High-T phase transition of synthetic ANaB(LiMg)CMg5Si8O22(OH)2 amphibole: an X-ray synchrotron powder diffraction and FTIR spectroscopic study     

Gianluca Iezzi  Mario Tribaudino  Giancarlo Della Ventura  Fabrizio Nestola  Fabio Bellatreccia 《Physics and Chemistry of Minerals》2005,32(7):515-523

The synthetic amphibole Na_0.95(Li_0.95Mg_1.05)Mg₅Si₈O₂₂(OH)₂ was studied in situ at high-T, using IR OH-stretching spectroscopy and synchrotron X-ray powder diffraction. At room-T the sample has P2₁ /m symmetry, as shown by the FTIR spectrum. It shows in the OH region two well-defined and intense absorptions at 3,748 and 3,712 cm⁻¹, respectively, and two minor bands at 3,667 and 3,687 cm⁻¹. The main bands are assigned to the two independent O–H groups in the primitive structure. The two minor bands evidencing the presence of small amount of vacant A-site (^A□_0.05). With increasing T, these bands shift continuously and merge into a unique absorption at high temperature. A change as a function of increasing T is revealed by the evolution of the refined unit-cell parameters, whose trend shows a transition to C2/m at about 320–330°C. The spontaneous scalar strain, fitted with a tricritical 2–6 Landau potential, gives a T _c of 325(10)°C (β parameter = 0.27). Comparison with the second-order P2₁ /m ⇔ C2/m phase transition at 255°C for synthetic amphibole ^ANa_0.8^B(Na_0.8Mg_1.2)^CMg₅Si₈O₂₂(OH)₂ indicates that the substitution of Na with Li at the B-sites strongly affects the thermodynamic character and the T _c of the phase transition. The comparison of LNMSH amphiboles with cummingtonitic ones shows that the high-T thermodynamic behaviour is affected by A-site occupancy.  相似文献   

The 17 March 2005 Kuzulu landslide (Sivas, Turkey) and landslide-susceptibility map of its near vicinity   总被引：3，自引：0，他引：3  

Candan Gokceoglu  Hakan A. Nefeslioglu  Tolga Can 《Engineering Geology》2005,81(1):65-83

Landslides are common natural hazards in the seismically active North Anatolian Fault Zone of Turkey. Although seismic activity, heavy rainfall, channel incisions, and anthropogenic effects are commonly the main triggers of landslides, on March 17, 2005, a catastrophic large landslide in Sivas, northeastern of Turkey, the Kuzulu landslide, was triggered by snowmelt without any other precursor. The initial failure of the Kuzulu landslide was rotational. Following the rotational failure, the earth material in the zone of accumulation exhibited an extremely rapid flow caused by steep gradient and high water content. The Agnus Creek valley, where Kuzulu village is located, was filled by the earth-flow material and a landslide dam was formed on the upper part of Agnus Creek. The distance from the toe of the rotational failure down to the toe of the earth flow measured more than 1800 m, with about 12.5 million m³ of displaced earth material. The velocity of the Kuzulu landslide was extremely fast, approximately 6 m/s. The main purposes of this study are to describe the mechanism and the factors conditioning the Kuzulu landslide, to present its environmental impacts, and to produce landslide-susceptibility maps of the Kuzulu landslide area and its near vicinity. For this purpose, a detailed landslide inventory map was prepared and geology, slope, aspect, elevation, topographic-wetness index and stream-power index were considered as conditioning factors. During the susceptibility analyses, the conditional probability approach was used and a landslide-susceptibility map was produced. The landslide-susceptibility map will help decision makers in site selection and the site-planning process. The map may also be accepted as a basis for landslide risk-management studies to be applied in the study area.  相似文献   

New magnetostratigraphic and pedostratigraphic investigations of loess deposits in north‐east China and their implications for regional environmental change during the Mid‐Pleistocene climatic transition          下载免费PDF全文

Lin Zeng  Huayu Lu  Shuangwen Yi  Yongxiang Li  Anqi Lv  Wenchao Zhang  Zhiwei Xu  Haifeng Wu  Han Feng  Mengchun Cui 《第四纪科学杂志》2016,31(1):20-32

