不同有机酸对矿物溶解的动力学实验研究   总被引：5，自引：0，他引：5  

陈传平  固旭  周苏闽  刘建平 《地质学报》2008,82(7):1007-2008-01-30

用石英、微斜长石和方解石混合颗粒模拟碎屑组分分别与不同有机酸水溶液进行溶蚀实验,以比较储集层内不同矿物在含低分子量有机酸地层水中溶解的速率,并试图探讨矿物溶蚀的微观机理。结果表明：①所有矿物颗粒都发生了不同程度的溶解,表现为颗粒失重,溶液中SiO2和金属阳离子含量增加,pH值上升。②优先溶解的是方解石,其次是硅酸盐矿物。③温度增加,硅酸盐矿物在水中的溶解度明显增加,而方解石的溶解度基本不变。④由于不同有机酸与二氧化硅和金属阳离子生成的络合物稳定性不同,因此,在不同有机酸水溶液中,矿物的溶蚀速率有较大差别。多官能团有机酸的水溶液中,不同矿物有更大的溶解;但在含有丰富Ca2＋的草酸水溶液中,由于矿物颗粒表面难溶草酸钙的沉淀,方解石的溶解变得更加困难。⑤多官能团有机酸与SiO2形成的多环螯合物由于完全取代了硅氧四面体的氧原子,在水中具有高度稳定性,可能有助于(铝)硅酸盐的溶蚀和硅元素的迁移  相似文献   

Mg₂B₂O₅晶须增强AZ91D镁基复合材料在Cl_-溶液中腐蚀行为_*          下载免费PDF全文

王晓民  喇培清  程楚  张廷安 《盐湖研究》2017,25(3):61-66

用电化学方法测量了Mg_2B_2O_5晶须增强AZ91D镁基复合材料在3.5%NaCl溶液中的开路电位、动电位极化曲线和交流阻抗,研究了晶须体积分数对镁合金基体耐腐蚀性能的影响,并利用SEM和XRD表征了腐蚀后复合材料表面的微观形貌和相组成。结果表明,随着Mg_2B_2O_5晶须体积分数的增加,AZ91D镁基复合材料的耐腐蚀性逐渐提高。当硼酸镁晶须的体积分数为35%时,材料的自腐蚀电位提高0.2V以上,自腐蚀流密度降低了1个数量级;SEM测试表明,复合材料表面生成了一层晶须增韧的腐蚀钝化膜,对基体起到保护作用。  相似文献   

山西早二叠世微古植物群基本特征   总被引：2，自引：0，他引：2  

高联达 《华北地质矿产杂志》1997,12(2):103-113

山西早二叠世德古植物－孢子花粉非常丰富，共发现６０余属１５０余种。根据孢子花粉在地质演化和分布规律，自下而上可划分三个孢子带，（１）Ｓｉｎｕｔａｔｉｓｐｏｒｉｔｏｅｓ ｓｉｎｅｎｓｉｓ－Ｇｕｌｉｓｐｏｒｉｔｅｓｃｏｃｈｌｅａｒｉｓ（ＳＣ）；（２）Ｒａｄｉｔｚｏｎａｔｅｓ ｓｏｌａｒｉｓ－Ｐｏｔｏｎｉｅｉｓｐｏｒｉｔｅｓ ｂｈａｒａｄｗａｊｉｉ（ＳＢ）；（３）Ｐａｔｅｌｌｉｓｐｏｒｉｔｅｓ ｍｅｉｓ  相似文献   

Experimental study on the effect of the critical temperature of water on the preparing and occurring of large earthquakes     

Dailu Rong  Fahui Jin  Yuting He  Ming Jin  Xuyuan Jiang  Zhongqiang Gao 《地震学报(英文版)》1992,5(4):739-747

The features of fracturing and dissolving of Yunnan marble in distilled water near the critical temperature have been studied experimentally. The results indicate that the mechanical parameters of the samples (fracture strength, Young’s Modulus, shear fracture energy and fracture toughness) drop with the temperature of the environment water, near the critical temperature (380°C), these parameters have sudden changes (drop), then keep stable values roughly. The contents of some chemical materials in the water, PH value and conductivity at every experiment temperature have been analysed and measured. At 380°C, there all exist sudden changes. According to the results, it is pointed out that the sudden changes are related to strong stress corrosion of water near its critical temperature to the rock and the exist and its migration of the water solution near the critical temperature in the crust have important significance to the earthquake source process, the formation cause of the low-focal depth earthquakes in the crust. The Chinese version of this paper appeared in the Chinese edition ofActa Seismologica Sinica,14, 156–163, 1992. This work was sponsored by the Chinese Joint Seismological Science Foundation.  相似文献   

Stress-induced crack path in Aji granite under tensile stress     

Yozo Kudo  Osam Sano  Naokuni Murashige  Yoshiaki Mizuta  Koji Nakagawa 《Pure and Applied Geophysics》1992,138(4):641-656

