油田污水中Fe2+,S2-,DO及pH值对HPAM-酚醛CDG成胶性能影响的研究     

陈艳玲  王红梅  谭中良  朱怀江  费琪 《地质科技情报》2002,21(3):61-64

在对河南油田双河矿区油田污水进行全分析的基础上，研究了污水中Fe^2 ,S^2-，溶解氧（DO）及污水的pH值对有机交联体系聚丙烯酰胺（HPAM）－酚醛胶态分散凝胶（CDG）成胶性能的影响。研究结果表明，Fe^2 ,S^2－，DO及污水的pH值对HPAM－酚醛体系的成胶性能都有影响当ρ（Fe^2 )=1.6mg/L,ρ（S^2-)=0.1mg/L,ρ（DO）=1.6mg/L，HPAM－酚醛体系就不能成胶；随着污水pH值的增大，CDG强度变弱。  相似文献   

基于GM(1,1)优化模型的岩石边坡变形预报     

巫德斌  徐卫亚 《地质灾害与环境保护》2002,13(4):60-63

岩石边坡系统是一典型灰色系统，其变形发展过程可以用灰色预测模型完成。尽管传统GM（1，1）模型预测有很多成功的实例，但是也存在一些预测偏差过大的情况，必须对其进行优化。逐步迭代法GM（1，1）模型不仅收敛速度快，而且与原始数据库序列的凹凸性保护一致。利用自编的计算程序对马步坎边坡预测测点G1沉降和开裂进行预测分析，结果表明逐步迭代法GM（1，1）优化模型计算精度较传统GM（1，1）模型和背景构造法GM（1，1）优化模型高，较好地反映了岩石边坡的变形趋势。  相似文献   

Comparative response analysis of conventional and innovative seismic protection strategies     

S. Bruno  C. Valente 《地震工程与结构动力学》2002,31(5):1067-1092

The paper presents a numerical investigation aimed at evaluating the improvements achievable through devices for passive seismic protection of buildings based on the use of shape memory alloys (SMA) in place of conventional steel or rubber devices. To get some generality in the results, different resisting reinforced concrete plane frames were analysed, either protected or not. ‘New’ and ‘existing’ buildings were considered depending on whether seismic provisions are adopted in the building design or not. Base isolation and energy dissipation were equally addressed for both conventional and innovative SMA‐based devices. Fragility analyses were performed using specific damage measures to account for comparisons among different damage types; the results were then used to estimate quantitatively the effectiveness of the various protection systems. More specifically, the assessment involved a direct comparison of the damage reduction provided by each protection system with respect to the severe degradation experienced by the corresponding non‐protected frame. Structural damage, non‐structural damage and damage to contents were used on purpose and included in a subsequent phase of cost analysis to evaluate the expected gains also in terms of economic benefits and life loss prevention. The results indicate that base isolation, when applicable, provides higher degrees of safety than energy dissipation does; moreover, the use of SMA‐based devices generally brings about better performances, also in consideration of the reduced functional and maintenance requirements. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

湘中锑(金)矿床成矿物质来源——Ⅰ.微量元素及其实验地球化学证据   总被引：9，自引：0，他引：9  

马东升  潘家永  解庆林  何江 《矿床地质》2002,21(4):366-376

为了查明湘中盆地中-低温梯（金）矿床的成矿物质来源，文章应用高分辨率ICP-MS、ICP-AES等方法对岩石与矿石进行了系统测定，并结合作者以往分析数据和实验地球化学结果，对该区盆地及周边基底地层与矿床中的微量元素分布特征及其水/岩反应效应进行了综合分析和系统研究。结果表明：Sb、Au等成矿元素在元古界基底碎屑岩中具有高的背景含量，在近似成矿条件下的水/岩反应实验中，成矿元素的淋出率达20%～90%，元古界基底碎屑岩中的金（锑、钨）矿床的周围蚀变围岩中出现明显的金负异常区。而盆地内泥盆系统地层中的高锑含量仅局限于锑矿床（化）及其蚀变围岩中；湘中锑（金）矿床中的矿石与基底碎屑岩具有相似的稀土元素球粒陨石标准化配分曲线特征，以上微量元素地球化学特征充分证明该区锑（金）矿床锑、金等成矿物质主要来源于元古界底碎屑岩。  相似文献   

Impact of Southern Oscillation on the Frequency of Monsoon Depressions in the Bay of Bengal     

