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71.
A. Hofzumahaus T. Brauers U. Platt J. Callies 《Journal of Atmospheric Chemistry》1992,15(3-4):283-298
The latitudinal variation of the photolysis frequency of ozone to O(1D) atoms, J(O1D), was measured using a filter radiometer during the cruise ANT VII/1 of the research vessel Polarstern in September/October 1988. The J(O1D) noon values exhibited a maximum of 3.6×10-5 s-1 (2 sr) at the equator and decreased strongly towards higher latitudes. J(O1D) reached highest values for clean marine background air with low aerosol load and almost cloudless sky. The J(O1D) data, measured under these conditions and a temperature of 295 K, can be expressed by: % MathType!MTEF!2!1!+-% feaafiart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGaamOsaiaacI% cacaqGpbWaaWbaaSqabeaaiiaacqWF8baFaaGccaqGebGaaeykaiaa% bccacqWF9aqpcaqGGaGaaeyzaiaabIhacaqGWbGaaeiiaiaabUhacq% GHsislcaaI4aGaaiOlaiaaicdacaaIYaGaeyOeI0IaaGioaiaac6ca% caaI4aGaaiiEaiaaigdacaaIWaWaaWbaaSqabeaacqGHsislcaaIZa% aaaOGaaeiiaiaabIhacaqGGaGaam4uaiabgUcaRiaaiodacaGGUaGa% aGinaiaacIhacaaIXaGaaGimamaaCaaaleqabaGaeyOeI0IaaGOnaa% aakiaadofadaahaaWcbeqaaiaaikdaaaGccaGG9bGaaeikaiaaboha% daahaaWcbeqaaiabgkHiTiaaigdaaaGccaGGPaaaaa!5EE9!\[J({\text{O}}^| {\text{D) }} = {\text{ exp \{ }} - 8.02 - 8.8x10^{ - 3} {\text{ x }}S + 3.4x10^{ - 6} S^2 \} {\text{(s}}^{ - 1} )\] where S represents the product of the overhead ozone column (DU) and the secant of the solar zenith angle. The meridional profile of the primary OH radical production rate P(OH) was calculated from the J(O1D) measurements and simultaneously recorded O3 and H2O mixing ratios. While the latitudinal distribution of J(O1D) and water vapour was nearly symmetric to the equator, high tropospheric ozone levels up to 40 ppb were observed in the Southern Hemisphere, SH, resulting in higher P(OH) in the SH. 相似文献
72.
青藏高原腹地湖泊沉积对第四纪晚期古季风变化的响应 总被引:2,自引:0,他引:2
通过对青藏高原腹地的综合科学考察和对中心钻孔岩芯剖面的最新研究,用层序地层学与年代地层学和气候地层学相结合的方法,分辨出可可西里地区湖泊沉积记录(孔深7.25 m)的第四纪晚期距今3万余年以来的古气候变化,沉积物磁化率等因子综合表征的高原古季风变化是波动发展的,发生在仙女木期地质环境事件中的季风活动具有强烈暴发的特点,是高原季风发展中的突变事件,而且地表热点效应对其起到了激发作用。综合分析的研究成果表明,它的变化频谱与激变因子及其运行机制是伴随着青藏高原地质效应的演变而发展的,为研究第四纪冰消期以来的气候变化提供了新的信息。 相似文献
73.
Treatment of high fluoride concentration wastewater by layered double hydroxides: Mechanism studies 总被引:1,自引:0,他引:1
Liang LU Jing HE 《中国地球化学学报》2006,25(B08):160-161
An appropriate concentration of fluoride in drinking water is required to prevent dental cavities, but long-term ingestion of water that contains more than a suitable level of fluoride can cause bone disease and mottling of the teeth. Fluoride ions can be found in wastewater from the fluoride chemical industry, as well as the semiconductor, metal processing, fertilizer, and glass-manufacturing industries. The discharge standard for fluoride in industrial wastewater in China is 10 mg/L. Efficient treatment of fluoride-containing wastewater is therefore of major concern in China, following the rapid development of the fluoride chemical industry. Several methods have been used to remove fluoride from water, such as adsorption, chemical precipitation, electrodialysis, ion exchange and electrochemical processes. Layered double hydroxides (LDHs) are anionic clays with high anion exchange capacities which are effective adsorbents for removal of a variety of anionic pollutants. LDHs have been studied as potential adsorbents for removing toxic anionic species such as CrO4^2-, TcO4^-, SeO3^2-, pesticides, and anionic surfactants from aqueous systems. One of the main attractions of using LDHs for fluoride removal, is that unlike other chemical treatment methods, no chemical sludge should be produced. In the present study, an attempt was made to investigate the mechanism of fluoride removal by LDHs under different conditions using batch methods. In addition, the release of fluoride adsorbed on LDHs by treatment with an aqueous solution of Na2CO3 was studied. The residual fluoride was found to be 10 mg/L in a solution with an initial concentration of 1000 mg/L, which meets the discharge standard for fluoride in industrial wastewater in China. 相似文献
74.