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Diagnosing snow accumulation errors in a rain‐snow transitional environment with snow board observations          下载免费PDF全文

Nicholas E. Wayand  Martyn P. Clark  Jessica D. Lundquist 《水文研究》2017,31(2):349-363

Diagnosing the source of errors in snow models requires intensive observations, a flexible model framework to test competing hypotheses, and a methodology to systematically test the dominant snow processes. We present a novel process‐based approach to diagnose model errors through an example that focuses on snow accumulation processes (precipitation partitioning, new snow density, and snow compaction). Twelve years of meteorological and snow board measurements were used to identify the main source of model error on each snow accumulation day. Results show that modeled values of new snow density were outside observational uncertainties in 52% of days available for evaluation, while precipitation partitioning and compaction were in error 45% and 16% of the time, respectively. Precipitation partitioning errors mattered more for total winter accumulation during the anomalously warm winter of 2014–2015, when a higher fraction of precipitation fell within the temperature range where partition methods had the largest error. These results demonstrate how isolating individual model processes can identify the primary source(s) of model error, which helps prioritize future research.  相似文献   

A new standardized Palmer drought index for hydro‐meteorological use          下载免费PDF全文

Mingwei Ma  Liliang Ren  Fei Yuan  Shanhu Jiang  Yi Liu  Hao Kong  Luyan Gong 《水文研究》2014,28(23):5645-5661

Accepting the concept of standardization introduced by the standardized precipitation index, similar methodologies have been developed to construct some other standardized drought indices such as the standardized precipitation evapotranspiration index (SPEI). In this study, the authors provided deep insight into the SPEI and recognized potential deficiencies/limitations in relating to the climatic water balance it used. By coupling another well‐known Palmer drought severity index (PDSI), we proposed a new standardized Palmer drought index (SPDI) through a moisture departure probabilistic approach, which allows multi‐scalar calculation for accurate temporal and spatial comparison of the hydro‐meteorological conditions of different locations. Using datasets of monthly precipitation, temperature and soil available water capacity, the moisture deficit/surplus was calculated at multiple temporal scales, and a couple of techniques were adopted to adjust corresponding time series to a generalized extreme value distribution out of several candidates. Results of the historical records (1900–2012) for diverse climates by multiple indices showed that the SPDI was highly consistent and correlated with the SPEI and self‐calibrated PDSI at most analysed time scales. Furthermore, a simple experiment of hypothetical temperature and/or precipitation change scenarios also verified the effectiveness of this newly derived SPDI in response to climate change impacts. Being more robust and preferable in spatial consistency and comparability as well as combining the simplicity of calculation with sufficient accounting of the physical nature of water supply and demand relating to droughts, the SPDI is promising to serve as a competent reference and an alternative for drought assessment and monitoring. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

辽东湾海洋工程可靠性设计的海冰参数选取     

马玉贤  关湃  许宁  许有良  袁帅  刘永青  于福祥 《海洋工程》2019,37(3):136-142

海冰参数的合理取值是海洋工程海冰灾害风险评估的重要内容。利用1950—2018年的冰情等级(5个等级)数据,进行了1950—2018、1950—1990、1991—2018三种情景下的回归分析,确定了不同时期的冰情等级概率分布密度函数。利用鲅鱼圈雷达观测站2002—2017年的海冰现场实测资料,分别对鲅鱼圈附近海域一般冰厚、最大冰厚、最小冰厚进行概率分布拟合。基于上述概率分布结果,给出不同冰情等级的重现期,进而对海冰作业条件给出的设计参考值进行评价。结果表明:1990年以后2级、3级冰情重现期相对1990年之前变小,4级、5级冰情重现期相对1990年之前变大,规范给出重现期范围已不能代表辽东湾冬季海冰情况。本研究成果可为辽东湾海洋工程可靠性设计提供重要数据支撑。  相似文献   

Upper Cretaceous marine‐continental transition (Leonese Area,NW Spain) defined from integrated outcrop and seismic stratigraphy     

Antonio Herrero‐Hernndez  Fernando Gmez‐Fernndez  Francisco Javier Lpez‐Moro 《Geological Journal》2015,50(1):39-55

