Effect of Temperature on the Fatty Acid Composition of Four Species of Marine Microalgae     

李文权  李芊  廖启斌  陈清花 《海洋通报(英文版)》2003,5(1)

For most aquacultured animals, the unsaturated fatty acids of marine microalgae have the effects of raising their rates of hatchability, survival and growth and the essential nutrients for the cultured animals such as fish and shrimp. Japanese and ROK scholars have reported that the algal powder added into the fish and shrimp bait may act as coagulating and anti-collapsing agents, and is especially effective if it is used in the water lacking minerals and vitamins[1]. Japanese scholars have p…  相似文献   

细基江蓠脂肪酸组成研究     

徐世平  盛国英  傅家谟  王永川  潘国瑛 《热带海洋学报》1993,(3)

研究表明,南海细基江蓠Gracilaria tenuistipitata中主要含有C_9—C_(30)一元饱和脂肪酸,其中n-十六酸含量占脂肪酸组分的40％以上。单烯和二烯酸的含量较低,缺乏多烯酸及前列腺素类化合物。此外,还含有少量二元酸类、4-及5-羰基羧酸,其中后两者是首次在红藻中发现。南海细基江蓠的脂肪酸组成特征与南海海域水质较清、光照充足及水温较高等环境因素有关。  相似文献   

氮浓度对四株海洋绿藻总脂含量和脂肪酸组成的影响   总被引：6，自引：0，他引：6  

曹春晖  孙世春  麦康森  梁英 《海洋湖沼通报》2006,(3):79-84

本文用NaNO3作为氮源,分别作了氮浓度的五个水平对2属(小球藻属、裂丝藻属)的四株绿藻的生长率、总脂含量及主要脂肪酸组成的影响。C19、C97和C102的脂肪含量随N浓度的改变而有较大变化,其中C102在1.6m mol/L时脂肪含量达到最大值(24.8%)。C95的脂肪含量随氮浓度变化不大。同时,由氮浓度引起的平均生长率μ与总脂含量之间无明显相关关系。四株绿藻的EPA(20∶5n-3)和PUFAs(polyunsaturated fatty acids)含量随培养基中氮浓度的改变有较大变化但因种而异。C95和C97均在中等氮浓度时EPA含量达到最大值,分别为23.8%和27.4%。C19和C102在高氮浓度(40mmol/L)获得EPA的最大值,分别为25.7%和26.6%。  相似文献   

Impact of Montmorillonite and Calcite on Release and Adsorption of Cyanobacterial Fatty Acids at Ambient Temperature   总被引：1，自引：0，他引：1  

刘邓  杨小芬  王红梅  李继红  苏念 《中国地质大学学报(英文版)》2008,19(5):526-533

Minerals might act as important sorbents of sedimentary organic matter and reduce biodegradation, which favors the formation of hydrocarbon source rocks in the earth's history. Since most organic matter is degraded during the sinking process, at ambient temperature, it is important to investigate the adsorption capacity of different minerals during this process, to assess the organic loss from primary productivity to sedimentary organic matter. In this study, montmorillonite and calcite have been selected to study the impact of different minerals on the release, adsorption, and deposition of cyanobacterial (Synechococcus elonpata) fatty acids (FAs) at ambient temperature. Gas chromatography (GC), gas chromatography-mass spectrometry (GC-MS) have been utilized to detect the variation in fatty acids. Primary results suggest that minerals have a different impact on dissolved organic matter. Montmorillonite can specifically enhance the release of fatty acids from cyanobacterial cells by lowering the pH values of the solution. The adsorption of the dissolved organic matter by montmorillonite will also be enhanced under a lower pH value. Conjunction of fatty acids with montmorillonite to form a complex will favor the sinking and preservation of these organics. Selective adsorption is observed among fatty acids with different carbon numbers. In contrast, calcite does not show any impact on the release and adsorption of organic matter even though it is reportedly capable of acting as a catalyst during the transformation of organic matter at high temperature. The primary data bridge a link between primary productivity and sedimentary organic matter, suggesting the relative importance of claystones in the formation of hydrocarbon source rocks in the earth's history.  相似文献   

酸溶——催化极谱法测定地质样品中的钨、钼   总被引：3，自引：0，他引：3  

陶秋丽 《陕西地质》2008,26(1):82-86

本文采用混合酸溶解样品,对影响催化体系稳定的酸度、温度和不同反应时间的因素分别进行了对比试验,确定催化体系相对稳定的最佳条件,经过大量样品的分析验证,分析方法可靠。  相似文献   

模拟酸雨及施磷对水稻土中铅的淋溶特性影响   总被引：1，自引：1，他引：0  

陶春军  周涛发  李湘凌  陈永宁  陈兴仁  贾十军  陈富荣  袁峰 《现代地质》2008,22(6)

采用pH=3.0、pH=4.5与对照pH=5.6的3种模拟酸雨淋溶土柱的方法,研究酸雨及含磷酸雨淋溶下合肥市郊水稻土中铅的释放特征与规律。结果表明:经过相当于1 980 mm降水量的淋溶后,铅释放量总体上表现为随着酸雨强度增加累积淋溶量也增加的现象。酸雨作用下,施磷量越多土壤中铅的淋失总量越大。在酸雨及施磷条件下,大兴地区黄褐土中Pb较义城地区水稻土中易于淋失。  相似文献   