CHEN Tianhu XU Huifang WANG Yifeng QING Chengsong FAN Mingde CHEN Gang 《《地质学报》英文版》2006,80(2):170-174
Although hydrotalcite, or layered double hydroxides (LDHs), is not a common mineral, it is an important material that can be easily synthesized in laboratory. In this study, structural evolvement and BET surface area changes of heat treated Mg/AI-LDH is evaluated by XRD, TEM and N2-BET analyses. The results indicate that the magnesium-aluminum LDH with carbonate as interlayer anion, periclase-like oxides was formed at temperatures of 400-800℃. Meanwhile, 2-3 nanometer mesoporous were formed during decomposition of LDH. However, the heat treated samples still preserve the morphology of the original LDH plates. Periclase-like formed from LDH heat treatment may re-hydrolyze and recover the structure of LDH. However, crystallinity of the recovered LDH is lower than that of the original LDH. This heat treatment will result in formation of (Mg, Al)-oxide nano-crystals and nanopores among the nano-crystals. When heating temperature exceeds 1000, the periclase-like (Mg, Al)-oxide is transformed into a composite with periclase (MgO) and spinel phases. The periclase can be re-hydrolyzed and dissolved in HCl solution. After acid treatment, the sample with a high surface area is composed of spinel nano-crystals and nanopores among them. Our results will provide a new and economic way to synthesize mesoporous materials through pathways of phase transformation of precursor materials with different composition. 相似文献
75.
A Review of Studies Dealing with Tree Rings and Rockfall Activity: The Role of Dendrogeomorphology in Natural Hazard Research 总被引:1,自引:0,他引:1
M. Stoffel 《Natural Hazards》2006,39(1):51-70
Over the last few years, rockfall research has increasingly focused on hazard assessment and risk analysis. Input data on
past rockfall activity were gathered from historical archives and lichenometric studies or were obtained through frequency–volume
statistics. However, historical records are generally scarce, and lichenometry may only yield data with relatively low resolutions.
On forested slopes, in contrast, tree-ring analyses may help, generally providing annual data on past rockfall activity over
long periods. It is the purpose of the present literature review to survey the current state of investigations dealing with
tree-ring sequences and rockfall activity, with emphasis on the extent to which dendrogeomorphology may contribute to rockfall
research. Firstly, a brief introduction describes how dendrogeomorphological methods can contribute to natural hazard research.
Secondly, an account is provided of the output of dendrogeomorphological studies investigating frequencies, volumes or spatial
distributions of past rockfall activity. The current and potential strengths of dendrogeomorphology are then presented before,
finally, the weaknesses of tree rings as natural archives of past rockfall activity are discussed and promising directions
for further studies outlined. 相似文献
76.
Assessing the Vibrational Frequencies of the Cathedral of Cologne (Germany) by Means of Ambient Seismic Noise Analysis 总被引:1,自引:0,他引:1
Andreas Fäcke Stefano Parolai Sandra M. Richwalski Lothar Stempniewski 《Natural Hazards》2006,38(1-2):229-236
Ambient seismic noise measurements were conducted inside the Cathedral of Cologne (Germany) for assessing its frequencies
of vibration and for checking whether these occur in the range where soil amplification is expected. If this is the case,
damages may increase in case of an earthquake due to an increased structural response of the building. Analysis of the ratio
between the horizontal and vertical components of the spectra recorded at stations located inside the building as well as
the ratio between the corresponding components of the spectra recorded simultaneously inside the building and at a reference
station placed in the basement of the cathedral indicated several modes of vibration. Facilitated by these results an assessment
of the seismic vulnerability was attempted for a 2D ground motion scenario using the finite element method. 相似文献
77.
