Contaminant concentrations in sport fish from San Francisco Bay, 1997     

Davis JA  May MD  Greenfield BK  Fairey R  Roberts C  Ichikawa G  Stoelting MS  Becker JS  Tjeerdema RS 《Marine pollution bulletin》2002,44(10):1117-1129

In 1997, seven sport fish species were sampled from seven popular fishing areas in San Francisco Bay. Mercury exceeded a human health screening value in 44 of 84 (52%) samples. All collected samples of leopard shark and striped bass exceeded the mercury screening value of 0.23 microg/g wet weight. PCBs exceeded the screening value in 51 of 72 (71%) samples. DDT, chlordane, and dieldrin, had lower numbers of samples above screening values: 16 of 72 (22%) for DDT, 11 of 72 (15%) for chlordanes, and 27 of 72 (37%) for dieldrin. Concentrations of PCBs and other trace organics were highest in white croaker and shiner surfperch, the two species with the highest fat content in their muscle tissue. Fish from one location, Oakland Harbor, had significantly elevated wet weight concentrations of mercury, PCBs, DDTs, and chlordanes compared to other locations. Removal of skin from white croaker fillets reduced lipid concentrations by 27-49% and concentrations of trace organics by 33-40%.  相似文献   

Physico-chemical Speciation of Lead in South San Francisco Bay     

P.B. Kozelka  S. Sañudo-Wilhelmy  A.R. Flegal  K.W. Bruland 《Estuarine, Coastal and Shelf Science》1997,44(6):649-658

The speciation of lead at a site in the South San Francisco Bay was determined using a combination of physical size fractionation and electrochemical analyses. The ‘ total dissolvable ’ Pb was 8·1 nM from analysis of an acidified unfiltered sample. The ‘ dissolved ’ Pb was equal to 0·20 nM (41 ng l⁻¹), only 2·5% of the ‘ total dissolvable ’ Pb. The difference yielded the ‘ particulate ’ Pb equal to 7·9 nM (1·6 μg l⁻¹). Results from crossflow ultrafiltration indicated that almost all (0·19 nM) of the dissolved Pb was ‘ in solution ’ [<10K nominal molecular weight (MW)] and that colloidal Pb (10K MW to 0·2 μm)accounted for onlyc. 1% of the dissolved Pb at this station. This small concentration (0·01 nM) of colloidal Pb may be attributed to the low amount of organic carbon associated with colloid size fraction as determined by dissolved organic carbon analyses.The chemical speciation of lead was determined in the dissolved sample and ultrafiltered sub-sample. Differential pulse anodic stripping voltammetry (DPASV) on a thin mercury film (TMF) rotating glassy carbon disk electrode (RGCDE) was used to distinguish the kinetically labile inorganic species (Pb′) from the Pb-chelated by organic ligands (PbL_i). Lead titration results were similar for both samples revealing that Pb′, PbL_iand excess unbound ligands were present primarily in the ultrafiltrate, rather than in the colloidal phase. The titration data can be interpreted as dissolved Pb being influenced by two classes of Pb-binding ligands. In the dissolved sample, the concentration of the stronger class of ligands was [L₁]=0·89±0·35 nM, with a conditional stability constant ofK^cond_L1,Pb′=3±1×10¹⁰M⁻¹. The weaker class was [L₂]=12·8±1·9 nM, withK^cond_L1,Pb′=4±1×10⁸ M⁻¹. The presence of these ligands, in excess of the dissolved Pb, resulted in [Pb′]=7±2 pM and [Pb²⁺]=0·3 pM (62 pg l⁻¹). While less than 2·4% of the ambient Pb was ‘ in solution ’, it existed chiefly in the form of organic complexes with [PbL₁]=0·15 nM and [PbL₂]=0·03 nM. More significantly, there were large concentrations of unchelated Pb-binding ligands, (L_i′), available to buffer the free Pb²⁺concentration in the event of perturbations in dissolved Pb.  相似文献   

Dissolved nutrient balance and net ecosystem metabolism in a Mediterranean-climate coastal lagoon: San Diego Bay     

F. Delgadillo-Hinojosa  A. Zirino  O. Holm-Hansen  J.M. Hernández-Ayón  T.J. Boyd  B. Chadwick  I. Rivera-Duarte 《Estuarine, Coastal and Shelf Science》2008

