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The role of clinopyroxene in producing grandite garnet is evaluatedusing data from an ultrahigh-temperature metamorphosed calc-silicategranulite occurrence in the Eastern Ghats Belt, India. ‘Peak’pressure–temperature conditions of metamorphism were previouslyconstrained from associated high Mg–Al granulites as c.0·9 GPa, >950°C, and the rocks were near-isobaricallycooled to c. 750°C. Grandite garnet of variable compositionwas produced by a number of reactions involving phases suchas clinopyroxene, scapolite, plagioclase, wollastonite and calcite,in closely spaced domains. Compositional heterogeneity is preservedeven on a microscale. This precludes pervasive fluid fluxingduring either the peak or the retrograde stage of metamorphism,and is further corroborated by computation of fluid–rockratios. With the help of detailed textural and mineral compositionalstudies leading to formulation of balanced reactions, and usingan internally consistent thermodynamic dataset and relevantactivity–composition relationships, new petrogenetic gridsare developed involving clinopyroxene in the system CaO–Al2O3–FeO–SiO2–CO2–O2in TaCO2fO2 space to demonstrate the importanceof these factors in the formation of grandite garnet. Two singularcompositions in garnet-producing reactions in this system arededuced, which explain apparently anomalous textural relations.The possible role of an esseneite component in clinopyroxenein the production of grandite garnet is evaluated. It is concludedthat temperature and fO2 are the most crucial variables controllinggarnet composition in calc-silicate granulites. fO2, however,behaves as a dependent variable of CO2 in the fluid phase. Externalfluid fluxing of any composition is not necessary to producechemical heterogeneity of garnet solid solution. KEY WORDS: grandite garnet; role of clinopyroxene; internal buffering; oxidation–decarbonation equilibria  相似文献   
43.
Lacustrine groundwater discharge (LGD) transports nutrients from a catchment to a lake, which may fuel eutrophication, one of the major threats to our fresh waters. Unfortunately, LGD has often been disregarded in lake nutrient studies. Most measurement techniques are based on separate determinations of volume and nutrient concentration of LGD: Loads are calculated by multiplying seepage volumes by concentrations of exfiltrating water. Typically low phosphorus (P) concentrations of pristine groundwater often are increased due to anthropogenic sources such as fertilizer, manure or sewage. Mineralization of naturally present organic matter might also increase groundwater P. Reducing redox conditions favour P transport through the aquifer to the reactive aquifer‐lake interface. In some cases, large decreases of P concentrations may occur at the interface, for example, due to increased oxygen availability, while in other cases, there is nearly no decrease in P. The high reactivity of the interface complicates quantification of groundwater‐borne P loads to the lake, making difficult clear differentiation of internal and external P loads to surface water. Anthropogenic sources of nitrogen (N) in groundwater are similar to those of phosphate. However, the environmental fate of N differs fundamentally from P because N occurs in several different redox states, each with different mobility. While nitrate behaves essentially conservatively in most oxic aquifers, ammonium's mobility is similar to that of phosphate. Nitrate may be transformed to gaseous N2 in reducing conditions and permanently removed from the system. Biogeochemical turnover of N is common at the reactive aquifer‐lake interface. Nutrient loads from LGD were compiled from the literature. Groundwater‐borne P loads vary from 0.74 to 2900 mg PO4‐P m?2 year?1; for N, these loads vary from 0.001 to 640 g m?2 year?1. Even small amounts of seepage can carry large nutrient loads due to often high nutrient concentrations in groundwater. Large spatial heterogeneity, uncertain areal extent of the interface and difficult accessibility make every determination of LGD a challenge. However, determinations of LGD are essential to effective lake management. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   
44.
Previous work on three‐dimensional shakedown analysis of cohesive‐frictional materials under moving surface loads has been entirely for isotropic materials. As a result, the effects of anisotropy, both elastic and plastic, of soil and pavement materials are ignored. This paper will, for the first time, develop three‐dimensional shakedown solutions to allow for the variation of elastic and plastic material properties with direction. Melan's lower‐bound shakedown theorem is used to derive shakedown solutions. In particular, a generalised, anisotropic Mohr–Coulomb yield criterion and cross‐anisotropic elastic stress fields are utilised to develop anisotropic shakedown solutions. It is found that shakedown solutions for anisotropic materials are dominated by Young's modulus ratio for the cases of subsurface failure and by shear modulus ratio for the cases of surface failure. Plastic anisotropy is mainly controlled by material cohesion ratio, the rise of which increases the shakedown limit until a maximum value is reached. The anisotropic shakedown limit varies with frictional coefficient, and the peak value may not occur for the case of normal loading only. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   
45.
