高效液相色谱法测定地下水中苯并(a)芘的不确定度评定   总被引：1，自引：1，他引：0  

冯静  王海娇  何超君  张激光 《岩矿测试》2011,30(5):617-622

通过对高效液相色谱法测定地下水中苯并(a)芘含量的全过程分析,确定了测定结果不确定度的来源。采用不确定度连续传递模型,对引入的不确定度分量进行评定,并采用最小二乘法对标准曲线进行拟合,确定了地下水中苯并(a)芘含量标准不确定度由样品取样量、样品定容体积及测定体积、样品重复性测定、标准溶液浓度和标准曲线拟合误差6部分不确定度合成。通过对2个不同含量样品测定结果不确定度评定,证明苯并(a)芘含量越低,测定结果的相对标准不确定度越大;且样品重复性测定和标准曲线拟合误差是测定结果不确定度的重要来源。  相似文献   

乙腈-硫酸铵-水双水相萃取-高效液相色谱法测定地下水中苯并(a)芘和苯并(e)芘     

王磊  安彩秀  朱裕穗  肖凡  刘金巍 《岩矿测试》2013,32(2):325-329

传统的液液萃取技术主要采用与水不相溶的有机溶剂作萃取剂,这种异相萃取的传质速率一般较低,需反复振荡或多次萃取.本文建立了以乙腈-硫酸铵-水的双水相萃取体系高效液相色谱法测定地下水中苯并(a)芘和苯并(e)芘的方法,以密度比水小的乙腈为萃取剂,将其与水样混合(互溶)获得乙腈-水体系,然后加入硫酸铵,溶液澄清、分相后取上层有机相(乙腈)进样分析.考察了萃取剂的选择、双水相的形成条件、离子强度以及pH等对测定结果的影响.两种化合物线性范围为2.00～ 400.00 ng/mL,相关系数大于0.999.方法检出限为0.012～0.020 ng/mL,平均回收率为94.6％～97.3％,相对标准偏差为1.3％ ～2.5％.与传统萃取方法相比,该方法具有操作流程简单、快速的特点,可实现对野外环境水样进行原地样品前处理.  相似文献   

一株多环芳烃芘降解菌的鉴定及其降解特性研究     

卢仕严  曹永军  招嘉佩  何红  孙省利 《海洋科学》2014,38(8):21-25

从红树植物红海榄叶片中分离一株对芘具有较好降解作用的海洋细菌,命名为B11,并对其菌体特征、生长条件及降解效能等进行了系统研究。结果发现该菌株为革兰氏阴性菌,结合其生理生化特征和16S rDNA序列比对,表明此菌株属于交替单胞菌属(Alteromonas sp.)。菌株在芘的起始浓度为100 mg/L,pH为中性或偏碱性条件下,盐度35时对芘的降解作用最强。外加碳源对B11对芘的降解效果都具有一定的抑制作用,其中水杨酸的抑制作用更为显著。综合菌株B11的生长特性和降解效能,初步认为B11菌株较适合用于降解多环芳烃芘,可用于红树植物多环芳烃生态污染的原位修复。  相似文献   

On the inverse dynamo problem in a simplified mean-field model     

R. Kaiser 《地球物理与天体物理流体动力学》2013,107(5):477-487

Inverse dynamo theory seeks to gain information about the motion of a liquid conductor from measurements of the magnetic field in the surrounding vacuum. We consider here a highly simplified model problem, namely a steady α²-dynamo in plane geometry with an α-field varying only in the z-direction normal to the conductor–vacuum interface. Based on perturbation theory about constant-α solutions, we find as many integral conditions on α(z) as modes are present in the vacuum field. This result is corroborated by the complete solution of a special case.  相似文献   

Mean-field equations for weakly nonlinear two-scale perturbations of forced hydromagnetic convection in a rotating layer     

Vladislav Zheligovsky 《地球物理与天体物理流体动力学》2013,107(5):489-540

We consider stability of regimes of hydromagnetic thermal convection in a rotating horizontal layer with free electrically-conducting boundaries, to perturbations involving large spatial and temporal scales. Equations governing the evolution of weakly nonlinear mean perturbations are derived under the assumption that the α-effect is insignificant in the leading-order (e.g. due to a symmetry of the system). The mean-field equations generalise the standard equations of hydromagnetic convection: New terms emerge – a second-order linear operator representing the combined eddy diffusivity and quadratic terms associated with the eddy advection. If the perturbed CHM regime is nonsteady and insignificance of the α-effect in the system does not rely on the presence of a spatial symmetry, the combined eddy diffusivity operator also involves a nonlocal pseudodifferential operator. If the perturbed CHM state is almost symmetric, α-effect terms appear in the mean-field equations as well. Near a point of a symmetry-breaking bifurcation, cubic nonlinearity emerges in the equations. All the new terms are in general anisotropic. A method for evaluation of their coefficients is presented; it requires solution of a significantly smaller number of auxiliary problems than in a straightforward approach.  相似文献   