The degree to which dust emissions are controlled by geomorphic conditions, wind environments and land use was investigated using the dust storm frequency (DSF) and data from more than 300 meteorological stations throughout northern China. Our analysis showed that most dust emissions originated in gobi deserts that developed in piedmont alluvial fans of the Kunlun, Qilian and Helan mountains. Dust emissions are low from other gobi desert regions, such as the northern Gurbantunggut and eastern Taklimakan, where high vegetation coverage restrained dust emissions or where dust-size particles are not abundant after a long period of strong wind erosion. Sandy deserts with relatively high vegetation coverage or an extensive cover by mobile sands are not a major dust source. Although the highest dust emissions did not appear in regions with the highest wind energy, DSF trends in each region from 1960 to 2003 were closely related to local wind activity. DSF was low in regions with high levels of human activity, where the mean DSF from 1960 to 2003 did not exceed 4 days/year; even from the 1960s to the early 1970s, the period with the greatest DSF, frequency did not exceed 8 days/year, which indicates that extensive land use did not contribute to DSF. The low DSF in these areas might result from the fact that although land use could produce abundant fine soil fractions, vegetation coverage and soil moisture remained higher than in the gobi deserts of arid China, thereby decreasing dust-storm occurrence. 相似文献
78.
Flood seasonality and generating conditions in the Tay catchment, Scotland from 1200 to present 总被引:1,自引:0,他引:1
Lindsey J McEwen 《Area》2006,38(1):47-64
The new maximum recorded river flows in Scotland since 1988 have triggered widespread interest in whether floods are becoming more frequent and in the conditions that generate floods of different magnitudes and frequencies. There are questions about the longer-term variability in flood-generating characteristics, and whether there are past analogues for present hydroclimatic variability. The present paper builds on previous work reconstructing a detailed historic flood chronology for the Tay, the largest catchment in Scotland, and its tributaries over the past 800 years, extending the gauged discharge record (1952 onwards). It categorizes flood-generating factors in the Tay catchment and analyses the hydro-meteorological conditions that have generated extreme and moderate floods over a historical period. This work is placed in a broader literature context of historical 'climaxes of storminess', periods of higher storm frequency, flood patterns observed in Scotland and Europe during the Little Ice Age and longer-term rainfall and temperature patterns. The paper concludes that the variability in flood-generating characteristics is highly dependent on the timescale of observation. Inevitably the relative dominance of winter and early spring flooding can vary from year to year and within specific time-periods, but so can the level of augmentation of the flood series with summer and autumn floods to produce notable 'flood years' and flood clusters. The Tay provides a good 'all-Scotland surrogate' for historical flood patterns, reflecting its gathering areas in eastern and western Scotland. The value of a historical approach to the assessment of flood seasonality and generating characteristics is clearly demonstrated. 相似文献
79.
VSP资料约束地层反滤波研究 总被引:2,自引:0,他引:2
WANG Yu HAN Li-guo CUI Jie College of GeoExploration Science Technology Jilin University Changchun China 《吉林大学学报(地球科学版)》2006,(Z2)
浅地表的低速带和地层滤波作用导致地震信号的能量衰减,地震子波的高频快速衰减,速度频散的子波变形,对地震底层分析带来了严重的影响。地层反滤波算法就是为了消除地层对子波的影响,利用VSP中的直达下行波推算出每个地层滤波算子,计算出各个地层滤波算子的反算子,然后利用这些反算子恢复出地表记录中损失掉的高频成分,减弱地层滤波对波形的影响,增加地表记录的频率成分和波形的准确度。分析实际地震资料表明,经过地层反滤波处理后的记录频率成分明显提升,地质构造更加准确、清晰。 相似文献
80.
HUANG Ling YANG Guang-da HAN Li-guo .Geophysical Exploration Company of Jilin Petroleum Group Co. Ltd Songyuan China .Jilin Petroleum Group Company Songyuan China .College of GeoExploration Science Technology Jilin University Changchun China 《吉林大学学报(地球科学版)》2006,(Z2)
深层地震勘探野外资料采集的关键是在保证原始资料一定信噪比的基础上,同时兼顾分辨率,激发井深是决定资料品质的重要因素之一。通过对虚反射滤波作用分析,提出了充分利用虚反射能量设计最佳激发井深,增强下传地震波能量的采集方法。理论分析和试验资料表明,在高速层下4~7m的最佳激发岩性深度是深层勘探的理想井深。 相似文献