催化动力学分光光度法测定痕量铜（Ⅱ）的研究     

《中国海洋大学学报(自然科学版)》2007,37(2):210-210

建立1种新的测定水体中痕量重金属元素铜的催化动力学光度分析方法。该方法是根据铜对过氧化氢氧化弱酸艳蓝（RAWL）的反应具有催化作用，利用固定时间法，测量Cu（Ⅱ）～RAWL—H2O2体系中弱酸艳蓝在λ=626nm处的吸光度的变化，从而得到铜的含量。实验得到的最佳反应条件是：反应介质为氢氧化钠-磷酸二氢钾，pH值选为7．20，弱酸艳蓝浓度为40g·L^-1，30％的过氧化氢0．50mL，反应温度为（80．0±0．1）℃，反应时间为20min。该方法的线性范围是0～12ng·mL^-1，检出限是0．0105ng·mL^-1对2ng·mL^-1和8ng·mL^-1铜（Ⅱ）溶液5次测定的相对标准偏差分别为3．2％和2．3％。多种离子不干扰铜的测定，将本方法用于自来水，黄河水中铜（Ⅱ）的测定，标准加入回收率分别为99．15％和1033o,6．  相似文献   

Ekman螺线的动力学结构     

纪文君  王卫强 《台湾海峡》2002,21(3):340-343

介绍了Ekman螺线的动力学结构 ,分析研究了风应力及海水内部的动量传递形式 .结果表明 :动量传递方向与海流方向成 45°左偏 .这对于研究海洋内部的动力结构是有意义的 .  相似文献   

薛家岛湾沉积动力学特征及海港开发研究   总被引：3，自引：0，他引：3  

李凡  林宝荣  吴永成  王从敏 《海洋与湖沼》1994,25(4):452-457

于１９９０年秋对胶州湾内的薛家岛湾进行海洋水动力条件及积动力学特征,泥沙运动规律研究,为开发建设港口提供科学依据。结果表明,湾内深大于１ｍ的海底泥沙发生“全面移动”的时间,一年内仅有１－２ｄ,其余处于稳定状态或“表面移动”状态。湾内泥沙来源很少,预计建港后,港池和航道年平均回淤量分别小于１６ｃｍ,１０ｃｍ对于开发中小型港口十分有利。  相似文献   

莺歌海盆地形成与演化的动力学机制   总被引：4，自引：0，他引：4  

孙向阳  任建业 《海洋地质与第四纪地质》2003,23(4):45-50

莺歌海盆地位于印支半岛与南海北部大陆边缘交接区,复杂的地质构造背景使其形成演化的动力学机制成为国内外的研究焦点。从区域动力学演化的角度,系统分析了影响莺歌海盆地发育的印支地块构造演化特征,认为莺歌海盆地构造演化主要受印支半岛早期的逃逸挤出构造和晚期的挤压-伸展构造系统影响(或控制),在此动力学驱动机制下,莺歌海盆地新生代以来的构造演化经历了3个阶段,即左旋走滑-伸展裂陷阶段、中下地壳韧性伸展-热沉降阶段和加速沉降阶段。  相似文献   

Modeling of the eddy viscosity by breaking waves     

ZHANG Shuwen  YUAN Yeli  ZHENG Quan''an 《海洋学报(英文版)》2007,26(6):116-123

Breaking wave induced nearsurface turbulence has important consequences for many physical and biochemical processes including water column and nutrients mixing,heat and gases exchange across air-sea interface.The energy loss from wave breaking and the bubble plume penetration depth are estimated.As a consequence,the vertical distribution of the turbulent kinetic energy(TKE),the TKE dissipation rate and the eddy viscosity induced by wave breaking are also provided.It is indicated that model results are found to be consistent with the observational evidence that most TKE generated by wave breaking is lost within a depth of a few meters near the sea surface.High turbulence level with intensities of eddy viscosity induced by breaking is nearly four orders larger than υwl(=κuwz),the value predicted for the wall layer scaling close to the surface,where uw is the friction velocity in water,κ with 0.4 is the von Kármán constant,and z is the water depth,and the strength of the eddy viscosity depends both on wind speed and sea state,and decays rapidly through the depth.This leads to the conclusion that the breaking wave induced vertical mixing is mainly limited to the near surface layer,well above the classical values expected from the similarity theory.Deeper down,however,the effects of wave breaking on the vertical mixing become less important.  相似文献   

Ecopath with Ecosim在水生生态系统研究中的应用   总被引：5，自引：0，他引：5  

宋兵  陈立侨  Chen Yong 《海洋科学》2007,31(1):83-86

地球上的水体为人类提供着无法计量的生态系统服务和相应的生态价值。然而,水生生态系统一直承受着巨大的捕捞和环境压力。为更好地分析人类以及自然扰动对水生生态系统的影响,并建立科学合理的管理机制,许多研究种群结构和动态的模型软件以  相似文献   

