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81.
Moon HB An YR Park KJ Choi SG Moon DY Choi M Choi HG 《Marine pollution bulletin》2011,62(9):1963-1968
Reports of the occurrence and accumulation patterns of polycyclic aromatic hydrocarbons (PAHs) and synthetic musk compounds (SMCs) in marine mammals are scarce. In this study, the concentrations and accumulation profiles of PAHs and SMCs were determined in blubber from finless porpoises in Korean coastal waters. Total concentrations of PAHs and SMCs ranged from 6.0 to 432 (mean: 160) ng/g lipid weight and from 17 to 144 (mean: 52) ng/g lipid weight, respectively. Residue levels of PAHs were lower than those reported from other studies, while residue levels of SMCs were relatively higher than those reported in other studies. Naphthalene was the most abundant PAH and HHCB was the dominant SMC observed in finless porpoises. The concentrations of PAHs and SMCs were not correlated with each other, but were significantly correlated within the same chemical groups. No correlations were found between body size and residue levels of PAHs and SMCs. 相似文献
82.
Distribution and mass inventory of polycyclic aromatic hydrocarbons in the sediments of the south Bohai Sea, China 总被引:4,自引:0,他引:4
Recent occurrence, distribution and mass inventories of 16 priority polycyclic aromatic hydrocarbons (PAHs) proposed by USEPA in the south Bohai Sea (BS) were studied based on the analytical data of 71 surface sediment samples. The concentrations of 16 PAHs varied from 37 to 537 ng g−1 (dry weight). A clear difference was observed between the coastal Bohai Bay (CBB) and its adjacent BS (ABS) in the distribution and compositions of PAHs. The petrogenic source of phenanthrene in CBB was attributable to the industrial wastewater, fugitive fuel leakages from ships and offshore oil production. Four to six ring PAHs were predominantly from the coal and wood combustions in the whole area. The estimated PAH input to the south BS (43,000 km2, 56% of BS in area) was 36.6 ton yr−1, indicating that the study area was one of the important reservoirs of PAHs in world. 相似文献
83.
Anthropogenic organic contaminants in water, sediments and benthic organisms of the mangrove-fringed Segara Anakan Lagoon, Java, Indonesia 总被引:1,自引:0,他引:1
Dsikowitzky L Nordhaus I Jennerjahn TC Khrycheva P Sivatharshan Y Yuwono E Schwarzbauer J 《Marine pollution bulletin》2011,62(4):851-80
Segara Anakan, a mangrove-fringed coastal lagoon in Indonesia, has a high diversity of macrobenthic invertebrates and is increasingly affected by human activities. We found >50 organic contaminants in water, sediment and macrobenthic invertebrates from the lagoon most of which were polycyclic aromatic compounds (PACs). Composition of PACs pointed to petrogenic contamination in the eastern lagoon. PACs mainly consisted of alkylated PAHs, which are more abundant in crude oil than parent PAHs. Highest total PAC concentration in sediment was above reported toxicity thresholds for aquatic invertebrates. Other identified compounds derived from municipal sewage and also included novel contaminants like triphenylphosphine oxide. Numbers of stored contaminants varied between species which is probably related to differences in microhabitat and feeding mode. Most contaminants were detected in Telescopium telescopium and Polymesoda erosa. Our findings suggest that more attention should be paid to the risk potential of alkylated PAHs, which has hardly been addressed previously. 相似文献
84.
Biomarker responses in pelagic and benthic fish over 1 year following the Hebei Spirit oil spill (Taean, Korea) 总被引:1,自引:0,他引:1
Jung JH Kim M Yim UH Ha SY An JG Won JH Han GM Kim NS Addison RF Shim WJ 《Marine pollution bulletin》2011,62(8):1859-1866
After the Hebei Spirit oil spill incident (7th December, 2007) in the west coast of Korea, contamination of biliary PAH metabolite and hepatic biomarkers in a pelagic and a benthic fish was monitored for 1 year. Concentrations of 16 PAHs and alkylated PAHs in fish muscle were highest (22.0 ng/g d.w. for 16 PAHs and 284 ng/g d.w. for alkylated PAHs) at 5 days after the spill and then decreased rapidly to background levels at 11 months after the spill. Fish from the oiled site had elevated biliary PAH metabolite concentrations immediately after the spill; these declined steadily in both species, but were still above reference site concentrations 2 months after the spill. Oiled-site fish showed hepatic CYP 1A induction whose trend closely followed those of biliary PAH metabolite concentrations, implying continuous exposure to PAHs. Brain acetylcholinesterase activity was not related to oil exposure. 相似文献
85.
