块金成因新见及其分级   总被引：6，自引：0，他引：6  

郑大中  郑若锋 《江西地质》2000,14(4):300-305

本文描述了块金的形成新机制。在热液中呈金氢化物、金羰基化合物及纳料金粒子、纳米金合金粒子活化迁移。在表生条件下,金硫代硫酸盐配合物、金粒子、金合金粒子是金迁移的主要形式。块金是地质的、化学的、物理的、生物化学的综合作用的结果。按块金成因分为内生块金和次生块金。按单块块金质量分为４级。  相似文献   

典型海洋大气环境中AZ80镁合金电偶腐蚀行为研究     

蒋全通  杨黎晖  路东柱  张杰  段继周  侯保荣 《海洋与湖沼》2020,51(4):899-908

镁合金作为最轻的金属结构材料,具有比强度高、比刚度高、减震性能好、电磁屏蔽等优点。随着海洋强国战略的实施,先进镁合金结构材料逐步在海洋装备上开始应用。已列装的新型高强AZ80镁合金,通过与QBe1.7铍青铜紧固件连接,共同构成整体在典型海洋大气环境中服役。在高盐、高湿的海洋环境环境中,镁合金与电位更正的QBe1.7铍青铜偶接后,极易发生电偶腐蚀。电位相对更负的高强AZ80镁合金,作为电偶腐蚀的阳极被加速溶解。本研究对高强AZ80镁合金电偶腐蚀样品经过12个月青岛海洋大气暴露试验,发现空白对照组、电偶1组(紧固件铍青铜直径Ψ=10mm)和电偶2组(紧固件铍青铜直径Ψ=20mm)的平均腐蚀速率分别为108.1071、133.8929、173.6250g/(m~2·a)。电偶对表面的主要腐蚀产物为:Mg(OH)_2、MgSO_4和MgCl_2。空白样品、电偶1组和电偶2组平均腐蚀深度分别为:0.175、0.330、0.315mm/a。样品中部腐蚀深度最大,边部腐蚀深度则相对较小。不同样品在青岛试验站的腐蚀产物对基体保护能力的量度(n值)分别为1.1337、1.1378、1.0895,表明随着暴露时间的延长,试样在海洋大气环境中的腐蚀速率会加快,试样表面的腐蚀产物对基体根本起不到保护作用。通过灰色关联分析法,计算了青岛海洋大气腐蚀站点的环境因素与AZ80镁合金腐蚀深度和腐蚀失重之间的关联度,结果表明:青岛海洋大气环境因素对高强AZ80镁合金空白样品腐蚀失重影响前三位分别为:SO_4~(2-)非水溶性硫酸盐转化率;对电偶1组样品影响前三位的环境因素分别为:SO_2硫酸盐转化率NO_2;对电偶2组样品影响前三位的环境因素分别为:水溶性降尘SO_2NH_3。对比电偶对2组和1组,唯一的差别是电偶对的面积比,但决定镁合金腐蚀速度的大气成分完全不同,相关机制会在未来工作中详细研究。  相似文献   

数字化技术在铁基合金铬元素可见光谱分析中的应用     

刘平  杨军红 《岩矿测试》2008,27(1):33-36

使用可见光谱数字化自动分析系统对铁基合金中铬元素可见光谱进行了分析测定。研究了铁基合金中铬元素的Cr 520.60 nm和Cr 534.58 nm分析谱线组的特征,并制作了数字化彩色图谱。探索了铁基合金中铬元素的数字化分析技术,结果可用于铁基合金中铬元素的定性、定量分析和牌号鉴别。  相似文献   

X射线荧光光谱法测定锌铝硅合金中硅和铁     

王军学 《岩矿测试》2008,27(1):77-78

采用岛津MXF-2400型多道X荧光光谱仪测定锌铝硅合金中硅及铁的含量,对样品分析面进行了选择,考察了分析面光洁度、样品放置时间对测定的影响条件。方法样品前期处理简便,分析速度快,灵敏度高,硅和铁的相对标准偏差(RSD,n=11)分别为1.15%和0.44%。与其他方法对照,结果相符。  相似文献   

一种用于铀同位素比值α能谱分析的磷化膜制源新技术     

王哲  王玉学  郭冬发  付琳  黄秋红  孙伟  陈春军 《铀矿地质》2016,(2):117-122

研发了一种用于铀同位素比值α能谱分析的磷化膜制源新技术。试验发现,当镍镀片面积为3.14cm2,盐酸浓度为0.5mol/L,氯化钠浓度为2.5mol/L,磷酸二氢钾浓度为0.08mol/L,抗坏血酸浓度为20g/L,溶液体积为25 mL,恒温90℃,振荡速率为160次/min,振程20 mm时,磷化膜制源70min,200μg以下的铀可在镍箔上定量转化为磷化膜。与传统的电沉积制源技术相比较,应用磷化膜制源技术进行测量源制备时无需电沉积装置,制源过程简单快速,工效高,大量共存的232 Th、230 Th、226 Ra、231Pa等核素均不产生干扰,铀的全程回收率接近100%,α能谱峰分辨率较好。  相似文献   

Deep CTD Casts in the Challenger Deep,Mariana Trench   总被引：1，自引：0，他引：1  

Keisuke?TairaEmail author  Daigo?Yanagimoto  Shoji?Kitagawa 《Journal of Oceanography》2005,61(3):447-454

