滨海含水层胶体絮凝导致地层损害的实验研究          下载免费PDF全文

唐晓梦  林奇云  林国庆  孙静  初慧  苏胜  张丽春 《山东国土资源》2020,36(8):48-53

滨海含水层地层损害是指淡水驱替咸水过程中,释放后的黏土胶体发生絮凝沉降,导致地层孔隙被堵塞,引起含水介质的渗透性降低的现象。该文通过絮凝沉降实验和定流速砂柱实验,分析不同离子强度和阳离子价态(一价、二价)对胶体絮凝沉降的影响,结果表明:NaCl作为电解质时,絮凝发生的离子强度范围在0.032~0.034 mol/L之间,絮凝时间从82 min减少至39 min;而电解质为CaCl 2,离子强度为0.006 mol/L时,胶体的絮凝时间仅需6 min;钙钠比越高,黏粒絮凝发生的越快。砂柱实验结果显示,含水介质渗透性会随着电解质溶液的离子强度增加和阳离子价态的升高快速降低。当电解质为NaCl,离子强度分别为0.054 mol/L和0.017 mol/L时,含水介质渗透性降低20%所需时间分别为15 min和50 min;当电解质为CaCl2,离子强度为0.011 mol/L时,含水介质渗透性降低20%仅需5 min。因为高离子强度和高价阳离子可以加速胶体絮凝,多孔介质的孔吼更容易发生堵塞,研究成果对降低滨海含水层的地层损害有一定的实际应用价值。  相似文献   

天山乌鲁木齐河融雪和河川径流的水文化学过程   总被引：12，自引：3，他引：9  

刘凤景 Willi.  M 《冰川冻土》1999,21(3):213-219

研究结果表明, 含 Ｃａ Ｃ Ｏ３矿物的溶解作用在乌鲁木齐河源区居主导地位 尽管融雪径流的 “离子脉冲”作用可以释放峰值强度达 ３～４ 倍的 Ｓ Ｏ２４ 和 Ｎ Ｏ－３ 流, 并且引起了总控断面河川径流与之相像的“离子脉冲”现象,但河川径流仍然呈现弱碱性;河源区强烈的含 Ｓ矿物的氧化溶解作用,产生大量的 Ｈ＋ ,被含 Ｃａ Ｃ Ｏ３矿物的溶解作用所缓冲, 未引起河川径流的酸化乌鲁木齐河以冰川站为界, 以上地区的水文化学过程为矿物的侵蚀－ 溶解过程,以下则发生部分矿物的沉淀,如 Ｃａ Ｃ Ｏ３的沉淀 Ｃａ Ｃ Ｏ３ 的沉淀作用一定程度上又增强了河流的酸缓冲力   相似文献   

黄壁庄水库降水效应的分析     

张学勇  谢会兰 《湖泊科学》1992,4(1):85-90

南极洲万达盐湖为饱和方解石湖水。计算出的方解石饱和指数随水深增加而变化。在Ca~(2+)及HCO_3~-活度值均一的上部氧化环境湖水中,pH及溶解氧(DO)是控制该变化的主要因素,在下部还原环境湖水中,Ca~(2+)及HCO_3~-的活度对方解石的饱和指数SI的变化起主要作用。这充分揭示了湖底部近代沉积物中分布较多方解石矿物的原因。  相似文献   

主成分分析法在判定新立矿井海水渗入中的应用     

李国庆  ;汪新庆  ;尹改梅 《中国地质灾害与防治学报》2014,25(3):83-88

为了判定新立矿井海水渗入情况,在详细的水文地质调查、取样测试的基础上,应用主成分分析法将7个水质测试指标进行了降维处理,分析了主成分的实际意义,并根据综合主成分指标进行了水样的分类。结果表明,7个指标可以综合为两个主成分,Cl^-,Mg^2＋,Na^＋和SO4^2-四个变量在第一主成分上具有类似的、较高的载荷值,反映海水的浓缩效应,K^＋在第二主成分上显示较高的载荷值,反映离子交换吸附效应;矿坑涌水中K^＋、Na^＋等指标即可反映海水渗入的物理、化学特征,通过涌水水质的监测可以判定海水渗入情况。  相似文献   

Atypical size selection of captive school prawns,Metapenaeus macleayi,by three recreational fishing gears in south‐eastern Australia     

Matt K. Broadhurst  Russell B. Millar  Damian J. Young  Michael E. L. Wooden  Stuart Rowland 《新西兰海洋与淡水研究杂志》2013,47(5):755-766

Three manipulative experiments were done to estimate the selectivity of conventional and new sizes and configurations of mesh for school prawns, Metapenaeus macleayi, in three south‐eastern Australian recreational fishing gears (haul, push, and scoop nets). The treatment meshes examined were: (1) conventional‐sized, diamond‐shaped mesh used in all gears (20 mm in scoop nets and 30 mm in push and haul nets); (2) 30 mm in scoop nets; and (3) 40‐mm diamond‐ and (4) 23‐mm square‐shaped mesh in all gears. In all experiments, known quantities of school prawns (6–24 mm carapace length (CL)) were placed in purpose‐built enclosures, monitored to ensure no experimental‐induced stress (as measured by changes in L‐lactate in their haemolymph) and the replicate treatments of the various gear configurations deployed. Escapees from the various treatment nets were collected from the enclosures using fine‐meshed nets. Logistic selection curves were derived for all treatment nets and specific comparisons made within and among gears. All nets had 50% retention lengths (L₅₀) comparable to other penaeid‐catching gears with similar mesh sizes, but most had selection ranges (SRs) that were atypically inflated. The large SRs were attributed to a combination of factors that included the mesh geometry and towing speed of the gears and the behaviour of school prawns. The 20‐mm scoop net had the smallest selection parameters, retaining >99% of individuals larger than 13 mm CL. Mesh size in this gear would need to be increased to at least 30 mm to allow some maturing prawns (>18 mm CL) to escape.  相似文献   