沙埋对策勒绿洲-沙漠过渡带两种建群种植物特征与格局的影响          下载免费PDF全文

韩章勇  王雪芹  杨帆  马洋  刘进辉 《干旱区地理》2013,36(6):1076-1083

以塔克拉玛干沙漠南缘策勒绿洲-沙漠过渡带为研究区,在半固定沙地、半流动沙地和流动沙地选择了3个50 m×50 m的典型样地,分别代表轻度、中度和强度3种沙埋条件。每个样地内确定植物种类组成,测定两种建群种植物的高度和冠幅,同时对相应的灌草丛沙堆进行形态测量;利用全站仪采集所有植物的空间点坐标数据,运用Ripley’s [K（t）]函数点格局分析,研究沙埋对两种建群种植物特征与格局的影响。结果表明：随着沙埋强度的增加,疏叶骆驼刺和花花柴两个建群种植株数量减小,数量比例从以花花柴为主向以骆驼刺为单优势种群方向发展,死亡植株比例从半固定沙地的14.5%升高到流动沙地的40.3%;疏叶骆驼刺和花花柴植株高度和冠幅从半固定沙地到半流动沙地有所降低,但疏叶骆驼刺在流动沙地中又表现出增加趋势;对应的灌草丛沙堆体积随沙埋强度增加而变大,沙堆形态从多种类型并存向带有风影沙尾的蝌蚪形为主转变;花花柴和骆驼刺均以聚集分布应对风积沙埋的威胁,两种植物的种群间关系并不明显。总体来看,风积沙埋有碍于两种建群种植物的繁殖与生长,但骆驼刺具有更强的耐沙埋能力,特别是在流动沙地中留存下来的骆驼刺植物单体明显大于半固定和半流动沙地。集群分布的植物沙堆往往从基部合并,导致相对密集的植物分布区总与局部凸起的地形相对应,是风沙环境中植物群体与风积沙埋相互作用的结果。  相似文献   

Optimization of Ethoxyresorufin‐O‐deethylase Determination in the Microsomes of Earthworms and Its Induction by Polycyclic Aromatic Hydrocarbons          下载免费PDF全文

Xiufeng Cao  Yufang Song  Shihua Fan  Jianrong Kai  Xiaoxia Yang  Lang Chen 《洁净——土壤、空气、水》2014,42(8):1121-1125

  相似文献   

Congruent,decreasing trends of gentoo penguins and Crozet shags at sub-Antarctic Marion Island suggest food limitation through common environmental forcing     

《African Journal of Marine Science》2013,35(2):225-231

Numbers of gentoo penguins Pygoscelis papua and Crozet shags Phalacrocorax [atriceps] melanogenis breeding annually at Marion Island, one of South Africa's Prince Edward Islands in the South-West Indian Ocean, were strongly correlated over 19 split-years from 1994/1995 to 2012/2013. Both species decreased between the mid-1990s and the mid-2000s, exhibited a partial recovery in the late-2000s and then decreased to their lowest recorded levels in 2012/2013. In both instances, the partial recoveries in the late-2000s were associated with improved breeding success. At a colony of gentoo penguins, breeding success was negatively correlated with the date of arrival of adults to breed. Gentoo penguins and Crozet shags are demersal feeders in inshore waters around Marion Island and there is considerable overlap in the composition of their diets. Therefore, trends in their populations may be driven by food availability, which is likely to be influenced by benthic production around the island. We propose that, in South Africa, and based on the current assessment, the Crozet shag, which elsewhere breeds only at the Crozet Islands, is now Critically Endangered, and the more widely ranging gentoo penguin is Endangered.  相似文献   

利用MAPGIS7．0控件开发应用程序     

张勇 《贵州地质》2009,26(3):241-242

MAPGIS是武汉中地信息工程有限公司开发的GIS基础平台软件系统,提供了多种二次开发方式。应用人员可根据自己的情况选用其中一种或组合多种方式进行开发,本文介绍了利用C#．net和MAPGIS7．0组件／控件进行二次开发的方法。  相似文献   

基于修正[BQ]值的软岩隧道挤压变形预测     

陈卫忠  田云  王学海  田洪铭  曹怀轩  谢华东 《岩土力学》2019,40(8):3125-3134

高地应力条件下,深埋隧道破碎围岩容易发生挤压大变形。挤压变形量的预测对于工程的设计与施工至关重要。经验预测方法因其形式简单、使用方便得到广泛应用,现有隧道挤压变形预测的经验法具有以下特点:(1)考虑的影响因素较少,多数仅能对挤压变形进行分级,无法给出挤压变形量;(2)现有经验变形预测方法多基于围岩Q分级系统,不能直接应用于国内的BQ分级系统。因此,基于对国内外100多条隧道变形监测数据的分析,提出一种新的适用于国内岩体基本质量指标修正值[BQ]的挤压变形预测方法。该方法综合考虑了隧道埋深、跨度、围岩强度应力比、地下水、岩体结构面等影响岩体挤压变形的多种因素。通过与多条大变形隧道监测结果的对比分析,验证了预测方法的合理性,研究成果对高地应力软岩隧道确定支护强度及提前采取超前加固措施具有十分重要的指导作用。  相似文献