Adsorption–Reduction Behavior of Co(NH3) on Activated Carbon     

Yan‐Peng Mao  Yu Chen  Jing‐Yi Cheng  Hai‐Song Zhu  Xiang‐Li Long  Wei‐Kang Yuan 《洁净——土壤、空气、水》2012,40(2):117-122

A novel method has been put forward to retrofit the wet ammonia desulfurization process to realize the combined removal of sulfur dioxide and nitric oxide by introducing soluble cobalt(II) salt into aqueous ammonia solution. The active constituent of scrubbing NO from the flue gases is the produced by ammonia coordinating with Co²⁺. The regeneration of can be realized under the catalysis of activated carbon so as to sustain a high NO removal efficiency for a long time. In this paper, the adsorption–reduction behavior of on activated carbon has been researched using scanning electron microscopy, X‐ray diffraction, and X‐ray photoelectron spectroscopy. A conclusion can be drawn from the results that cobalt ions in the aqueous solution are adsorbed by activated carbon and most of them are reduced to Co²⁺ ions, and some of the Co²⁺ ions are further reduced into metallic cobalt. The results also demonstrate that the functional groups on the surface of carbon take part in this redox reaction. The C? H groups on the carbon surface are oxidized into C? OH, and then some of the hydroxyl groups are further oxidized into carbonyl or carboxyl groups.  相似文献   

甜水海钻孔TS95若干地球化学指标的非线性分析与意义   总被引：1，自引：0，他引：1  

周厚云  朱照宇  李世杰  李炳元  向明菊  余素华 《湖泊科学》2001,13(2):97-102

应用关联维分析和R／S分析对西昆伦甜水海孔TS95的4项指标（FeO,Fe2O3,Fe2O3/FeO和有机碳）进行分析,发现它们存在明显的混沌特征和Hurst现象,4项指标的混沌吸引子分别为：FeO－2．8;Fe2O3－3．2;Fe2O／FeO－2．9;有机碳2．5,饱和嵌入维数为5到6,表明控制该地区气候环境演化的动力系统是由有限维数确定的混沌系统,构筑该系统所需变量至少3到4个,最多5到6个,这种体上与深海氧同位素比较接近,与黄土剖面一些指标差异较大,4项指标折Hurst指数（FeO－0．85;Fe2O3－0．76;Fe2O3／FeO－0．65;有机碳－0．74）显示该地区气候环境演化存在明显的持续性成分,这与早期的研究一致,很可能与青藏高原的构造抬升有关,表明除了全球性气候环境波动背景外,局域性因素,如肝藏高原构造抬升和未海地区水系变迁,都会在各种气候环境演化的替代性指标上有所反映。4项指标Hurst指数的差异可能反映FeO容易迁移,受到了流域水系变化的影响,因而有机碳和Fe2O3可能是反映这种环境演化持续性分更好的指标。  相似文献   

云南兰坪高含泥低品位氧化铜矿选矿试验   总被引：5，自引：0，他引：5  

王世涛  曾茂青  罗兴  李玺  孙广周 《云南地质》2010,29(1):105-108

原矿为高含泥高氧化率低品位铜矿。根据矿石的工艺矿物学特性,开展“直接浮选”、“预先脱泥＋浮选”和“酸浸”三种工艺流程试验。试验结果表明,“酸浸”是最佳的提铜工艺流程。在较佳的酸浸工艺条件下,可获得铜浸出率92．09％,硫酸耗量54kg／T的技术经济指标。  相似文献   

溶藻弧菌对凡纳滨对虾血清中一氧化氮及氧自由基的影响     

刘文珍  邱德全 《广东海洋大学学报》2007,27(3):60-63

对凡纳滨对虾注射浓度为1×105、1×106、1×107mL-1的溶藻弧菌悬液,在注射后4、12、24、48、72和120 h于腹血窦取血,测定其血清中一氧化氮(NO)、丙二醛(MDA)含量,以及一氧化氮合酶(NOS)、超氧化物岐化酶(SOD)活力。结果表明,注射溶藻弧菌后,凡纳滨对虾血清中NO含量及NOS活力显著高于对照组,且NOS活力最大值出现时间较NO早;而SOD活力先升高后下降,MDA含量在SOD活力开始下降后逐渐升高,说明一氧化氮系统对凡纳滨对虾感染的溶藻弧菌有清除作用,并能在一定程度上对损伤过程中生成的氧自由基产生作用。  相似文献   

