Determination of High Field Strength Elements, Rb, Sr, Mo, Sb, Cs, Tl and Bi at ng g⁻¹ Levels in Geological Reference Materials by Magnetic Sector ICP-MS after HF/HClO₄ High Pressure Digestion     

Zongshou Yu  Philip Robinson  Ashley T. Townsend  Carsten Mnker  Anthony J. Crawford 《Geostandards and Geoanalytical Research》2000,24(1):39-50

Six low abundance rock reference materials (basalt BIR-1, dunite DTS-1, dolerite DNC-1, peridotite PCC-1, serpentine UB-N and basalt TAFAHI) have been analysed for high field strength elements (Zr, Nb, Hf, Ta, Th and U), Rb, Sr, Mo, Sb, Cs, Tl and Bi at ng g⁻¹ levels (in rock) by magnetic sector inductively coupled plasma-mass spectrometry after HF/HClO₄ high pressure decomposition. The adopted method uses only indium as an internal standard. Detection limits were found to be in the range of 0.08 to 16.2 pg ml⁻¹ in solution (equivalent to 0.08 to 16.2 ng g⁻¹ in rock). Our data for high field strength elements, Rb, Sr, Mo, Sb, Cs, Tl and Bi for the six selected low abundance geological reference materials show general agreement with previously published data. Our Ta values in DTS-1 and PCC-1 (1.3 and 0.5 ng g⁻¹) are lower than in previously published studies, providing smooth primitive mantle distribution patterns. Lower values were also found for Tl in BIR-1, DTS-1 and PCC-1 (2, 0.4 and 0.8 ng g⁻¹). Compared with quadrupole ICP-MS studies, the proposed magnetic sector ICP-MS method can generally provide better detection limits, so that the measurement of high field strength elements, Rb, Sr, Mo, Sb, Cs, Tl and Bi at ng g⁻¹ levels can be achieved without pre-concentration, ion exchange separation or other specialised techniques.  相似文献   

Determination of the REE in Geological Reference Materials DTS-1 (Dunite) and PCC-1 (Peridotite) by Ultrasonic and Microconcentric Desolvating Nebulisation ICP-MS     

Jinesh C. Jain  M. Paul Field  Clive R. Neal  James C. Ely  Robert M. Sherrell 《Geostandards and Geoanalytical Research》2000,24(1):65-72

Inductively coupled plasma-mass spectrometry is well suited for the precise, accurate and rapid determination of rare earth elements in most geological samples. However, determination of rare earth elements in certain mantle-derived materials, without applying preconcentration techniques, remains problematical due to low natural concentrations (generally < 1 ng g⁻¹). Consequently, USGS reference materials DTS-1 (a dunite) and PCC-1 (a partially serpentinized harzburgite) have only suggested rather than recommended values for the rare earth elements in reference material compilations. We compared results obtained using two ICP-MS instruments: a U-5000AT ultrasonic nebuliser coupled to a PQ2+ quadrupole ICP-MS and an ELEMENT sector field ICP-MS equipped with a MCN-6000 microconcentric desolvating nebuliser, with the suggested literature values for these two reference materials. Precision and accuracy of analytical methods employed by both instruments were demonstrated by excellent relative standard deviations (< 2%) and inter-laboratory agreement (< 5%) for numerous analyses of BHVO-1 and BIR-1, which are well established with rare earth elements contents at the μg g⁻¹ level. Repeat analyses of DTS-1 and PCC-1 at each laboratory indicate that each method is generally precise to better than 5% at sub-g g⁻¹ levels. Furthermore, values from both instruments generally agree to within 10%. Our DTS-1 and PCC-1 values agree reasonably well with selected data reported in the literature (except for Ce and Sm in DTS-1) but exhibit poorer agreement with reported compilation values. With the demonstrated level of precision and accuracy, we contend that these new values for DTS-1 and PCC-1, generated by two different instruments, are the best estimates of the true whole-rock composition of these samples reported to date.  相似文献   