The double-torsion test using Aji granite was carried out to investigate the interaction between stress-induced crack path and mineral grains. Crack velocities were controlled at range 10^–7 m/s to 10^–1 m/s. After the stressed specimens were dyed, we checked the crack path by thin section analysis, using an optical microscope. The stress-induced crack path was divided into two types, transgranular and intergranular cracks, and each path was subdivided with respect to mineral grains. In spite of the extensive range of crack velocities, the ratios between the transgranular and intergranular crack lengths did not change. The crack paths were all jagged, and often showed detour around the grain boundary when faced with obstacles like hard grains or preexisting cracks. That is to say, quartz grain played an important role as an obstacle. Feldspar grain could change the crack path because of its cleavage plane. Biolite grain had a serious effect on the path even if its constitution ratio is very small. Fractal dimensions of the crack paths were calculated by three methods, as indicators of surface roughness. The fractal dimensions were shown in a slight trend with the change of crack velocity. This trend can be explained from the point of limited cracking rate in stress corrosion.  相似文献   

页岩气钻探冲洗液体系的研究与应用          下载免费PDF全文

单文军  蒋睿  陶士先  岳伟民  李艳宁 《探矿工程》2016,43(10):176-181

中国页岩气资源开发潜力巨大,近年来页岩气勘探开发力度不断加大,对钻探工艺和技术的要求不断提高。页岩气地层岩性主要为泥岩、砂岩、页岩、碳质板岩、灰岩,该类地层胶结性差、破碎、井壁强度低,钻进中易出现孔壁失稳,发生坍塌、卡钻、埋钻等孔内事故,需要研制具有强抑制性、低成本、绿色环保的冲洗液体系来保证施工安全。本文通过对页岩气井壁稳定机理的探究,优选出一种适用于页岩地层双聚防塌和成膜防塌低固相冲洗液体系,该体系由抑制剂、防塌剂、降失水剂、润滑剂、封堵剂、流型调节剂等处理剂组成,具有良好的抑制性和胶结性。现场应用取得了良好的效果,保证了项目的顺利施工。  相似文献   

南极冰钻钻井液应用性试验研究          下载免费PDF全文

刘宁  徐会文  韩丽丽  王莉莉  Pavel Talalay 《探矿工程》2016,43(8):11-14,43

钻井液的性质及性能参数对于南极科学钻探有着重要的影响。钻井液除了必须要具备合适的粘度和密度,以满足冷却钻头、平衡孔壁压力、携带冰屑、清洁孔底的要求外,钻井液的性质如导电性、导热性及其腐蚀性对于保证钻具的正常工作、输送孔内信息也有着重要的影响。根据目前已经在南极使用的钻井液类型,分别对6种介质（国产硅油-3cst、KF96硅油-2cst、丁酸乙酯、丁酸丁酯、丁酸戊酯、丙酸丙酯）在不同温度下的电导率、导热系数和对密封件的腐蚀性进行了试验测试,选出了适合南极应用的钻井液类型及在钻具中使用的密封件材质,可供极地钻探选择钻井液类型及钻具设计提供重要的参考。  相似文献   

贵州猫场超大型铝土矿床成因浅析   总被引：1，自引：1，他引：0       下载免费PDF全文

庄志贤  陶泳昌  周安乐 《贵州地质》2016,33(4):272-277,283

猫场铝土矿床位于大威岭背斜北东端猫场穹窿背斜。由于寒武系碳酸盐岩古喀斯特侵蚀面,经长期风化溶蚀淋滤作用,在古喀斯特正地形上先形成粘土层,粘土层进一步风化溶蚀经脱硅、脱铁形成三水铝石的矿源层,而古喀斯特负地形则为铝土矿的沉积提供了充足的场所。本文通过对含矿岩系的特征分析,结合沉积相与古地理环境等研究,揭示了猫场铝土矿床的形成严格受大地构造和古喀斯特地形的控制。  相似文献   

黄岛原油码头管道腐蚀的原因分析     

邹中坚  张连生  朱相荣  周玲玲 《海洋科学》1990,14(3):44-47

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Seawater Corrosion Fatigue of Welded Joints Under Random Variable Amplitude Loading     

Xue Yinian  Xu Jilin Li Yanping Li He Professor  Solid Mechanics Division 《中国海洋工程》1993,(2)

- Offshore platforms are always subjected to wave action which is random variable amplitude cyclic loading. In order to simulate the stressing condition at the 'hot spot' of the tubular joints and the marine environment, random variable amplitude fatigue tests have been carried out on welded plate joints in sea water. The tests have been conducted under the conditions of loading frequency of 0.2 Hz, stress ratio of -1, seawater temperature of about 20℃ and cathodic protection with the potential about -850 mV, SCE. The test results have been compared with the seawater corrosion fatigue life under constant amplitude loading. Miner's linear cumulative damage summation rule has been used to predict the corrosion fatigue life under variable amplitude loading. The predicted life is in good agreement with the test data.  相似文献