Scientific CMOS Pixels   总被引：1，自引：0，他引：1  

James Janesick  Ferry Gunawan  Taner Dosluoglu  John Tower  Niel McCaffrey 《Experimental Astronomy》2002,14(1):33-43

High performance CMOS pixels are introduced; and their development is discussed. 3T (3-transistor) photodiode, 5T pinned diode, 6T photogate and 6T photogate back illuminated CMOS pixels are examined in detail, and the latter three are considered as scientific pixels. The advantages and disadvantages of these options for scientific CMOS pixels are examined. Pixel characterization, which is used to gain a better understanding of CMOS pixels themselves, is also discussed. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Application of fuzzy AHP method to IOCG prospectivity mapping: A case study in Taherabad prospecting area,eastern Iran     

《International Journal of Applied Earth Observation and Geoinformation》2014

Using fuzzy analytical hierarchy process (AHP) technique, we propose a method for mineral prospectivity mapping (MPM) which is commonly used for exploration of mineral deposits. The fuzzy AHP is a popular technique which has been applied for multi-criteria decision-making (MCDM) problems. In this paper we used fuzzy AHP and geospatial information system (GIS) to generate prospectivity model for Iron Oxide Copper-Gold (IOCG) mineralization on the basis of its conceptual model and geo-evidence layers derived from geological, geochemical, and geophysical data in Taherabad area, eastern Iran. The FuzzyAHP was used to determine the weights belonging to each criterion. Three geoscientists knowledge on exploration of IOCG-type mineralization have been applied to assign weights to evidence layers in fuzzy AHP MPM approach. After assigning normalized weights to all evidential layers, fuzzy operator was applied to integrate weighted evidence layers. Finally for evaluating the ability of the applied approach to delineate reliable target areas, locations of known mineral deposits in the study area were used. The results demonstrate the acceptable outcomes for IOCG exploration.  相似文献   

Catalytic Reduction of Hexaminecobalt(III) by Pitch‐based Spherical Activated Carbon (PBSAC)     

Yu Chen  Yan‐peng Mao  Hai‐song Zhu  Jing‐yi Cheng  Xiang‐li Long  Wei‐kang Yuan 《洁净——土壤、空气、水》2010,38(7):601-607

The wet ammonia (NH₃) desulfurization process can be retrofitted to remove nitric oxide (NO) and sulfur dioxide (SO₂) simultaneously by adding soluble cobalt(II) salt into the aqueous ammonia solution. Activated carbon is used as a catalyst to regenerate hexaminecobalt(II), Co(NH₃), so that NO removal efficiency can be maintained at a high level for a long time. In this study, the catalytic performance of pitch‐based spherical activated carbon (PBSAC) in the simultaneous removal of NO and SO₂ with this wet ammonia scrubbing process has been studied systematically. Experiments have been performed in a batch stirred cell to test the catalytic characteristics of PBSAC in the catalytic reduction of hexaminecobalt(III), Co(NH₃). The experimental results show that PBSAC is a much better catalyst in the catalytic reduction of Co(NH₃) than palm shell activated carbon (PSAC). The Co(NH₃) reduction reaction rate increases with PBSAC when the PBSAC dose is below 7.5 g/L. The Co(NH₃) reduction rate increases with its initial concentration. Best Co(NH₃) conversion is gained at a pH range of 2.0–6.0. A high temperature is favorable to such reaction. The intrinsic activation energy of 51.00 kJ/mol for the Co(NH₃) reduction catalyzed by PBSAC has been obtained. The experiments manifest that the simultaneous elimination of NO and SO₂ by the hexaminecobalt solution coupled with catalytic regeneration of hexaminecobalt(II) can maintain a NO removal efficiency of 90% for a long time.  相似文献   