Singh  O. P.  Ali Khan  Tariq Masood  Rahman  Md. Sazedur 《Natural Hazards》2002,25(2):101-115

The impact of Southern Oscillation on thecyclogenesis over the Bay of Bengal duringthe summer monsoon has been investigated.The analysis of correlation coefficients(CCs) between the frequency of monsoondepressions and the Southern OscillationIndex (SOI) reveals that more depressionsform during July and August of El Niñoyears. Due to this, the seasonal frequencyof monsoon depressions remains little higherduring El Niño epochs even though thecorrelations for June and September are notsignificant. The CCs for July and August aresignificant at the 99% level.The El Niño-Southern Oscillation (ENSO)is known to affect Indian MonsoonRainfall (IMR) adversely. The enhancedcyclogenesis over the Bay of Bengal duringJuly and August is an impact of ENSO whichneeds to be examined closely. Increasedcyclogenesis over the Bay of Bengal may bereducing the deficiency in IMR duringEl Niño years by producing more rainfallover the eastern parts of India duringJuly and August. Thus there is a considerablespatial variation in the impact of ENSOon the monsoon rainfall over India and El Niñoneed not necessarily imply a monsoonfailure everywhere in India.The area of formation of monsoon depressionsshifts eastward during El Niño years.Warmer sea surface temperature (SST) anomaliesprevail over northwest and adjoiningwestcentral Bay of Bengal during premonsoon andmonsoon seasons of El Niño years.May minus March SOI can provide useful predictionsof monsoon depression frequencyduring July and August.  相似文献   

Low-temperature thermodynamic properties of disordered zeolites of the natrolite group     

I. E. Paukov  N. K. Moroz  Yu. A. Kovalevskaya  I. A. Belitsky 《Physics and Chemistry of Minerals》2002,29(4):300-306

 The heat capacity of paranatrolite and tetranatrolite with a disordered distribution of Al and Si atoms has been measured in the temperature range of 6–309 K using the adiabatic calorimetry technique. The composition of the samples is represented with the formula (Na_1.90K_0.22Ca_0.06)[Al_2.24Si_2.76O₁₀]·nH₂O, where n=3.10 for paranatrolite and n=2.31 for tetranatrolite. For both zeolites, thermodynamic functions (vibrational entropy, enthalpy, and free energy function) have been calculated. At T=298.15 K, the values of the heat capacity and entropy are 425.1 ± 0.8 and 419.1 ±0.8 J K⁻¹ mol⁻¹ for paranatrolite and 381.0 ± 0.7 and 383.2 ± 0.7 J K⁻¹ mol⁻¹ for tetranatrolite. Thermodynamic functions for tetranatrolite and paranatrolite with compositions corrected for the amount of extraframework cations and water molecules have also been calculated. The calculation for tetranatrolite with two water molecules and two extraframework cations per formula yields: C _p (298.15)=359.1 J K⁻¹ mol⁻¹, S(298.15) −S(0)=362.8 J K⁻¹ mol⁻¹. Comparing these values with the literature data for the (Al,Si)-ordered natrolite, we can conclude that the order in tetrahedral atoms does not affect the heat capacity. The analysis of derivatives dC/dT for natrolite, paranatrolite, and tetranatrolite has indicated that the water- cations subsystem within the highly hydrated zeolite may become unstable at temperatures above 200 K. Received: 30 July 2001 / Accepted: 15 November 2001  相似文献   

Iron(II) oxide determination in rocks and minerals     

Sandra Andrade  Raphael HypolitoHorstpeter H.G.J. Ulbrich  Marinês L. Silva 《Chemical Geology》2002,182(1):85-89

The determination of FeO of geologic materials by modern instrumental methods (such as atomic absorption spectroscopy (AAS), inductively coupled plasma atomic emission spectroscopy (ICP-AES), X-ray fluorescence (XRF), etc.) cannot distinguish between different oxidation states of elements. In many cases, the oxidation state of Fe has to be known in order to perform several chemical calculations (norms, etc.) and discuss the reactions that occur during weathering, hydrothermal alteration and other processes. A modified Wilson method is proposed, giving reproducible results in a much shorter time than the classical method. Back-titration with potassium dichromate and an Fe(II) and ammonia sulphate solution is used, after dissolution of the sample powder in a heated HF/H₃PO₄ mixture and an ammonium vanadate solution. This modified method, tested with several international reference materials, gives reliable results, equivalent to the ones cited in the literature for the reference materials.  相似文献   