The temporal and spatial variability of dissolved inorganic phosphate (DIP), nitrogen (DIN), carbon (DIC) and dissolved organic carbon (DOC) were studied in order to determine the net ecosystem metabolism (NEM) of San Diego Bay (SDB), a Mediterranean-climate lagoon. A series of four sampling campaigns were carried out during the rainy (January 2000) and the dry (August 2000 and May and September 2001) seasons. During the dry season, temperature, salinity and DIP, DIC and DOC concentrations increased from oceanic values in the outer bay to higher values at the innermost end of the bay. DIP, DIC and DOC concentrations showed a clear offset from conservative mixing implying production of these dissolved materials inside the bay. During the rainy season, DIP and DOC increased to the head, whereas salinity decreased toward the mouth due to land runoff and river discharges. The distributions of DIP and DOC also showed a deviation from conservative mixing in this season, implying a net addition of these dissolved materials during estuarine mixing within the bay. Mass balance calculations showed that SDB consistently exported DIP (2.8–9.8 × 10³ mol P d⁻¹), DIC (263–352 × 10³ mol C d⁻¹) and DOC (198–1233 × 10³ mol C d⁻¹), whereas DIN (5.5–18.2 × 10³ mol N d⁻¹) was exported in all samplings except in May 2001 when it was imported (8.6 × 10³ mol N d⁻¹). The DIP, DIC and DOC export rates along with the strong relationship between DIP, DIC or DOC and salinity suggest that intense tidal mixing plays an important role in controlling their distributions and that SDB is a source of nutrients and DOC to the Southern California Bight. Furthermore, NEM ranged from −8.1 ± 1.8 mmol C m⁻² d⁻¹ in September to −13.5 ± 5.8 mmol C m⁻² d⁻¹ in January, highlighting the heterotrophic character of SDB. In order to explain the net heterotrophy of this system, we postulate that phytoplankton-derived particulate organic matter, stimulated by upwelling processes in the adjacent coastal waters, is transported into the bay, retained and then remineralized within the system. Our results were compared with those reported for the heterotrophic hypersaline coastal lagoons located in the semi-arid coast of California–Baja California, and with those autotrophic hypersaline systems found in the semi-arid areas of Australia. We point out that the balance between autotrophy and heterotrophy in inverse estuaries is dependent on net external inputs of either inorganic nutrients or organic matter as it has been indicated for positive estuaries.  相似文献   

The late Quaternary tephrostratigraphical record of the San Gregorio Magno basin (southern Italy)     

R. Munno  P. Petrosino 《第四纪科学杂志》2007,22(3):247-266

Twenty‐one primary pyroclastic layers were found embedded in the lacustrine sediments of the San Gregorio Magno basin (Southern Apennines). These sand‐sized layers were characterised by a noticeable juvenile fragments content and by a sharp basal contact with the underlying clay and silt sediments. The tephra layers have been correlated with terrestrial counterparts from well‐known eruptive events of the Campanian volcanic area, or with reference layers from deep sea sediment cores and from the Monticchio maar sequence. The investigation of the San Gregorio Magno tephra layers made it possible to deduce that lacustrine sedimentation at San Gregorio Magno basin began before 170k yr BP and lasted at least until the emplacement of the Neapolitan Yellow Tuff, which occurred about 15k yr BP. The tephrochronology allowed determination of the varying sedimentation rate that occurred in the basin. Correlation of the lacustrine record with marine sequences has allowed development of a late Quaternary tephrostratotype for southern Italy. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

Aseismic-Seismogenic Coupling For A Long Strike-Slip Fault     

Moujahed I. Husseini 《Geophysical Journal International》1989,97(3):391-407

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Mineralogy and pressure–temperature–time path of Cretaceous granulite gneisses, south-eastern San Gabriel Mountains, southern California     