Reflecting internal catchment hydrological processes in hydrological models is important for accurate predictions of the impact of climate and land-use change on water resources. Characterizing these processes is however difficult and expensive due to their dynamic nature and spatio-temporal variability. Hydropedology is a relatively new discipline focusing on the synergistic integration of hydrology, soil physics and pedology. Hydropedological interpretations of soils and soil distribution can be used to characterize key hydrological processes, especially in areas with no or limited hydrometric measurements. Here we applied a hydropedological approach to reflect flowpaths through detailed routing in SWAT+ for a 157 ha catchment (Weatherley) in South Africa. We compared the hydropedological approach and a standard (no routing) approach against measured streamflow (two weirs) and soil water contents (13 locations). The catchment was treated as ‘ungauged’ and the model was not calibrated against hydrometric measurements in order to determine the direct contribution of hydropedology on modelling efficiency. Streamflow was predicted well without calibration (NSE > 0.8; R2 > 0.82) for both approaches at both weirs. The standard approach yielded slightly better streamflow predictions. The hydropedological approach resulted in considerable improvements in the simulation of soil water contents (R2 increased from 0.40 to 0.49 and PBIAS decreased from 40% to 20%). The routing capacity of SWAT+ as employed in the hydropedological approach reduced the underestimation of wetland water regimes drastically and resulted in a more accurate representation of the dominant hydrological processes in this catchment. We concluded that hydropedology can be a valuable source of ‘soft data’ to reflect internal catchment structure and processes and, potentially, for realistic calibrations in other studies, especially those conducted in areas with limited hydrometric measurements.  相似文献   
46.
An analytical approach using a Winkler model based on two lateral soil displacement components in a three‐dimensional soil is investigated to provide analytical solutions of horizontal response of a rectangular pile subjected to lateral loads in nonhomogeneous soil. The two lateral displacement components of a soil surrounding the rectangular pile are represented by the Fourier series of displacement potential functions in the elastic three‐dimensional analysis. The lateral stiffness coefficient of the rectangular pile shaft in nonhomogeneous soil is derived from the rocking stiffness coefficient taking into account rocking rotation of a rigid pile shaft. The relationship between horizontal displacement, rotation, moment, and shear force for the rectangular pile subjected to horizontal loads in nonhomogeneous soil is obtainable in the form of the recurrence equation. The formulation of lateral displacement and rotation for a rectangular pile subjected to lateral loads on the pile base in nonhomogeneous soil is proposed by taking into account Mindlin's equation and the equivalent thickness for soil layers in the equivalent elastic method. The difference of lateral behavior between square and circular piles subjected to lateral loads is insignificant. The effect of aspect ratio of the rectangular pile on the lateral behavior is great for the lower stiffness ratio between pile and soil and the larger length–equivalent diameter ratio. The effect of the value of Poisson's ratio of soil on lateral stiffness coefficient is relatively small except Poisson's ratio close to 0.5. The comparison of the results calculated by the current method for a rectangular pile subjected to lateral loads in nonhomogeneous soil has shown good agreement with those obtained from the analytical methods and the finite element method. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   
47.
Metal loads were determined from water samples collected under different streamflow conditions (baseflow and storm events) in a rural catchment (NW Spain) during 4 years. A study at annual, seasonal and storm‐event scales was carried out. In all analysed scales, the export order was Fe > Al > Mn > Zn > Cu. A high inter‐annual, seasonal and storm‐event scale variability of metal load was observed. The total metal loads in stream were higher during baseflow conditions than during storm events, which only represented 4% of the duration of the study period and 25% of streamflow. During storm events, both Al and Fe loads accounted 45% of the total load of the study period, whereas Mn, Cu and Zn loads represented 42%, 33% and 24%, respectively. This highlights the role of high flows on metal export. Only four big events exported around 30% of load of each metal transported in events. At all time scales, a prevalence of export of particulate metals over dissolved metals was observed, more pronounced for Al, Fe and Mn than for Cu and Zn. The export of metals in the Corbeira catchment is influenced by runoff and, to a lesser extent, by the rainfall amount. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   
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49.
姜海  郭海燕  张林  王伟 《海洋与湖沼》2016,47(6):1101-1106
为研究内孤立波质量源数值造波方法,本文采用两个点源形式的质量源,分别放置于两层流体的上下层中作为内孤立波激发源。推导源项表达式,从不可压缩流体的Navier-Stokes方程出发,结合内孤立波Kd V、e Kd V理论,基于商业软件FLUENT发展了一种内孤立波质量源数值造波方法。通过数值模拟,分析了质量源造波过程中内孤立波的生成过程,并将数值模拟结果同理论及实验作对比。结果表明:基于此方法生成的内孤立波波形、波高及波致水平速度与理论及实验吻合度较好,该方法是可行的,并且耗时短、效率高。  相似文献   
50.
This paper presents an incremental elastoplastic finite element method (FEM) to simulate the undrained deformation process of suction caisson foundations subjected to cyclic loads in soft clays. The method is developed by encoding the total-stress-based bounding surface model proposed by the authors in the ABAQUS software package. According to the model characteristics, elastoplastic stress states associated with the incremental strains of each iteration are determined using the sub-incremental explicit Euler algorithm, and the state parameters describing the cyclic accumulative rates of strains are updated by setting state variables during the calculations. The radial fallback method is also proposed to modify the stress states outside the bounding surface to the surface during determination of the elastoplastic stress states. The stress reversals of soil elements are judged by the angle between the incremental deviatoric stress and the exterior normal vector at the image stress point on the bounding surface to update the mapping centre and state variables during cyclic loading. To assess the general validity of the method, the reduced scale model tests and centrifuge tests of suction caissons subjected to cyclic loads are simulated using the method. Predictions are in relative good agreement with test results. Compared with the limit equilibrium and quasi-static methods, the method can not only determine the cyclic bearing capacity, but can also analyse the deformation process and the failure mechanisms of suction caisson under cyclic loads in soft clays.  相似文献   
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