基于多灰度共生矩阵特征值的黄渤海白天海雾识别算法     

谢涛  郎紫晴  冉茂农  赵立 《气象科学》2024,44(1):189-198

本文基于多灰度共生矩阵特征值,即相关性、对比度、同质性和能量,进行联合海雾遥感判识,提出一种高准确率黄渤海白天海雾识别算法。采用第二代静止气象卫星FY-4A可见光、近红外和红外数据,将该算法应用于黄渤海区域白天海雾判识,并利用2019—2020年沿黄渤海气象站点能见度实测数据及CALIPSO卫星数据产品对本算法识别结果进行精度验证。结果表明：海雾识别平均检测率(POD)为92%,误报率(FAR)为27%,临近成功指数(CSI)为69%,可以实现对海雾的动态监测,为海上交通等领域提供较好的数据支持。  相似文献   

用非等时距序列灰色模型预测粉喷桩的承载力   总被引：4，自引：0，他引：4  

张建新  谭燕秋  杜海金 《岩土力学》2002,23(6):757-759

针对粉喷桩单桩承载力具有随时间增长而增大的现象,运用灰色理论,建立了非等时距预测GM（1, 1）模型,对粉喷桩承载力进行了预测,并取得了很好的效果。通过实测值与预测值的分析,认清了粉喷桩承载力的时效性规律及变化趋势,提出了进行粉喷桩单桩载荷试验的适宜时间。  相似文献   

星载高光谱Hyperion数据在海滩涂调查应用中的分析   总被引：3，自引：0，他引：3  

唐伯惠姜小光  唐伶俐习晓环 戴昌达 《地球信息科学学报》2004,6(2):81-87

以江苏苏北地区为研究区,较系统地分析了目前世界上星载传感器中光谱分辨率最高的EO-1卫星Hyperion数据的基本特点和处理方法,研究了将图像的灰度值转变为辐射能量值和反射率的方法和步骤,并选取了15类典型地物,进行了样本采集、辐射亮度和反射率反演,最后对典型地物的光谱曲线进行综合分析研究,并概括了苏北沿海滩涂典型地物的基本光谱特征。  相似文献   

安徽巢湖煤田控矿构造雏论     

朱君星 《煤田地质与勘探》2004,32(2):4-6

采用现代构造几何分析方法,研究了巢湖煤田的控煤构造,发现巢湖煤田主要受大型平卧式褶皱逆冲推覆构造控制。按构造变形特点从南到北可以划分为和县-含山平卧式褶皱推覆构造、巢湖银屏山平卧式褶皱推覆构造和无为平卧式褶皱推覆构造 3个构造带,卷入了震旦系灯影组-三叠系的整个扬子海相沉积盖层。这种大规模的褶皱逆冲推覆是扬子板块沿着郯庐断裂向华北板块A型俯冲的产物。   相似文献   

以控制地面沉降为约束的地下水资源评价——以上海地区为例   总被引：2，自引：0，他引：2  

张卫  覃小群  易连兴  林玉山 《中国岩溶》2004,23(3):196-205

以上海市区第V承压含水层(埋深约350m )以上的整个第四系松散沉积层为研究体,将上海地下水系统作为一个完整且不可分割的系统来研究。由于开采地下水资源引起地下水系统内部物质能量变化,因而产生一系列的环境地质问题(如地面沉降、地下水位下降、资源开采条件恶化等)。根据研究区地下水系统特征和已有的研究程度,在技术方法和途径上,着重研究上海地区第四系含水层结构、水文地质工程地质条件,建立水文地质工程地质概念模型; 在此基础上建立以地下水资源开采量最大、水位降幅及地面沉降较小、社会经济效益较好为目标的地下水拟三维渗流一维地面沉降的评价与管理模型,并为我国大中城市(特别是在诸如开采地下水引起的地面沉降问题的地区)的地下水资源评价与管理提供可借鉴的经验和方法。   相似文献   

Impact of 1/8° to 1/64° resolution on Gulf Stream model–data comparisons in basin-scale subtropical Atlantic Ocean models     

Harley E. Hurlburt  Patrick J. Hogan 《Dynamics of Atmospheres and Oceans》2000,32(3-4)

