Effect of Fly Ash on Frost-Resistance and Chloride Ions Diffusion Properties of Marine Concrete     

杨文武  钱觉时  章一颖 《中国海洋工程》2009,23(2):367-377

It is necessary to pay more attention to the durability of concrete undergoing freeze-thaw cycles and seawater attack simultaneously.Investigated are the effects of water-binder ratio,fly ash (FA) contents and air-entraining agent on resistance to frost and chloride diffusion of marine concrete blended with FA in natural seawater.The results show that fly ash does not improve the frost resistance of concrete but can improve its resistance to chloride diffusion by addition of less than 30%.The resistance to frost and chloride diffusion of FA concrete can be improved with the decrease of water-binder ratio,and FA may improve both of them simultaneously only being mixed with air-entraining agent.A ratio (named as R) of the frost-resisting durability factor to chloride diffusion coefficient can be used to evaluate the durability of marine concrete.Scanning electron microscope (SEM) analyses are consistent with the evaluations by the value of R.  相似文献   

Effect of nearby supernova remnants on local cosmic rays     

Satyendra Thoudam 《Monthly notices of the Royal Astronomical Society》2007,378(1):48-54

We study in detail the effect of different particle release times from sources on the cosmic ray (CR) spectrum below 10¹⁵ eV in the Galaxy. We discuss different possible forms of particle injection such as burst-like injection, continuous injection for a finite time, injection from a stationary source and energy-dependent injection. When applied to the nearby known supernova remnants, we find that the observed CR anisotropy data favour the burst-like particle injection model for the CR diffusion coefficient   D ( E ) ∝ E ^a   with   a = 0.3 –0.6  in the local region. In this study we have also found that the contribution of the sources G114.3+0.3 and Monogem dominate if the observed anisotropy is a result of the effect of the nearby sources. Further study shows that we should not neglect the contribution of the undetected old sources to the local CR anisotropy.  相似文献   

Asthenospheric Viscosity and Stress Diffusion: A Mechanism to Explain Correlated Earthquakes and Surface Deformations In Ne Japan   总被引：1，自引：0，他引：1  

P. A. Rydelek  I. S. Sacks 《Geophysical Journal International》1990,100(1):39-58

  相似文献   

Cascade model for fluvial geomorphology   总被引：3，自引：0，他引：3  

W. I. Newman  D. L. Turcotte 《Geophysical Journal International》1990,100(3):433-439

  相似文献   

围海造陆工程泄水口悬浮物扩散规律分析   总被引：1，自引：1，他引：0  

陈杰  蒋昌波  张绍华  胡保安 《海洋科学》2015,39(8):58-62

掌握围海造陆工程泄水口悬浮物扩散规律,对保护海洋水环境质量具有重要意义。选取围海造陆工程泄水口为研究对象,基于泥沙对流扩散方程,推求出泄水口悬浮物扩散平面二维分析解表达式。开展现场观测,确定泄水口源强取值,并对泄水口悬浮物扩散进行理论计算和分析。研究结果显示,围海造陆工程施工后期,泄水口悬浮物流失非常严重。泄水口附近水域出现的最大悬浮物浓度主要由源强的大小来决定,悬浮物扩散范围主要由流速的大小来控制。  相似文献   

黄河沉积物向渤海湾扩散的沉积地球化学示踪   总被引：1，自引：0，他引：1       下载免费PDF全文

张爱滨  刘明  廖永杰  张艳丽  范德江 《海洋科学进展》2015,33(2):246-256

使用ICP-AES和ICP-MS对渤海中部118°54′E左右南北向断面的表层沉积物中53种常、微量及稀土元素进行了测试,研究了其含量变化和分布特征,并进行了物质组成分析。研究表明:该区沉积物以B94站为界,南北差异明显,南部区域沉积物以黏土质粉砂为主,富集Al2O3,CaO,Fe2O3,MgO,MnO,P2O5和TiO等常量元素以及绝大多数的微量元素和稀土元素等与细颗粒黏土矿物相关的元素;北部区域沉积物以粉砂-砂为主,富集SiO2,K2O和Na2O等常量元素以及Zr,Ba,Sr,Sb和Hf等微量元素,稀土元素相对亏损。物源对比表明南部沉积物具有黄河来源沉积物特点,北部沉积物具有滦河来源特点,两者的分界大致在38°42′N附近。河口动力过程、渤海环流是影响该区沉积物扩散的主要因素。  相似文献   

1961-2012年江苏省霾日时空变化特征及影响因素分析     

田心如  林惠娟  陈广昌  武艳  王伟丽 《气象与环境学报》2015,(3):29-34

利用1961—2012年江苏省69个地面气象站观测资料和2012年苏州市大气气溶胶观测资料,在对霾日进行判识和筛选的基础上,分析江苏省霾日的时空变化特征及霾与气象条件和污染物的关系。结果表明：1961—2012年江苏省各站年总霾日数均呈上升趋势,85％的台站呈极显著上升趋势;江苏省年平均霾日数呈显著上升趋势,其中2011—2012年呈急剧上升趋势;1980年前霾日的空间分布差异不明显,1980年后,沿江和苏南地区为霾的高发区,东部沿海大部地区霾日较少。霾天气主要发生在冬季和春季,以12月和1月发生最多。降水少和风速小有利于霾天气的发生;除SO2外,PM10、PM2.5和NO2等污染物浓度随着霾等级的增加而增大,其中PM2.5浓度增大明显。  相似文献   

