Heavy Metal Load of Sediments of the River Gurk (Carinthia/Austria) — Merits and Limitations of Sequential Leaching Schwermetallbelastung des Sediments der Gurk in Kärnten — Vorzüge und Einschränkungen sequentieller Löseverfahren     

M. Sager  W. Vogel 《洁净——土壤、空气、水》1993,21(1):21-32

By means of the analysis of sediments cored in the small river Gurk (Carinthia/Austria), the input of Ag, Cd, Ce, Cr, Hg, La, Mo, Ni, V, and W from a chemical industrial plant could be detected. To estimate the actual load, and to obtain data for comparison with other sites, both unsieved fine sediments and sediments sieved to 20 μm were investigated from the same cores. Environmental mobilities of toxic heavy metals (Co, Cr, Cu, Ni, Zn) have been shown by sequential leaching following Tessier/Förstner. In the last step, HNO₃ leaches a purely geogenic fraction, which is fairly constant along the investigated river. Whereas the additional Cr from the input of the chemical plant is mainly found in the oxalate-leachable fraction, short-time-load to unpolluted sediments in the laboratory is found mainly in hydroxylamine/acetic acid. Both is due to the high affinity of Cr to Fe- and Mn-oxides. Adsorption/desorption experiments reveal that the low carbonate content of the Gurk sediments increases the importance of Fe/Mn-oxides for the sorption of Cr compared to other samples containing carbonate. The Ni-load was primarily found in weak-acid-leachable and oxalate-leachable fractions. Similarly, the oxalate-leachable fraction is dominant for adsorption of other metals and phosphorus. Other interelement relationships among the amounts leached, which are attributable partly to carbonate-, silicate-, organic or coating phases, have been found by means of factor analyses together with marker fractions for each type.  相似文献   

ICP-MS测定土壤中的As、Cr、Pb、Se、Cu和Zn   总被引：1，自引：0，他引：1  

万飞  张之鑫 《吉林地质》2010,29(3):90-91,94

本文用电感耦合等离子质谱法(ICP-MS)测定了土壤的As、Cr、Pb、Se、Cu和Zn6种微量元素的质量分数,以In作为内标进行基体效应的补偿,方法快速灵敏,回收率为92.4%～106.8%,相对标准偏差小于5.0%,结果达到国家标准要求。  相似文献   

青海省海北化工厂Cr~(6+)污染调查评价与治理     

安勇  刘丽峰  保善磊  张永艳 《地质与资源》2014,23(4):408-413

海北化工厂已停产15年之久,但Cr6+污染依旧十分严重.调查得知,海北化工厂原生产废液排放及堆存废渣经降水淋滤作用下渗,是造成该区包气带和地下水Cr6+污染的主要原因.采用地下水质量法和污染指数法评价分析该区地下水Cr6+污染范围和污染影响程度.评价结果显示:Cr6+重度污染区面积0.75 km2,厂区包气带Cr6+平均含量67.67×10-6,平均超标指数1691.75,地下水中Cr6+浓度超过Ⅴ类水标准.在分析厂区周边水文地质条件的基础上,提出清除场地废渣废料并置换被污染的包气带、采用抽水法治理被污染的地下水的综合方案.  相似文献   

Cultural characteristics of chromium resistant unicellular cyanobacteria isolated from local environment in Pakistan     

Abdul Hameed Shahida Hasnain 《中国海洋湖沼学报》2005,23(4):433-441

Many unicellular cyanobacteria were isolated from different places： fields, ponds, polluted water, and soils from Muredkey and Kasur tannery areas, near Lahore, Pakistan. Different media like BG 11 medium, Bold Basal medium, Chu＇s # 10 medium and Gotham＇s medium, in standard forms and with slight variations of ingredients, and different pH, temperature and light regimes were checked for the optimum growth of the isolates. The isolation pro- cedure was repeated with different concentrations of chromium to select the resistant strains. These selected strains grew on chromium of the range 100-200 μg/ml in BG 11 medium. Cyanobacteria were maintained in solid and liquid media with/without shaking. Cyanobacterial strains were collected from natural habitats that were accompanied by a diversified group of organisms including bacteria, protozoan, and rotifers etc. In order to eliminate these agents termed as contaminants, we used several methods including phenol treatment, use of antibiotic and careful manual picking of unicellular cyanobacteria. Resistance of these strains against different heavy metals （ZnSO4, MnSO4, NiSO4, COCl2, Pb（NO3）3, CuSO4, HgCl2, AgNO3 and CdCl2） and antibiotics （erythromycin, streptomycin, kanamycin, chloramphenicol, neomycin） was evaluated. Optimum temperature was 30℃ with variable pH for the reduction of Cr^6＋ in to Cr^3＋ in majority of strains.  相似文献   