On 1 December 1992, CTD (conductivity-temperature-depth profiler) casts were made at three stations in a north-south section of the Challenger Deep to examine temperature and salinity profiles. The station in the Challenger Deep was located at 11°22.78′ N and 142°34.95′ E, and the CTD cast was made down to 11197 db or 10877 m, 7 m above the bottom by reeling out titanium cable of 10980 m length. The southern station was located at 11° 14.19′ N and 142°34.79′ E, 16.1 km from the central station, where water depth is 9012 m. CTD was lowered to 7014 db or 6872 m. The northern station was located at 11°31.47′ N and 142° 35.30′ E, 15.9 km from the central station, and CTD was lowered to 8536 db or 8336 m, 10 m above the bottom. Below the thermocline, potential temperature decreased monotonously down to 7300–7500 db beyond a sill depth between 5500 m and 6000 m, or between 5597 db and 6112 db, of the trench. Potential temperature increased from 7500 db to the bottom at a constant rate of 0.9 m°C/1000 db. Salinity increased down to 6020–6320 db, and then stayed almost constant down to around 9000 db. From 9500 db to the bottom, salinity increased up to 34.703 psu at 11197 db. Potential density referred to 8000 db increased monotonously down to about 6200 db, and it was almost constant from 6500 db to 9500 db. Potential density increased from 9500 db in accordance with the salinity increase. Geostrophic flows were calculated from the CTD data at three stations. Below an adopted reference level of 3000 db, the flow was westward in the north of Challenger Deep and eastward in the south, which suggests a cyclonic circulation over the Challenger Deep. Sound speed in Challenger Deep was estimated from the CTD data, and a relation among readout depth of the sonic depth recorder, true depth, and pressure was examined.  相似文献   

LF4铝合金在海水中的腐蚀性能研究   总被引：1，自引：0，他引：1  

张波  韩冰 《海洋科学》2005,29(7):4-7

对艇用铝材LF4及其它多种管系金属材料进行静态和动态条件下的自然电位、自然腐蚀率、电化学性能、电偶腐蚀行为等进行多方面的腐蚀试验，得出这些材料在静态和动态海水中的腐蚀性能指标以及变化规律。随着海水流速的增加，LF4铝合金耐蚀性迅速降低。LF4在天然海水中有钝化的趋势，但是钝化膜不完整易破坏。在与其它常用管系金属材料组成的电偶对中，LF4均作为阳极受到加速腐蚀。  相似文献   

非晶态Ni-S合金在碱液中析氢反应(HER)机理的研究   总被引：1，自引：0，他引：1  

杜敏  高荣杰 《中国海洋大学学报(自然科学版)》2003,33(6):961-968

本文研究了非晶态 Ni- S合金的析氢反应机理。用稳态极化曲线研究非晶态 Ni- S合金的极化行为 ,得到其反应的动力学参数塔菲尔斜率和表观反应活化能。用断电流法和循环伏安法研究氢原子的吸附和中间态粒子。考察电极表面粗糙度、活性粒子表面吸附浓度等因素 ,综合分析得出 Ni- S合金电极具有高催化活性的原因及其 HER电催化机理  相似文献   

Effect of local atomic disorder on the half-metallicity of full-Heusler Co₂FeSi alloy: a first-principles study     

李冠男  金迎九  李在一 《海洋学报(英文版)》2010,29(9)

This paper investigates the effect of atomic disorder on the electronic structure, magnetism, and half-metallicity of full-Heusler Co₂FeSi alloy by using the full-potential linearized augmented plane wave method within the generalized gradient approximation (GGA) and GGA+U schemes. It considers three types of atomic disorders in Co₂FeSi alloy: the Co--Fe, Co--Si, and Fe--Si disorders. Total energy calculations show that of the three types of disorders, the Fe--Si disorder is more likely to occur. It finds that for the Co--Si disorder, additional states appear in the minority band-gap at the E_F and the half-metallcity is substantially destroyed, regardless of the disorder level. On the other hand, the Co--Fe and Fe--Si disorders have little effect on the half-metallicity at a low disorder level. When increasing the disorder levels, the half-metallcity is destroyed at about 9 % of the Co--Fe disorder level, while that stays at 25 % of the Fe--Si disorder level.  相似文献   

Effects of high-pressure heat treatment on the solid-state phase transformation and microstructures of Cu_61.13Zn_33.94Al_4.93 alloys     

王海燕  刘建华  彭桂荣  王文魁 《海洋学报(英文版)》2010,29(9)

The phase transformation activation energy of the Cu_61.13Zn_33.94Al_4.93 alloys, which were treated at 4 GPa and 700 °C for 15 minutes, was calculated by means of differential scanning calorimetry curves obtained at various heating and cooling rates. Then, the effects of high-pressure heat treatments on the solid-state phase transformation and the microstructures of Cu_61.13Zn_33.94Al_4.93 alloys were investigated. The results show that high-pressure heat treatments can refine the grains and can change the preferred orientation from (111) to (200) of α phase. Compared with the as-cast alloy, the sample with high-pressure heat treatment has finer grains, lower β' → β and β → β ' transformation temperature and activation energy. Furthermore, we found that high cooling rate favours the formation of fine needle-like α phase in the range of 5--20 °C/min.  相似文献