The Upper Cretaceous succession of the Leonese Area (NW Spain) comprises mixed clastic and carbonate sediments. This succession is divided into two lithostratigraphic units, the Voznuevo Member and the Boñar Formation, which represent fluvial, shoreface, intertidal, subtidal and open‐shelf sedimentary environments. Regional seismic interpretation and sequence stratigraphic analysis have allowed the study of lateral and vertical changes in the sedimentary record and the definition of third‐order levels of stratigraphic cyclicity. On the basis of these data, the succession can be divided into two second‐order depositional sequences (DS‐1 and DS‐2), incorporating three system tracts in a lowstand to transgressive to highstand system tract succession (LST–TST–HST). These sequences are composed of fluvial systems at the base with palaeocurrents that flowed westward and south‐westward. The upper part of DS‐1 (Late Albian–Middle Turonian) shows evidence of intertidal to subtidal and offshore deposits. DS‐2 (Late Turonian–Campanian) comprises intertidal to subtidal, tidal flat, shallow marine and lacustrine deposits and interbedded fluvial deposits. Two regressive–transgressive cycles occurred in the area related to eustatic controls. The evolution of the basin can be explained by base‐level changes and associated shifts in depositional trends of successive retrogradational episodes. By using isobath and isopach maps, the main palaeogeographic features of DS‐1 and DS‐2 were constrained, namely coastline positions, the existence and orientation of corridors through which fluvial networks were channelled and the location of the main depocentres of the basin. Sedimentation on the Upper Cretaceous marine platform was mainly controlled by (i) oscillations of sea level and (ii) the orientation of Mesozoic faults, which induced sedimentation along depocentres. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

2000～2015年会理县地表覆盖变化监测     

陈传华  陈阳  张云  李胜  李俊斌 《测绘与空间地理信息》2016,(11):110-114

以LandSat多时相影像为数据源,采用基于规则的面向对象分类方法,监测会理县2000～ 2015年地表覆盖变化.结合1∶50 000 DEM数据,分析了会理县地表覆盖构成与转移、变化动态度及潜在退耕地情况.监测分析结论能为会理县加强空间管制、促进土地资源集约利用、指导生态文明建设等提供决策信息支撑.  相似文献   

Scaling the Anthropocene: How the stories we tell matter     

《Geoforum》2016

Ongoing debates in the Earth, planetary, and social sciences examine the merits and implications of traces in the stratigraphic record that would indicate that humans are now one of the ‘great forces of nature’. Candidates for key marker horizons in such a stratal section include noted changes in carbon and nitrogen concentrations, plastics, radionuclides, and metals. Candidates for determining calendar age, include the tipping point in land cover from wildlands to agriculture and the first nuclear detonation. Here we offer a critical review of recent literature contributing to delineating an Anthropogenic stratum, by exploring their interpretation as initiating, sustaining, or indeed ending an Anthropocene epoch. We also offer a reflection on the layer not representing a new period, any more than, for instance, iridium marks a ‘meteoritic’ epoch between the Cretaceous and Palaeogene. We examine temporal scales for their accord with geological methods of definition and delineation, and for the opportunities and constraints each presents for understanding and responding to transformations in the Earth system. Our thesis is that increasingly fortified stances on the ‘right’ definition of the Anthropocene epoch follow traditions of linear and authoritarian historical accounts, and prevent discovering epistemes of human-environment interactions that are open for coexistence. The co-existence of many key transitions will sustain ongoing and fruitful deliberations over human-environment interactions that the Anthropocene proposal has initiated, promoting research that can work with the many scales, discourses, and narratives of environmental change.  相似文献   

岩石圈中水的临界奇异性——大规模成矿的根源     

胡宝群  王倩  王运  邱林飞  吕古贤  孙占学 《地质论评》2016,62(S1):307-308

水的临界奇异性是岩石圈中许多重大地质作用的关键和枢纽,有独特的地质意义、超乎常识。水在临界点发生二级相变,许多物理化学性质奇异性突变,特别是溶解行为和热压的突变,对成矿作用影响极大。  相似文献