From an initial transient-state to a steady-state in metamorphic reactions: An experimental approach in the system dolomite-quartz-H₂O     

Tadao  Nishiyama  Aiko  Tominaga  Hiroshi  Isobe 《Island Arc》2007,16(1):16-27

Abstract We carried out hydrothermal experiments in the system dolomite‐quartz‐H₂O to track the temporal change in reaction rates of simultaneous reactions during the development of reaction zones. Two types of configurations for the starting materials were prepared: dolomite single crystals + quartz powder + water and quartz single crystals + dolomite powder + water, both sealed separately in gold capsules. Runs at 0.1GPa and 600°C with cold seal pressure vessels gave the following results. (i) In short duration (45–71 h) runs metastable layer sequences involving wollastonite and talc occur in the reaction zone, whereas they disappear in longer duration (168–336 h) runs. (ii) The layer sequence of the reaction zones in short duration runs differs from place to place on the dolomite crystal even in the same run. (iii) The diversity of layer sequences in the short duration runs merges into a unique layer sequence in the longer duration runs. (iv) The reaction zone develops locally on the dolomite crystal, but no reaction zone was observed on the quartz crystal in any of the runs. The lines of evidence (i)–(iii) show that the system evolves from an initial transient‐ to a steady‐state and that the kinetic effect is important in the development of reaction zones. A steady diffusion model for the unique layer sequence Qtz/Di/Fo + Cal/Dol + Cal/Dol shows that the Dol + Cal layer cannot be formed by diffusion‐controlled process and that the stability of the layer sequence Qtz/Di/Fo + Cal/Dol depends not only on L‐ratios (a = /L_CaOCaO and b = /L_MgOMgO) but also on the relative rate P = (−2ξ₁ − ξ₂)/(–ξ₁ − 2ξ₂) of competing reactions: Dol + 2Qtz = Di + 2CO₂ (ξ₁) and 2Dol + Qtz = Fo + 2Cal + 2CO₂ (ξ₂). For smaller P the stability field will shift to higher values of a and b. The steady diffusion model also shows that the apparent‐non‐reactivity on the quartz surface can be attributed to void formation in a large volume fraction in the diopside layer.  相似文献   

Numerical estimation of effective diffusion coefficients for charged porous materials based on micro-scale analyses     

Arash Mohajeri  Guillermo A. Narsilio  Peter Pivonka  David W. Smith 《Computers and Geotechnics》2010

In order to describe diffusive transport of solutes through a porous material, estimation of effective diffusion coefficients is required. It has been shown theoretically that in the case of uncharged porous materials the effective diffusion coefficient of solutes is a function of the pore morphology of the material and can be described by the tortuosity (tensor) (Bear, 1988 [1]). Given detailed information of the pore geometry at the micro-scale the tortuosity of different materials can be accurately estimated using homogenization procedures. However, many engineering materials (e.g., clays and shales) are characterized by electrical surface charges on particles of the porous material which strongly affect the (diffusive) transport properties of ions. For these type of materials, estimation of effective diffusion coefficients have been mostly based on phenomenological equations with no link to underlying micro-scale properties of these charged materials although a few recent studies have used alternative methods to obtain the diffusion parameters (Jougnot et al., 2009; Pivonka et al., 2009; Revil and Linde, 2006 2, 3 and 4). In this paper we employ a recently proposed up-scaled Poisson–Nernst–Planck type of equation (PNP) and its micro-scale counterpart to estimate effective ion diffusion coefficients in thin charged membranes. We investigate a variety of different pore geometries together with different surface charges on particles. Here, we show that independent of the charges on particles, a (generalized) tortuosity factor can be identified as function of the pore morphology only using the new PNP model. On the other hand, all electro-static interactions of ions and charges on particles can consistently be captured by the ratio of average concentration to effective intrinsic concentration in the macroscopic PNP equations. Using this formulation allows to consistently take into account electrochemical interactions of ions and charges on particles and so excludes any ambiguity generally encountered in phenomenological equations.  相似文献   

扩散法——EA-IRMS测定天然水体铵态氮同位素实验条件研究   总被引：2，自引：0，他引：2  

胡婧  刘卫国 《矿物岩石地球化学通报》2010,29(1):31-37

稳定氮同位素是研究氮循环和氮污染源示踪的一个有效手段。然而目前国内对水体中铵态氮同位素测定方法研究较少,限制了水体氮循环和污染机理的深入探讨。本文采用改进的扩散法(EA-IRMS)测定水中铵态氮同位素,探讨了样品制备过程中扩散溶液的体积、浓度和扩散时间对回收率及氮同位素测定值的影响。实验得出最佳扩散条件为:1.50 mg/L氯化铵溶液400 mL扩散14天,回收率大于95%,且不会产生氮同位素分馏。本研究为高精度测定天然水体中铵态氮同位素提供了更可靠的实验条件。  相似文献