P–T–t evidence for mechanisms of vertical tectonic motion in a contractional orogen: north-western US and Canadian Cordillera     

Whitney  Miller  & Paterson 《Journal of Metamorphic Geology》1999,17(1):75-90

The >1800 km long Coast Mountains–North Cascades orogen of the Canadian Cordillera and north-western US developed as a continental magmatic arc. Metamorphic rocks in the orogen contain widespread evidence for burial of supracrustal rocks to depths of c. 40 km, followed by nearly isothermal decompression to depths of <10 km. Near many shallowly-emplaced, mid-Cretaceous plutons, low-pressure contact metamorphic effects were overprinted by high-pressure regional metamorphic minerals and textures, as evidenced by kyanite±staurolite pseudomorphs after andalusite in metapelitic rocks. Therefore, near-pluton rocks record the loading history of the orogen. Metapelitic rocks not associated with plutons only preserve evidence for high-pressure conditions and/or high-temperature decompression, as indicated, for example, by sillimanite and cordierite after kyanite and garnet, respectively. Petrological evidence for burial and decompression is therefore recorded in different rocks. Various regions of the orogen differ in timing of metamorphism, the overall shape of P–T paths and the relative timing and regional extent of the high-pressure event, but most of these data and observations are consistent with thrusting and/or pure shear thickening as primary loading mechanisms throughout the orogen, as opposed to magma-dominated loading. This interpretation is further supported by comparison with thermal models, which demonstrate that the P–T paths are consistent with simultaneous thrusting and folding at a high initial geothermal gradient (35–40 °C km^?1) in much of the orogen. A high geothermal gradient supports tectonic models invoking intra-arc contraction and suggests that magmatism played an important role in regional temperature-time paths. This tectonic-thermal history may be typical of other contractional orogens and illustrates the importance of large vertical displacement of crust in magmatic arcs.  相似文献   

Transformation of ammonium nitrogen and response characteristics of nitrifying functional genes in tannery sludge contaminated soil          下载免费PDF全文

Kong Xiang-ke  Zhang Zi-xuan  Wang Ping  Wang Yan-yan  Zhang Zhao-ji  Han Zhan-tao  Ma Li-sha 《地下水科学与工程》2022,10(3):223-232

High concentrations of ammonium nitrogen released from tannery sludge during storage in open air may cause nitrogen pollution to soil and groundwater. To study the transformation mechanism of NH₄⁺-N by nitrifying functional bacteria in tannery sludge contaminated soils, a series of contaminated soil culture experiments were conducted in this study. The contents of ammonium nitrogen (as NH₄⁺-N), nitrite nitrogen (as NO₂^?-N) and nitrate nitrogen (as NO₃^?-N) were analyzed during the culture period under different conditions of pollution load, soil particle and redox environment. Sigmodial equation was used to interpret the change of NO₃^?-N with time in contaminated soils. The abundance variations of nitrifying functional genes (amoA and nxrA) were also detected using the real-time quantitative fluorescence PCR method. The results show that the nitrification of NH₄⁺-N was aggravated in the contaminated silt soil and fine sand under the condition of lower pollution load, finer particle size and more oxidizing environment. The sigmodial equation well fitted the dynamic accumulation curve of the NO₃^?-N content in the tannery sludge contaminated soils. The Cr(III) content increased with increasing pollution load, which inhibited the reproduction and activity of nitrifying bacteria in the soils, especially in coarse-grained soil. The accumulation of NO₂^?-N contents became more obvious with the increase of pollution load in the fine sand, and only 41.5% of the NH₄⁺-N was transformed to NO₃^?-N. The redox environment was the main factor affecting nitrification process in the soil. Compared to the aerobic soil environment, the transformation of NH₄⁺-N was significantly inhibited under anaerobic incubation condition, and the NO₃^?-N contents decreased by 37.2%, 61.9% and 91.9% under low, medium and high pollution loads, respectively. Nitrification was stronger in the silt soil since its copy number of amoA and nxrA genes was two times larger than that of fine sand. Moreover, the copy numbers of amoA and nxrA genes in the silt soil under the aerobic environment were 2.7 times and 2.2 times larger than those in the anaerobic environment. The abundance changes of the amoA and nxrA functional genes have a positive correlation with the nitrification intensity in the tannery sludge-contaminated soil.  相似文献   

