热带东太平洋中国多金属结核开辟区深海成矿环境的氨基酸表征     

金海燕  陈建芳  于晓果  王奎  周怀阳  李宏亮  王文亮 《沉积学报》2007,25(5):737-744

为了解中国多金属结核开辟区沉积物有机质活性及深海成矿沉积环境特征，使用高效液相色谱（HPLC）法分析了表层沉积物氨基酸的组成状况。结果显示该区表层沉积物中氨基酸与氨基糖含量(干样)均较低，分别在0.30～0.59 mg·g-1及 0.10～0.17 mg·g-1之间。其中以中性氨基酸占绝对优势，占50%以上，其次为酸性氨基酸和含氢氧基氨基酸，分别占17%和11%，碱性氨基酸占9%，芳香与含硫氨基酸均在5%以下,表明深海沉积环境为氧化环境，且偏碱性条件。表征有机质活性的Asp/β Ala、Glu/γ Aba及DI值（（Glu+Phe+Leu+Ala+Val）/ (β Ala+γ Aba)）分别为1.1～1.9，0.8～2.2和1.4～2.9，表明该区有机质成熟度已很高。蛋白氨基酸/非蛋白氨基酸的比值为1.0～2.0，葡萄糖胺/半乳糖胺比值则在1.7～3.0之间变化，表明该海区有机质经过强烈的细菌改造，即海区存在强烈的细菌活动，活性较低，表征了多金属结核有机—微生物成矿的可能性。  相似文献   

Stratigraphy and geochemistry of a sequence of Quaternary palaeosols in the Lower Teleki Valley,Mount Kenya,East Africa — Implications for interregional correlations     

W. C. Mahaney  R. G. V. Hancock Slowpoke  N. Rutter  K. Sanmugadas 《第四纪科学杂志》1991,6(3):245-256

The relative weathering of a sequence of five palaesols formed in different parent materials, including bedrock of phonolitic composition, is described and assessed. The three lower palaeosols (units 3–5) are considered to be of interglacial origin. The saprolite (unit 5), in phonolite, formed prior to deposition of the lower Brunhes-age till, is considered to be as old as the Brunhes Matuyama boundary (0.73 myr). The other two palaeosols in this group (units 3 and 4), derived from loess and till, respectively, formed over middle to late Brunhes time under palaeoclimates that were wetter (and presumably warmer), and of sufficient leaching power to move clay, as well as organically complexed extractable Fe and Al. The palaeosols in unit 3 are more complex than the lower ones. Their upper and lower horizons have about the same chemical composition as the lowest two palaeosols, while the middle horizons are similar to the upper two palaeosols (units 1 and 2). Radiocarbon dates for unit 3 are considered to be too young to account for the strong weathering in the upper and lower horizons. This interpretation is supported by high D/L ratios of aspartic acid. Overlying sediments, emplaced by episodic colluvial (unit 2) and slope wash (unit 1) processes, are less weathered; the lower colluvial unit in this group was emplaced during the late stade of the last glaciation. The surface sediments were emplaced more recently during the same interval and weathered mainly during the post-glacial period. Tentative correlations with core 82PCS18 from the Canary Basin show that upper unit 3 is probably equivalent to Isotope Stage 5e, lower unit 3 to Isotope Stage 7, unit 4 to Isotope Stage 8, and unit 5 to Isotope Stage 9. Units 1 and 2 are firmly correlated with Isotope Stage 2.  相似文献   

硅灰石在氨基酸水溶液中的电化学及溶解作用研究   总被引：3，自引：0，他引：3  

李国武  董发勤  彭同江  万朴  宋功保 《岩石矿物学杂志》2000,19(3):206-211

在模拟人体温度３７℃条件下,进行硅灰石纤维粉尘与氨基酸作用的实验研究,测定在７２ｈ内溶解过程中ｐＨ值和电导率（к）的变化。结果表明,硅灰石纤维矿物在氨基酸中发生的溶解作用与酸的性质有关,酸性氨基酸对矿物的溶解能力最强,中性次之,碱性最弱。硅灰石在酸性和碱性氨基酸中８ｈ左右出现溶解饱和点,而在中性氨基酸中７２ｈ内无溶解饱和点,溶解度具有随时间的增加而呈线性增长的趋势。硅灰石的这种溶解特征表明,硅灰石  相似文献   

翡翠贻贝软体部营养成分的研究     

庆宁  林岳光  金启增 《热带海洋学报》2000,19(1)

分析了翡翠贻贝Pernaviridis软体部的营养成分。其中蛋白质及氨基酸含量较高 ,必需氨基酸占总氨基酸量的 33 2 %。粗脂肪和脂肪酸含量丰富 ,特别是EPA和DHA总量占总脂肪酸的 2 6 0 1 %。除富含Ca,Mg ,Fe等无机元素外 ,Se的含量也较高。  相似文献   