Probabilistic Models for the Probability of Wave Breaking and Whitecap Coverage Based on Kinematic Breaking Criterion     

郑桂珍  徐德伦 《中国海洋工程》2004,18(3):357-370

More and more researches show that neither the critical downward acceleration nor the critical slope of water waves is a universal constant. On the contrary, they vary with particular wave conditions. This fact moders the models either for the probability of wave breaking B or for the whitecap coverage W based on these criteria difficult to apply. In this paper and the one which follows we seek to develop models for the prediction of both B and W based on the kinematical criterion. First, several joint probabihstic distribution functions (PDFs) of wave characteristics are derived, based on which the breaking properties B and W are estimated. The estimation is made on the assumption that a wave breaks ff the horizontal velocity of water particles at its crest exceeds the local wave celerity, and whitecapping occurs in regions of fluid where water particles travel faster than the waves. The consequent B and W depend on wave spectral moments of orders 0 to 4.Then the JONSWAP spectrum is used to represent the fetch-limited sea waves in deep water, so as to relate the probahility of wave breaking and the whitecap coverage with wind parameters. To this end, the time-averaging technique proposed by Glazman (1986) is applied to the estimation of the spectral moments involved, and furthermore, the theoretical models are compared with available observations collected from published literature. From the comparison, the averaging time scale is determined. The final models show that the probability of wave breaking as well as the whitecap coverage depends on the dimensionless fetch. The agreement between these models and the database is reasonable.  相似文献   

Analysis of Dynamic Characteristics of Submarine Free Spanning Pipelines by Complex Damping Method   总被引：2，自引：0，他引：2  

傅强郭海燕  杨新华 《中国海洋工程》2004,18(3):485-491

Considering the effect of the internal flowing fluid and the external marine environmental condition, the differential equation for the vortex-induced vibration (V1V) of the free spanning pipeline is derived and is discretized by the Hermit interpolation function. The free vibration equation with the damping term is solved by the complex damping method for the natural frequency, and then the effect of fluid damping on the natural frequency of the free spanning pipeline is analyzed.The results show that fluid damping has a significant influence on the damped natural frequency of the free spanning pipeline in the lock-in state, while it has little influence when the pipeline is out of the lock-in state. In the meantime,the change of the free span length has the same effect on the damped natural frequency and the undamped natural frequency.  相似文献   

气候变化中海洋和冰冻圈的变化、影响及风险     

王慧  刘秋林  李文善  潘嵩  李琰  王爱梅  徐浩  吕江华 《海洋通报》2020,39(2):143-151

本文系统梳理了IPCC 《气候变化中的海洋和冰冻圈特别报告》(SROCC)的主要结论,并对主要观点进行了解读。报告主要关注全球变暖背景下高山、极地、海洋和沿海地区现在和未来的变化及其对人类和生态系统的影响,以及实现气候适应发展路径的方案。在全球变暖背景下,冰冻圈大面积萎缩,冰川冰盖质量损失,积雪减少,北极海冰范围和厚度减小,多年冻土升温,全球海洋持续增温,1993年以来,海洋变暖和吸热速度增加了一倍以上。同时,海洋表面酸化加剧,海洋含氧量减少。全球平均海平面呈加速上升趋势,2006—2015年全球海平面上升速率为3.6 mm/yr,是1901—1990年的2.5倍,但存在区域差异。高山、极地和海洋的生态系统的物种组成、分布和服务功能均发生变化,并对人类社会产生了显著负面影响。极端海洋气候事件发生频率增多,强度加大。1982年以来,全球范围内海洋热浪的发生频率增加了一倍,且范围更广,持续时间更长。海平面持续上升加剧了洪涝、海水入侵、海岸侵蚀等海岸带灾害,并影响沿海生态系统。海洋及冰冻圈的变化及其影响在未来一定时期仍将持续,应对这些影响而面临的挑战,应加强基于生态系统的适应和可再生能源管理,强化海岸带地区的海平面上升综合应对,打造积极有效、可持续和具有韧性的气候变化应对方案。  相似文献   

从海岛生态系统和自然资源的特殊性谈海岛立法的必要性   总被引：1，自引：0，他引：1  

穆治霖 《海洋开发与管理》2007,24(2):44-46

海岛往往远离大陆,具有特殊的地理位置,其生态系统脆弱,自然资源独特,目前尚无专门的法律予以规范,而其具有的这些明显区别于陆地环境的特征决定了对海岛的保护与利用不能仅靠传统环境保护法律的一般性规定,必须进行专门立法以解决当前海岛保护与利用工作中存在的诸多问题。  相似文献