采用高效液相色谱法对沈阳市地表土壤中的多环芳烃(Polycyclic Aromatic Hydrocarbons,PAHs)进行了定量分析,研究了沈阳市地表土壤中PAHs在不同功能区的含量及分布特征。结果表明:从土壤PAHs总量来看,居民区最低,其次是商业区,交通干道、文教区和公园排在商业区之后,工业区的PAHs总量最多;从PAHs的空间差异来看,靠近工业区以及机动车车流量较大的地区PAHs含量较高,靠近文教区和居住区的地区PAHs含量较低;从PAHs种类来看,所有功能区样品中PAHs的组分分布状况较为一致,以四环PAHs含量最多,其次是五环PAHs和三环PAHs;参考美国EPA沉积物PAHs质量标准和治理标准,沈阳市内五区PAHs总量超过质量标准的功能区有工业区、交通干道(4个采样点,占比36.3%)、文教区(3个采样点,占比75%)和公园区(4个采样点,占比40%),超过治理标准的功能区有工业区,公园区(1个采样点,占比10%),文教区(1个采样点,25%)。 相似文献
86.
2013年1月在贡嘎山海螺沟3个不同采样点共收集了多个雪样,利用GC-MS分析了雪样中16种优控多环芳烃的含量,探讨了多环芳烃的短周期分布特征与来源,估算了采样点与排放源的直线距离。结果显示,海螺沟各采样点雪样中多环芳烃的总含量在163.7 ng/L~281.4 ng/L之间,其中菲的含量最高。雪样中2~4环多环芳烃占多环芳烃总量的百分比为92.0%~93.7%,表明污染来自较远距离传输,但主要排放源离海螺沟的直线距离不超过357 km。将雪层与气象资料的降雪期对应,结果表明从2012年11月到2013年1月这个短周期内,海螺沟雪样受多环芳烃污染的程度没有太大变化。对海螺沟雪样中的多环芳烃进行了来源分析,结果表明海螺沟雪样中的多环芳烃主要来自煤燃烧,不排除少部分木材燃烧,这一源解析结果与海螺沟及其周边地区主要以煤炭作为燃料的能源特征相吻合。 相似文献
87.
Qihang Wu Jonathan Y.S. Leung Nora F.Y. Tam Shejun Chen Bixian Mai Xizhen Zhou Lihua Xia Xinhua Geng 《Marine pollution bulletin》2014
Chinese government has taken various measures to alleviate pollution caused by polycyclic aromatic hydrocarbons (PAHs) in the region of Pearl River Delta since the economic reform in 1978, but the effectiveness of these measures remains largely unknown. This study aimed to elucidate the biological risk and pollution history of PAHs by measuring the concentrations of 28 PAHs in the surface and core sediments, respectively, in Nansha mangrove. Results found that the biological risk of PAHs was low without obvious spatial variation. The PAH concentration along the depth gradient indicated that PAH pollution was stabilized since the early 1990s while the source of PAHs has gradually changed from combustion of coal to petroleum products. This implied that the mitigation measures taken by the Chinese government were effective. Compared to marine bottom sediment, we propose that using mangrove sediment can provide a more accurate and precise estimate of pollution history of PAHs. 相似文献
88.
Kaiyan Wang Yating Shen Shucai Zhang Youbin Ye Qiong Shen Jundong Hu Xuejun Wang 《Environmental Geology》2009,56(6):1041-1050
Surface soil samples were collected from 161 sites throughout the downtown and suburban area of Beijing, China. The samples
were analyzed for polycyclic aromatic hydrocarbons (PAHs) concentrations. Through Kriging analysis, five heavily contaminated
zones were identified in the study area. Sources of PAHs in the soil were apportioned using principal factor analysis and
multiple linear regression. Three factors were identified representing coal combustion/vehicle emission, coking emission,
and petroleum sources, respectively. The relative contributions of the three sources were 48% for coal/vehicle emission, 28%
for coking emission, and 24% for petroleum sources. The contributions of total PAHs from the three sources were 16.4, 4.63
and 3.70 ng g−1, respectively. Spatial analysis indicated that the contribution of coal/vehicle sources was higher in the downtown area than
in the suburban area, the petroleum sources had a high contribution in the urban area, and the contribution of coking sources
was high in the suburban area. The results indicated that PAH contamination in the surface soil in Beijing was closely related
to the spatial characteristics of energy consumption and functional zoning. Improvement of the energy consumption structure
and relocation of industries with heavy pollution are effective ways to control PAH contamination in surface soil in the area. 相似文献
89.
Saioa Elordui-Zapatarietxe Núria Moraleda Joan Albaigés 《Marine pollution bulletin》2010,60(10):1667-1673
Spills from wrecks are a potential major source of pollution in the deep ocean. However, not much is known about the fate of a spill at several kilometers depth, beyond the oceans continental shelves. Here, we report the phase distribution of hydrocarbons released from the wrecks of the Prestige tanker, several years after it sank in November 2002 to depths between 3500 and 3800 m. The released oil reached the surface waters above the wrecks without any signs of weathering and leaving an homogenous signature throughout the water column. At depths of several kilometers below the sea surface, the occurrence and spread of the deep sea oil spill could be evaluated better by quantifying and characterizing the dissolved hydrocarbon signature, rather than just the investigation of hydrocarbons in the suspended particulate matter. 相似文献
90.