海水中铁(Ⅲ)-氨基酸盐配合物的光化学反应研究   总被引：2，自引：1，他引：1  

杨桂朋  赵润德  陆小兰  高先池 《海洋学报》2005,27(3):46-51

系统研究了高压汞灯模拟日光照射下铁(Ⅲ)-氨基酸盐配合物在天然海水中的光化学反应情况,结果发现,在氨基酸盐配体的存在下,铁(Ⅲ)会发生光化学反应生成还原态的铁(Ⅱ),同时生成的铁(Ⅱ)会被容器内的氧再氧化为铁(Ⅲ).铁(Ⅲ)的光还原反应速率会受到配体浓度、pH和光强以及温度的影响.在氨基酸与铁(Ⅲ)浓度配比大于2的情况下,在铁(Ⅲ)氨基酸盐配合物的光还原反应初期铁(Ⅱ)浓度的增长符合一级动力学反应规律,100min后浓度趋于稳定.光强升高和pH降低都能加快光还原速率,而改变温度则基本上对光还原反应速率无影响,这证明铁(Ⅲ)的光还原反应为一自由基引发的电子转移过程.  相似文献   

南极绿藻中类菌胞素氨基酸对UV-B胁迫的响应     

顾智强  张振华  徐琰雯  顾梦娇  徐强  朱自强  钟伯坚 《海洋科学》2018,42(12):37-46

南极上空臭氧层的破坏导致了紫外辐射日益增强,高强度的UV-B辐射会造成细胞中DNA的损伤,影响蛋白质、脂类和色素的代谢过程。生长在南极的绿藻具有一系列防御机制以应对增强的UV-B辐射,其中类菌胞素氨基酸(Mycosporine-like amino acids, MAAs)是一类重要的紫外防御物质。为探究类菌胞素氨基酸对UV-B辐射的响应,本文以南极冰藻(Chlamydomonassp.ICE-L)、针丝藻(Raphidonema nivale Lagerheim, NIES-2290)和胶球藻(Coccomyxa subellipsoidea E.Acton, NIES-2166)三种生活在南极的绿藻为材料,采用UV-B辐射胁迫(强度0.35 W/m~2,短时处理3 h),并通过液相色谱-质谱联用法检测类菌胞素氨基酸的种类和含量的变化。Mycosporine-glycine为三种南极绿藻中共有的MAAs,在UV-B辐射胁迫下三种南极绿藻中Mycosporine-glycine含量变化不尽相同,表明不同的南极绿藻中MAAs对UV-B辐射的响应各有其特性。首次在绿藻(南极冰藻和胶球藻)中检测到Gadusol。Gadusol作为MAAs的合成前体,它的合成积累使得生活在海冰环境的南极冰藻和胶球藻具有良好的抗UV-B辐射能力。其中南极冰藻抗紫外能力最强,这可能得益于不同MAAs间的动态转化,含量升高的Palythine及Usujirene/Palythene可能对南极冰藻的紫外屏蔽起着至关重要的作用。  相似文献   

长肋日月贝的营养成分分析及评价          下载免费PDF全文

朱彩艳  王雨  张殿昌  苏天凤  吴开畅 《海洋科学》2011,35(3):87-91

对野生长肋日月贝(Amusium pleuronectes)的闭壳肌和贝肉其他部分的基本营养成分进行分析.结果表明:闭壳肌的平均质量分数为18.13%±2.15%,超过优良养殖海湾扇贝"中科红".闭壳肌的蛋白质质量比(干质量)为847.62 g/kg,贝肉其他部分蛋白质质量比为662.50 g/kg.必需氨基酸与非必需...  相似文献   