中条山西南段与变基性岩有关的铜矿地质特征及成因浅析     

薛克勤  赵月凤  董清雷 《华北地质》2002,(Z1)

与变基性岩有关的铜矿 ,是在中条山西南段新发现的一种新的铜矿类型 ,其形成是在原始基性岩浆侵入或喷发作用形成的矿源岩或矿化体基础上 ,经过区域变质和印支 -燕山期构造 -岩浆热液的改造加富而成 ,其成因应属与变基性岩有关的变质 -热液改造型铜 (镍、铁 )矿床。  相似文献   

Sulfur Content and Isotopic Ratio of Cambro-Ordovician Carbonate Rocks from South Korea: A Possible Source for Mesozoic Magmatic-hydrothermal Ore Sulfur     

Shunso ISHIHARA  Myung–Shik JIN  Yoshimichi KAJIWARA 《Resource Geology》2002,52(1):41-48

Abstract: Carbonate rocks of Cambrian (18 samples) and lower-middle Ordovician (11 samples) ages from South Korea were analyzed for sulfur contents of structurally substituted sulfate (SSS) and sulfides and their δ³⁴S values. The δ³⁴S values of SSS ranging from +25.9 to +45.2 permil, are averaged as +33.6 and +33.5 permil for the Cambrian and Ordovician rocks, respectively, which indicate high δ³⁴S values of the Cambro-Ordovician seawater. The SSS contents in the carbonate rocks are low being 2.9 to 17.3 ppm S (averaged as 7.0 ppm S). Sulfide sulfur, on the contrary, is much abundant containing 3 to 1,880 ppm S and the δ³⁴S values range widely between –17.6 and +31.1 permil. Sulfide sulfur of the studied rocks excluding impure carbonates has an average content of 187 ppm S and δ³⁴S value of +12.8 permil (n=24). The estimated δ³⁴S (sulfate–sulfide) values, which range from 13.8 to 25.4 permil in general with a few exceptions from 36.5 up to 52.3 permil for some impure carbonates, may provide evidence for the persistent oceanic anoxia with its temporary recovery during the Cambro-Ordovician time.
The SSS and sulfide sulfurs have often higher δ³⁴S values than the Mesozoic-Cenozoic ore sulfur (Ishihara et al., 2000). Since carbonate rocks are very reactive with circulating hydrothermal ore solution, high δ³⁴S values of the Korean ore deposits might be caused to some extent by ³⁴S enrichment from the host carbonates, resulting in the low SSS contents observed.  相似文献   

Negative Ce Anomaly in the Indian Banded Iron Formations: Evidence for the Emergence of Oxygenated Deep-Sea at 2.9-2.7 Ga     

Yasuhiro KATO  Takashi KANO  Keitaro KUNUGIZA 《Resource Geology》2002,52(2):101-110

Abstract: Major and rare earth element contents are reported for Late Archean banded iron formations (BIFs) in the Bababudan Group of the Dharwar Craton, South India. The BIFs are mostly composed of SiO₂ (average1ρ = 54.88.1 wt%) and Fe₂O₃* (44.38.2 wt%). The Al₂O₃ and TiO₂ contents are remarkably low, suggesting that detrital components were starved during the BIF deposition. The BIFs have a LREE-enriched pattern with a relatively high (La/Yb)_N (6.644.07). Total REE concentrations (RE) vary from 5.2 to 65.3 ppm. The REE patterns are characterized by the presence of a very large negative Ce anomaly (Ce/Ce*: 0.13-0.83) and a positive Eu anomaly (Eu/Eu*: 0.96-2.45). The Eu/Eu* decreases and (La/Yb)_N increases with a increase of RE. These correlations of REE indices are similar to those of modern hydrothermal iron-rich sediments near a mid-ocean ridge (MOR). Greenstones associated with the BIFs have MORB-like geochemical features. These geochemical and geological lines of evidence indicate that the depositional site of the BIFs was remote from a continent and/or island arc and that the BIFs were in situ hydrothermal sediments near a MOR. A striking negative Ce anomaly in the BIFs indicates that oxygenated deep-sea environments emerged at 2.9-2.7 Ga. The existence of contemporaneous Mn deposits in the Dharwar Craton supports this assertion. Our scenario of oxygen in the Earth's surface of the Late Archean is different from long-held notion that the atmosphere and ocean were persistently anoxic throughout the Archean.  相似文献