沈阳市新城子铬渣堆存区土壤铬污染分布及形态研究          下载免费PDF全文

惠秀娟  孟雪莲  徐成斌  马溪平  付保荣 《气象与环境学报》2009,25(6):64-67

采用 Tessier A连续提取法研究分析了沈阳市新城子铬渣堆存区土壤中重金属铬的污染分布和迁移转化规律。结果表明：土壤中重金属铬的5 种形态分布, 主要以残渣态和碳酸盐结合态为主,分别占总量的49.74%和21.40%,而有机结合态含量最低,占总铬含量的6.25%。不同的功能区域铬的形态分布有所不同。总体的分布特征是残渣态大于碳酸盐结合态大于交换态大于铁锰氧化态大于有机态。  相似文献   

Chromium speciation in oxide-type compounds: application to minerals,gems, aqueous solutions and silicate glasses     

François Farges 《Physics and Chemistry of Minerals》2009,36(8):463-481

Cr K-edge XANES spectra were obtained for a variety of Cr-bearing model compounds containing Cr(II), Cr(III), Cr(IV), Cr(V) and Cr(VI), in which the Cr-site symmetry is D4h, Oh and Td. The centroid position of the pre-edge feature is a better indicator of the Cr valence than the edge position. In Cr-rich oxides, higher-energy transitions must be excluded in order to refine a robust valence for Cr. The pre-edge for chromates is not unique and varies as a function of the CrO₄ ^2? moiety distortion, which is often related to Cr-polymerization (monochromate vs. dichromate). Both the analogy with the Mn K-pre-edge information and ab initio FEFF calculations of the pre-edge feature for Cr(III) and Cr(VI) confirm the experimental trends. This methodology is applied to the Cr K-edge pre-edge feature collected in gems (emerald, spinel and ruby), the layered minerals fuchsite and kämmererite, two Cr-bearing aqueous solutions and a set of sodo-calcic silicate glasses used for bottling sparkling white wine. In emerald and fuchsite, the Cr-site is differently distorted than its ruby or spinel counterpart. In a Cr(III)-bearing aqueous solution and sodo-calcic glass, no evidence for Cr(III) with Td and C3v symmetry is detected. However, minor amounts of chromate moieties (most likely monomeric) are detected in a glass synthesized in air. Preliminary spectra for the wine bottle glass suggest that only trace amounts of chromates might possibly be present in these glasses.  相似文献   

西藏雅鲁藏布江缝合带中段仁布豆荚状铬铁矿成因及构造意义     

杨胜标  李源  杨经绥  巴登珠  薄容众  李瑞保  刘成军  熊发挥  曹楚奇 《地质学报》2022,96(2):533-553

藏南雅鲁藏布江缝合带为目前国内铬铁矿储量最大的缝合带.本文报道了缝合带中段仁布蛇绿岩的豆荚状铬铁矿床,围绕矿床特征开展成因探讨,对缝合带的形成演化和成矿作用提供新制约.仁布蛇绿岩呈近东西走向带状产出,主要由近30个大小不等的地幔橄榄岩体组成.地幔橄榄岩体主要为经历不同程度蛇纹石化的方辉橄榄岩和少量纯橄岩.在纯橄岩和方辉...  相似文献   

几种重金属对青岛文昌鱼毒性及生长的影响   总被引：24，自引：1，他引：23  

吴贤汉  江新霁  张宝录  曲艳梅 《海洋与湖沼》1999,30(6):604-608

对１９９１年８月在青岛崂山沙子口海区底层沙中拖网采集的体长为１．８￣２．２ｃｍ的青岛文昌鱼,进行不同剂量的Ｃｕ＾２＋、Ｚｎ＾２＋、Ｃｒ＾６＋等重金属的毒性影响实验,结果表明,青岛文昌鱼对重金属反应敏感,重金属如超过一定浓度便可起文晶鱼中毒乃至死亡,但微量的重金属则能促进文昌鱼的生长。  相似文献