BOOK REVIEWS     

《The Professional geographer》1987,39(2):238-266

Book Reviewed in this article: Women, Work, and Ideology in the Third World . Haleh Afshar, ed. The Birth of the National Park Service. The Founding Years 1913–33 . Horace M. Albright Theatres of Accumulation: Studies in Asian and Latin American Urbanization . Warwick Armstrong and T.G. McGee. New Tools for Social Scientists, Advances and Applications in Research Methods . William D. Berry and Michael S. Lewis -Beck , eds . Uncertain Dimensions: Western Overseas Empires in the Twentieth Century . Raymond F. Betts. Geography of Sugar Cane . Helmut Blume. The Mines of Neptune: Minerals and Metals from the Sea . Elisabeth Mann Borgese. Geographical Dimensions of Energy . F.J. Calzonetti and B.D. Solomon, eds. Statistical Methods for Geographers . W. A. V. Clark and P. L. Hosking. In The Wake of Columbus, Islands and Controversy . John DeVorsey, Jr., and John Parker, eds. Housing, States and Localities . Peter Dickens, Simon Duncan, Mark Goodwin and Fred Gray. Physician Location and Specialty Choice . Richard L. Ernst and Donald E. Yett. Practical Ecology for Geography and Biology: Survey, Mapping, and Data Analysis . D.D. Gilbertson , M. Kent and F.B. Pyatt Large Scale Water Transfers: Emerging Environmental and Social Experiences . Genady N. Golubev and Asit K. Biswas, eds. The Nature of the Environment . Andrew Goudie. Planning for Population Change . W.T.S. Gould and R. Lawton. The Niger and its Neighbors: Environmental History and Hydrobiology. Human Use and Health Hazards of the Major West African Rivers . A.T. Grove, ed. Remote Sensing of Ice and Snow . Dorothy K. Hall and Jaroslav Martinec. Atlas of Antebellum Southern Agriculture . Sam Bowers Hilliard. Galilee Divided; The Israel-Lebanon Frontier, 1916-1984 . Frederic C. Hor . Plains Country Towns . John C. Hudson. Agricultural Geography: A Social and Economic Analysis . Brian W. Ilbery. Industry in the 1980s: Structural Change and Interdependence . U.N. Industrial Development Organization. Crabgrass Frontier: The Suburbanization of the United States . Kenneth T. Jackson. The Industrial Geography of Italy . Russell King. Studies in Linguistic Geography: The Dialects of English in Britain and Ireland . John M. Kirk, Stewart Sanderson, J.D.A. Widdowson, eds. Tourism: A Community Approach . Peter E. Murphy. Cities and Services: The Geography of Collective Consumption . Steven Pinch. An Historical Geography of Europe 1800–1914 . Norman J. G. Pounds. An Introduction to Human Ecology Research on Agricultural Systems in Southeast Asia . A. Terry Rambo and Percy E. Sajise, eds. Discovering Past Landscapes . Michael Reed, ed. Managing the Ocean: Resources, Research, Law . Jacques G. Richardson, ed. Carta fitosociologica de la transecta botanica de la Patagonia Austral . F.A. Roig , Juan Anchorema , Orlando Dollenz , A.M. Faggi and Eduardo Mandez Intermetropolitan Migration in Canada: Changing Determinants over Three Decades . R. Paul Shaw. Chinese Cities—The Growth of the Metropolis since 1949 . Victor F. Sit, ed. Urbanization in the World-Economy . Michael Timberlake, ed. The Al Business: Commercial Uses of Artificial Intelligence . Patrick H. Winston and Karen A. Prendergast, eds.  相似文献   

南太平洋东劳扩张中心表层沉积物氨基酸组成所揭示的生物地球化学意义   总被引：2，自引：0，他引：2  

王丽玲  杨群慧  付少英  胡建芳 《地球化学》2012,(1):23-34

通过对南太平洋劳盆地东劳扩张中心(ELSC)表层沉积物进行水解氨基酸(THAA)分析、氨基酸对映异构体比值(D/L)分析及总有机碳(TOC)分析,对沉积物中氨基酸含量和来源、有机质降解程度和采样区域生物活动性及温度特征等问题进行了探讨。结果表明,ELSC区域样品中有机质含量较低,TOC含量为0.70～2.15 mg/g(干重),THAA含量为30～511μg/g(干重),热液活动区域原位化能合成作用对沉积物中氨基酸的相对富集有较大的贡献。沉积物中THAA含量和生物群落活动状况与分布范围有关,样品矿物组分对氨基酸的保存亦有一定的影响。由于各采样点热液活动、沉积物类型、生物群落的类型及分布均有所不同,样品中个体氨基酸的组成分布特征有较大差异。以TOC中氨基酸态碳所占百分比TAAC%作为指标对样品有机质活性进行了判别,热液喷口区域样品有机质新鲜程度要普遍高于非热液喷口区域样品,高温热液环境对氨基酸降解途径有一定的影响。样品中个体氨基酸D/L比值变化范围较大,天冬氨酸(Asp)为0.08～0.46,谷氨酸(Glu)为0.06～0.19,丝氨酸(Ser)为0.01～0.81,丙氨酸(Ala)为0.10～0.30。根据样品中THAA含量、TAAC%及个体氨基酸的D/L比值可以粗略判断生物活动性的大小及细菌对THAA的相对贡献,但并不能准确地区分热液活动活跃区域和非活跃区域在温度和生物活动性方面的差异。  相似文献   

罗非鱼鱼鳞胶制备降血压胶原肽的工艺及酶解物活性     

吴靖娜  许永安  王茵  苏捷 《广东海洋大学学报》2012,(1):75-80

以罗非鱼鱼鳞胶为原料,制备对血管紧张素转换酶(ACE)有抑制活性的降血压肽。以水解度(DH)及ACE抑制率为指标,筛选水解鱼鳞胶的最适酶种,并对其水解工艺条件进行优化;采用超滤技术对所制备的降血压肽进行分离纯化,比较不同组分的ACE抑制率,测定高ACE抑制率组分的氨基酸组成,并运用MALDI-TOF-MS法分析其分子质量分布。结果表明,复合蛋白酶是水解鱼鳞胶最适酶种,在50℃、pH7.5、料液质量体积比1∶5、酶与底物质量比(mE/mS)1.5%条件下,酶解6 h,酶解液的ACE抑制作用最强,其水解度DH 73%,ACE的抑制率76.15%。酶解液经超滤分离所获得的分子质量小于2 000 u的组分对ACE抑制率最高,达83.15%;该组分的氨基酸主要含有Gly和Pro,含量分别为22.04%和11.40%;该组分分子质量范围为1 300~2 000 u。  相似文献