We investigate the impact of 1/8°, 1/16°, 1/32°, and 1/64° ocean model resolution on model–data comparisons for the Gulf Stream system mainly between the Florida Straits and the Grand Banks. This includes mean flow and variability, the Gulf Stream pathway, the associated nonlinear recirculation gyres, the large-scale C-shape of the subtropical gyre and the abyssal circulation. A nonlinear isopycnal, free surface model covering the Atlantic from 9°N to 47°N or 51°N, including the Caribbean and Gulf of Mexico, and a similar 1/16° global model are used. The models are forced by winds and by a global thermohaline component via ports in the model boundaries. When calculated using realistic wind forcing and Atlantic model boundaries, linear simulations with Munk western boundary layers and a Sverdrup interior show two unrealistic mean Gulf Stream pathways between Cape Hatteras and the Grand Banks, one proceeding due east from Cape Hatteras and a second one continuing northward along the western boundary until forced eastward by the regional northern boundary. The northern pathway is augmented when a linear version of the upper ocean global thermohaline contribution to the Gulf Stream is added as a Munk western boundary layer. A major change is required to obtain a realistic pathway in nonlinear models. Resolution of 1/8° is eddy-resolving but mainly gives a wiggly version of the linear model Gulf Stream pathway and weak abyssal flows except for the deep western boundary current (DWBC) forced by ports in the model boundaries. All of the higher resolution simulations show major improvement over the linear and 1/8° nonlinear simulations. Additional major improvement is seen with the increase from 1/16° to 1/32° resolution and modest improvement with a further increase to 1/64°. The improvements include (1) realistic separation of the Gulf Stream from the coast at Cape Hatteras and a realistic Gulf Stream pathway between Cape Hatteras and the Grand Banks based on comparisons with Gulf Stream pathways from satellite IR and from GEOSAT and TOPEX/Poseidon altimetry (but 1/32° resolution was required for robust results), (2) realistic eastern and western nonlinear recirculation gyres (which contribute to the large-scale C-shape of the subtropical gyre) based on comparisons with mean surface dynamic height from the generalized digital environmental model (GDEM) oceanic climatology and from the pattern and amplitude of sea surface height (SSH) variability surrounding the eastern gyre as seen in TOPEX/Poseidon altimetry, (3) realistic upper ocean and DWBC transports based on several types of measurements, (4) patterns and amplitude of SSH variability which are generally realistic compared to TOPEX/Poseidon altimetry, but which vary from simulation to simulation for specific features and which are most realistic overall in the 1/64° simulation, (5) a basin wide explosion in the number and strength of mesoscale eddies (with warm core rings (WCRs) north of the Gulf Stream, the regional eddy features best observed by satellite IR), (6) realistic statistics for WCRs north of the Gulf Stream based on comparison to IR analyses (low at 1/16° resolution and most realistic at 1/64° resolution for mean population and rings generated/year; realistic ring diameters at all resolutions), and (7) realistic patterns and amplitude of abyssal eddy kinetic energy (EKE) in comparison to historical measurements from current meters.  相似文献   

发窝构造油气潜力评价     

梁秋原 《云南地质》2000,19(4):433-442

云龙凹陷地处楚雄盆地东部浅坳陷区,面积１４６４ｋｍ＾２,由于具有良好的石油地质条件而被各方所瞩目。发窝构造位于云龙凹陷中部断弯构造带,南高点为断背斜,北高点为断鼻,云参１井位于云龙凹陷发窝构造南高点,从区域石油地质条件入手,结合地震勘探成果,含油气性剖面研究、区带评价及圈闭评价资料,论述了发窝构造的油气潜力,对云参１井钻探的可行性进行分析研究,肯定了钻探的可行性及必要性,也对钻探的风险进行分析。  相似文献   

SD-3A自动测氡仪山东网逸出氡资料分析与研究   总被引：4，自引：0，他引：4  

邢玉安  张平  武建华  王华  张壮峰  魏汝庆  王长喜  周斌  吴春华 《华北地震科学》2000,18(2):12-17

对ＳＤ－３Ａ自动测氡仪在山东试验台网运行期间取得的连续逸出氡观测资料进行了全面深入的分析研究,同时为了说明ＳＤ－３Ａ仪器观测逸出氡资料的一致性和可靠性,用ＦＤ－１０５Ｋ和ＦＤ－１２５测氡仪与ＳＤ－３Ａ同时取１００ｍｌ水样进行人工观测,其所测的氡浓度一致,之后又同时聚逸出氡气样进行观测,所测逸出氡浓度也一致,证明仪器的观测结果是可靠的。说明试验观测期间获得的１９９８年１１月初逸出气氡大幅度高值异常是  相似文献