km wide and ca 200 m deep. As the channel aggraded, largely inactive and empty gullies served as entry points into the overbank area for turbidity currents within the axial channel. Subsequently, debris‐flow mounds, 7 km wide and >15 km long, plugged and forced the main channel to step abruptly ca 7 km to the south. This resulted in development of an abrupt turn in the channel pathway that propagated to the east and probably played a role in forming a sinuous channel later. As debris‐flow topography was healed, flows spread out onto narrow area between the main channel and northern slope forming a broad fine‐grained apron that serves as the main gas reservoir in this area. This model of the overbank splay formation and the resulting stratigraphic architecture within the confined basin could be applied in modern and ancient systems or for subsurface hydrocarbon reservoirs where three‐dimensional seismic‐reflection data is limited. This study elucidates the geomorphology of the oversteepened slope of the under‐riding plate and its effects on the sedimentation.  相似文献   
79.
Thin‐bedded delta‐front and prodelta facies of the Upper Cretaceous Ferron Notom Delta Complex near Hanksville in southern Utah, USA, show significant along‐strike facies variability. Primary initiation processes that form these thin beds include surge‐type turbidity currents, hyperpycnal flows and storm surges. The relative proportion of sedimentary structures generated by each of these depositional processes/events has been calculated from a series of measured sedimentological sections within a single parasequence (PS6–1) which is exposed continuously along depositional strike. For each measured section, sedimentological data including grain size, lithology, bedding thickness, sedimentary structures and ichnological suites have been documented. Parasequence 6–1 shows a strong along‐strike variation with a wave‐dominated environment in the north, passing abruptly into a fluvial‐dominated area, then to an environment with varying degrees of fluvial and wave influence southward, and back to a wave‐dominated environment further to the south‐east. The lateral facies variations integrated with palaeocurrent data indicate that parasequence 6–1 is deposited as a storm‐dominated symmetrical delta with a large river‐dominated bayhead system linked to an updip fluvial feeder valley. This article indicates that it is practical to quantify the relative importance of depositional processes and determine the along‐strike variation within an ancient delta system using thin‐bedded facies analysis. The wide range of vertical stratification and grading sequences present in these event beds also allows construction of conceptual models of deposition from turbidity currents (i.e. surge‐type turbidity currents and hyperpycnal flows) and storm surges, and shows that there are significant interactions and linkages of these often paired processes.  相似文献   
80.
Observed reduction in recent sea ice areal extent and thickness has focused attention on the fact that the Arctic marine system appears to be responding to global‐scale climate variability and change. Passive microwave remote‐sensing data are the primary source underpinning these reports, yet problems remain in geophysical inversion of information on ice type and concentration. Uncertainty in sea‐ice concentration (SIC) retrievals is highest in the summer and fall, when water occurs in liquid phase within the snow–sea‐ice system. Of particular scientific interest is the timing and rate of new ice formation due to the control that this form of sea ice has on mass, energy and gas fluxes across the ocean–sea‐ice–atmosphere interface. In this paper we examine the critical fall freeze‐up period using in situ data from a ship‐based and aerial survey programme known as the Canadian Arctic Shelf Exchange study combined with microwave and optical Earth observations data. Results show that: (1) the overall physical conditions observed from aerial survey photography were well matched with coincident moderate‐resolution imaging spectroradiometer data and Radarsat ScanSAR imagery; (2) the shortwave albedo was linearly related to old ice concentration derived from survey photography; (3) the three SSM/I SIC algorithms (NASA Team (NT), NASA Team 2 (NT2), and Bootstrap (BT)) showed considerable discrepancies in pixel‐scale comparison with the Radarsat ScanSAR SICs well calibrated by the aerial survey data. The major causes of the discrepancies are attributed to (1) the inherent inability to detect the new thin ice in the NT and BT algorithms, (2) mismatches of the thin‐ice tie point of the NT2 algorithm, and (3) sub‐pixel ambiguity between the thin ice and the mixture of open water and sea ice. These results suggest the need for finer resolution of passive microwave sensors, such as AMSR‐E, to improve the precision of the SSM/I SIC algorithms in the marginal ice zone during early fall freeze‐up. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   
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