A. P. BARTH  D. J. MAY 《Journal of Metamorphic Geology》1992,10(4):529-544

Mid-Cretaceous granulite gneisses crop out in a narrow belt in the Cucamonga region of the south-eastern foothills of the San Gabriel Mountains, southern California. Interlayered mafic granulites and pelitic, carbonate, calc-silicate and quartzofeldspathic metasediments record hornblende granulite subfacies metamorphism at approximately 8 kbar and 700–800°C. Regional deformation and formation of banded gneisses ceased by c. 108 Ma. although mafic-intermediate magmatism and high-grade metamorphism continued locally as late as c. 88 Ma. Garnet zoning in metapelitic gneisses suggests that peak metamorphism was followed locally by a period of near-isobaric cooling, but this interpretation requires diachronous cooling of the granulite belt which cannot be demonstrated without detailed thermo-chronological data. It is more likely that the entire terrane remained at granulite facies P–T conditions until 88 Ma, followed by rapid uplift associated with juxtaposition against adjacent middle and upper crustal arc terranes. Uplift occurred between c. 88 and 78 Ma at rates of approximately 1–2 km Ma^-1. The geotectonic evolution of the Cucamonga granulites is similar to mid-Cretaceous high- P granulites in the Sierra Nevada and Salinian block of central California. Late Cretaceous uplift common to these granulites may provide an important tectonic link between dismembered Mesozoic batholithic terranes in the California Cordillera.  相似文献   

Volumetric strain in relation to particle displacements for body and surface waves in a general viscoelastic half-space     

Roger D. Borcherdt 《Geophysical Journal International》1988,93(2):215-228

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Spatial-temporal characterization of the San Andreas Fault by fault-zone trapped waves at seismic experiment site,Parkfield, California          下载免费PDF全文

Yong-Gang Li 《地震科学（英文版）》2021,34(3):261-285

In this article, we review our previous research for spatial and temporal characterizations of the San Andreas Fault (SAF) at Parkfield, using the fault-zone trapped wave (FZTW) since the middle 1980s. Parkfield, California has been taken as a scientific seismic experimental site in the USA since the 1970s, and the SAF is the target fault to investigate earthquake physics and forecasting. More than ten types of field experiments (including seismic, geophysical, geochemical, geodetic and so on) have been carried out at this experimental site since then. In the fall of 2003, a pair of scientific wells were drilled at the San Andreas Fault Observatory at Depth (SAFOD) site; the main-hole (MH) passed a ～200-m-wide low-velocity zone (LVZ) with highly fractured rocks of the SAF at a depth of ～3.2 km below the wellhead on the ground level (Hickman et al., 2005; Zoback, 2007; Lockner et al., 2011). Borehole seismographs were installed in the SAFOD MH in 2004, which were located within the LVZ of the fault at ～3-km depth to probe the internal structure and physical properties of the SAF. On September 282004, a M6 earthquake occurred ～15 km southeast of the town of Parkfield. The data recorded in the field experiments before and after the 2004 M6 earthquake provided a unique opportunity to monitor the co-mainshock damage and post-seismic heal of the SAF associated with this strong earthquake. This retrospective review of the results from a sequence of our previous experiments at the Parkfield SAF, California, will be valuable for other researchers who are carrying out seismic experiments at the active faults to develop the community seismic wave velocity models, the fault models and the earthquake forecasting models in global seismogenic regions.  相似文献   

Visionary Politics: Technologies of Government in the Capital of Innovation     

John W. Elrick 《社会与自然资源》2017,30(7):860-876

ABSTRACT

Taking up experiments in “civic innovation” as windows into the making of new urban worlds, I attempt in this essay to map out the parameters of a novel framework for municipal rule and account for the conditions underlying its ascendance in San Francisco, CA. I explore how productions of urban space and nature today serve as the means and objects of an emerging mode of government premised on yoking all forms of urban activity to the dictates of innovation. When proponents of civic innovation pursue particular forms of intervention in the built environment to constitute urban subjects as human capital, they imbibe, reproduce, and enact normative notions about the nature of the city as a problem to manage. Though the project of civic innovation is neither complete nor inevitable, the political vision animating it entails the subsumption of urban life as such within a rubric of decision making modeled on the market.  相似文献   

QUANTIFYING AND MITIGATING FLOOD RISK IN RAPIDLY AGGRADING FLUVIAL SYSTEMS     

Brad R. HALL 《国际泥沙研究》1999,(2)

ILOWERGUADALUPERIVER,SANJOSECALIFORNIATheLowerGuadalupeRiverProjectAreadoesnothavetheabilitytoconveytheflowofthe100-yearfloodevent.LocatedbetweentheSanrranciscoBayandDowntownSanJose,theLowerGuadalupeRiverProjectareaissubjecttomanynaturalandman-inducedagentsandnaturalphysicalprocessesthataffectthehydraulicandsedimenttransportcharacteristicsoftheRiver.Themostsignificantagentsandprocessesincludethelocalgeology,regionalseismicity,tidalprocesses,pastsubsidenceintheregion,risings…  相似文献