火山沉积岩及其矿床研究中伽马测井曲线解释的误区     

冯宝华 《物探与化探》2008,32(2):171-174

根据酸性凝灰岩和酸性火山事件粘土岩的自然伽马测井曲线,对当前流传的"沉积岩层的放射性强度(或放射性核素的含量)随泥质含量的增加而增高"的概念和用自然伽马值及经验公式求泥质含量提出质凝。酸性凝灰岩的自然伽马曲线有高异常响应,若解释为泥岩显然是误解,故将沉积岩伽马曲线高异常一律解释为泥岩是片面的。各类火山事件粘土岩的伽马值相差悬殊,但其泥质含量几乎相等,用它们的伽马值计算泥质含量误差甚大。最后对铝土矿层的伽马曲线稍加解释,指出核测井应用的远景。  相似文献   

Interaction of copper with fatty acids in Soxhlet extraction and its influence     

Ming Jin  Yanqing Xia  Tianzhu Lei  Junli Qiu  Rui Zhang 《中国地球化学学报》2008,27(2):157-160

Treatment with metallic copper for the removal of elemental sulfur from bitumen extracted from sedimentary rocks or petroleum is the most widely used method. Little attention has been paid, however, to its disadvantages. It was observed that copper can interact with some polar organic substances during conventional sulfur removal, which can strongly influence the quantitative and qualitative determination of bitumen, as has been confirmed by interaction of long-chain fatty acids with copper. The copper soap generated was analyzed by element analysis, inductively coupled plasma optical emission spectrometry （ICP-OES）, thermal analysis （TG-DSC） and Fourier Transform Infrared spectroscopy （FFIR）. Mechanism of the interaction was investigated and elucidated. Our experimental results would necessitate improvement of the present method for sulfur removal and/or a search for a new one.  相似文献   

酸性矿山废水中生物成因次生高铁矿物的形成及环境工程意义   总被引：10，自引：1，他引：9  

周立祥 《地学前缘》2008,15(6)

酸性矿山废水(acid mine drainage,AMD)是一类pH低并含有大量有毒金属元素的废水。AMD及受其影响的环境中次生高铁矿物类型主要包括羟基硫酸高铁矿物(如黄铁矾和施威特曼石等)和一些含水氧化铁矿物(如针铁矿和水铁矿等),而且这些矿物在不同条件下会发生相转变,如施氏矿物向针铁矿或黄铁矾矿物相转化。基于酸性环境中生物成因次生矿物的形成会"自然钝化"或"清除"废水中铁和有毒金属这一现象所获得的启示,提出利用这些矿物作为环境吸附材料去除地下水中砷,不但吸附量大(如施氏矿物对As的吸附可高达120mg/g),而且可直接吸附As(III),还几乎不受地下水中其他元素影响。利用AMD环境中羟基硫酸高铁矿物形成的原理,可将其应用于AMD石灰中和主动处理系统中,构成"强化微生物氧化诱导成矿-石灰中和"的联合主动处理系统,以提高AMD处理效果和降低石灰用量。利用微生物强化氧化与次生矿物晶体不断生长的原理构筑生物渗透性反应墙(PRB)并和石灰石渗透沟渠耦联,形成新型的AMD联合被动处理系统,这将有助于大幅度增加处理系统的寿命和处理效率。此外,文中还探讨了上述生物成因矿物形成在AMD和地下水处理方面应用的优点以及今后需要继续研究的问题。  相似文献   

Rate constants for the reactions of the NO3 radical with HCOOH/HCOO− and CH3COOH/CH3COO− in aqueous solution between 278 and 328 K     

M. Exner  H. Herrmann  R. Zellner 《Journal of Atmospheric Chemistry》1994,18(4):359-378

The kinetics of the aqueous phase reactions of NO₃ radicals with HCOOH/HCOO^– and CH₃COOH/CH₃COO^– have been investigated using a laser photolysis/long-path laser absorption technique. NO₃ was produced via excimer laser photolysis of peroxodisulfate anions (S₂O ₈ ^2– ) at 351 nm followed by the reactions of sulfate radicals (SO ₄ ^– ) with excess nitrate. The time-resolved detection of NO₃ was achieved by long-path laser absorption at 632.8 nm. For the reactions of NO₃ with formic acid (1) and formate (2) rate coefficients ofk ₁=(3.3±1.0)×10⁵ l mol^–1 s^–1 andk ₂=(5.0±0.4)×10⁷ l mol^–1 s^–1 were found atT=298 K andI=0.19 mol/l. The following Arrhenius expressions were derived:k ₁(T)=(3.4±0.3)×10¹⁰ exp[–(3400±600)/T] l mol^–1 s^–1 andk ₂(T)=(8.2±0.8)×10¹⁰ exp[–(2200±700)/T] l mol^–1 s^–1. The rate coefficients for the reactions of NO₃ with acetic acid (3) and acetate (4) atT=298 K andI=0.19 mol/l were determined as:k ₃=(1.3±0.3)×10⁴ l mol^–1 s^–1 andk ₄=(2.3±0.4)×10⁶ l mol^–1 s^–1. The temperature dependences for these reactions are described by:k ₃(T)=(4.9±0.5)×10⁹ exp[–(3800±700)/T] l mol^–1 s^–1 andk ₄(T)=(1.0±0.2)×10¹² exp[–(3800±1200)/T] l mol^–1 s^–1. The differences in reactivity of the anions HCOO^– and CH₃COO^– compared to their corresponding acids HCOOH and CH₃COOH are explained by the higher reactivity of NO₃ in charge transfer processes compared to H atom abstraction. From a comparison of NO₃ reactions with various droplets constituents it is concluded that the reaction of NO₃ with HCOO^– may present a dominant loss reaction of NO₃ in atmospheric droplets.  相似文献