原油污染对栉孔扇贝抗氧化酶活性的影响   总被引：2，自引：0，他引：2  

蒋凤华  高伟  赵美丽  王振  郑立 《海洋科学》2012,36(7):28-33

以原油水溶性成分(water soluble fraction of crude oil,WSF)为污染物,采用暴露实验法,研究了栉孔扇贝(Chlamys farreri)鳃和消化腺组织中超氧化物歧化酶(Superoxide Dismutase,SOD)和过氧化氢酶(Catalase,CAT)活性的变化.结果表明,WSF污染下,鳃和消化腺组织SOD和CAT酶活性随暴露时间增加一般表现为降低-升高-降低的趋势,酶活性达到最高的时间随浓度不同而变化.第1天时消化腺SOD在0.08 mg/L浓度下被诱导,而后随时间增加表现为抑制效应;浓度为0.21和0.88 mg/L时消化腺SOD酶活性被抑制,随暴露时间延长而活性增加.暴露时间为4d时,石油烃浓度在0.08和0.88 mg/L时鳃组织SOD酶活性均被抑制,而浓度为0.21 mg/L时被诱导.消化腺和鳃组织SOD可以作为扇贝被污染胁迫的指标.  相似文献   

Enhancing the Sustainability of Household Fe0/Sand Filters by Using Bimetallics and MnO2     

Chicgoua Noubactep  Sabine Caré  Brice Donald Btatkeu K.  Charles Péguy Nanseu‐Njiki 《洁净——土壤、空气、水》2012,40(1):100-109

Filtration systems containing metallic iron as reactive medium (Fe⁰ beds) have been intensively used for water treatment during the last two decades. The sustainability of Fe⁰ beds is severely confined by two major factors: (i) reactivity loss as result of the formation of an oxide scale on Fe⁰ and (ii) permeability loss due to pore filling by generated iron corrosion products. Both factors are inherent to iron corrosion at pH > 4.5 and are common during the lifespan of a Fe⁰ bed. It is of great practical significance to improve the performance of Fe⁰ beds by properly addressing these key factors. Recent studies have shown that both reactivity loss and permeability loss could be addressed by mixing Fe⁰ and inert materials. For a non‐porous additive like quartz, the threshold value for the Fe⁰ volumetric proportion is 51%. Using the Fe⁰/quartz system as reference, this study theoretically discusses the possibility of (i) replacing Fe⁰ by bimetallic systems (e.g., Fe⁰/Cu⁰), or (ii) partially replacing quartz by a reactive metal oxide (MnO₂ or TiO₂) to improve the efficiency of Fe⁰ beds. Results confirmed the suitability of both tools for sustaining Fe⁰ bed performance. It is shown that using a Fe⁰:MnO₂ system with the volumetric proportion 51:49 will yield a filter with 40% residual porosity at Fe⁰ depletion (MnO₂ porosity 62%). This study improves Fe⁰ bed design and can be considered as a basis for further refinement and detailed research for efficient Fe⁰ filters.  相似文献   

Methodology of analysis associating survey results by the filter-pack method with those of precipitation- Acid-base balance on acid-related and alkali-related chemical species in urban ambient air and its influence on the acidification of precipitation -     

Masahide Aikawa  Takatoshi Hiraki 《Journal of Atmospheric Chemistry》2008,61(1):21-29

Continuous weekly monitoring on the concentration of gases and aerosols in urban ambient air by a four-stage filter-pack method was carried out for 7 years in order to study not only the acid-base balance of acid-related (HNO₃, NO₃ ⁻, and non-sea-salt-(nss-)SO₄ ²⁻) and alkali-related (NH₃, NH₄ ⁺, and nss-Ca²⁺) chemical species but also its influence on the acidification of precipitation. The concentrations of the total nitrate (= NO₃⁻ + HNO₃) and nss-SO₄²⁻ showed a similar seasonal variation: high in the summer and low in the winter. The total nitrate and nss-SO₄²⁻ accounted for 0.43 and 0.57 of the acid-related species, respectively, on an equivalent basis. The total ammonium (= NH₃ + NH₄⁺) accounted for more than 0.9 of the alkali-related species, except for a springtime nss-Ca²⁺ episodic peak. The alkali-related species were generally overabundant compared with the acid-related species in the HNO₃-NO₃⁻-nss-SO₄²⁻-NH₃-NH₄⁺-nss-Ca²⁺ system. The alkali-rich distribution was especially pronounced in the winter, but the acid-related species was comparable to the alkali-related species in the summer, which was attributed to the larger H⁺ deposition by precipitation in the summer. This study can provide a methodology to associate survey results obtained by a filter-pack method with those of precipitation.  相似文献