Mechanisms and factors affecting the adsorption of sodium alginate onto modified clays     

林勇新  曹西华  宋秀贤  王楠  俞志明 《中国海洋湖沼学报》2013,31(4):867-875

Algal organic materials (AOMs) are one critical factor affecting the efficiency of modified clays used for the mitigation of harmful algal blooms (HABs). This study was conducted to develop a deeper understanding of the mechanisms and factors affecting the adsorption of AOMs onto modified clays. Sodium alginate (polysaccharide) and kaolinite modified with polyaluminium chloride (PACl) were used as AOMs and modified clay model substances, respectively, and the effects of modifier dosage, contact time, solution pH and ionic strength were investigated through batch adsorption experiments. Kinetics revealed that the alginate adsorption rate was described well by a pseudo-second order model. PACl effectively enhanced the adsorption capacity of kaolinite and increased the adsorption rate, and the optimum additive amount of PACl was 5%. The experimental data fitted both the Freundlich and Langmuir adsorption equations well. The adsorption thermodynamics for alginate onto modified clays suggests that alginate adsorption is a spontaneous process. The adsorption of alginate onto modified clays was highly dependent on pH, with a decrease in adsorption observed with increased pH to 9.48, but the opposite was true above pH 9.48. Finally, adsorption increased with increasing ionic strength.  相似文献   

Hydrochemistry and sediment characteristics of polar periglacial lacustrine environments on Fisher Island and Broknes Peninsula,East Antarctica     

Raj esh Asthana  Prakash Kumar Shrivastav  Hari Bahadur Srivastava  Mirza Javed Beg  Pradeep Kumar 《极地研究(英文版)》2013,(4):281-295

Fisher Island and Broknes Peninsula in the Larsemann Hills constitute part of a polar lowland periglacial environment between marine and glacial ecosystems. The landscape is characterized by gently rolling hills and broad valleys interspersed with lakes formed in glacially scoured basins. We analyzed the physieochemical parameters and the ionic constituents of water samples from 10 lakes in each of these two locations. Our results showed considerable differences between the two regions and demon- strated the influence of lithology and processes including weathering, evaporation, and atmospheric precipitation. All major cations and anions in the lake waters showed positive correlations indicating balanced ionic concentrations. Unconsolidated sediments were sparsely distributed and scattered over glacial deposits, valley fills, and occasional moraine ridges. The type and rate of sedi- mentation was mainly controlled by surface run-off and aeolian influx. The sediment samples from lake beds and the catchment area on Fisher Island were immature and poorly to very poorly sorted, consisting of gravelly sand with negligible silt and finer fractions. Sediments had a polymodal grain size distribution with the two major populations lying between -2 and 1 phi and be- tween 0 and 1.5 phi. The sediments were lithic arenite to arkosic in composition and the microtextures imprinted over quartz grains were dominated by mechanical textures resulting from several stages of glacial crushing and grinding. The presence of deep disso- lution cavities, cryptocrystalline precipitation, and euhedral crystal growth signified the effect of chemical activity after the deposition of grains in the lacustrine environment.  相似文献   

中国铁路客运网络可达性空间格局   总被引：13，自引：6，他引：7  

吴威  曹有挥  梁双波  曹卫东 《地理研究》2009,28(5):1389-1400

基于铁路客运的基本特点,文章采用空间距离、时间距离、连接性、可选择性等多项指标对我国铁路客运网络可达性空间格局进行了分析。各项指标侧重点不同导致其反映的空间格局的明显差异。空间、时间距离指标均呈现以郑州为核心的中心－外围格局,但前者由中心向外围呈环状各向同性衰减,后者表现为各向异性,沿若干铁路干线衰减速度较慢; 连接性指标中东部地区优于西部,中心地区优于边缘,而可选择性指标东西分异显著,京广线以东(含京广沿线)地区明显优于西部地区。从空间均衡角度,主要体现铁路客运基本服务的空间距离、时间距离、连接性三指标相对较好,但偏重于高级服务的可选择性空间分布相对不均衡。主要铁路枢纽中,北京、上海、郑州、武汉等全国性铁路枢纽可达性明显优于广州、成都、兰州和沈阳等区域性枢纽。  相似文献   

Variability of heterotrophic activity in Mediterranean stream biofilms: A multivariate analysis of physical-chemical and biological factors     

Anna M. Romaní  Sergi Sabater 《Aquatic Sciences - Research Across Boundaries》2000,62(3):205-215

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Ar和H在矿物中的扩散补偿关系及其对扩散系数的预测   总被引：2，自引：0，他引：2  

赵子福 《地学前缘》2000,7(2):367-380

对现有实验扩散数据的检查发现 ,Ar和H两种元素在不同矿物中分别存在着扩散补偿关系。孔隙度作为矿物内部离子堆积密度的一种量度 ,它与Ar和H的扩散活化能之间存在负的线性相关性 ,因而可以用于预测元素在矿物中的扩散系数。文中采用离子孔隙度法预测了Ar和H在不同矿物中的扩散系数 ,得到的结果与已有的实验数据在实验误差范围内是一致的。由于扩散补偿效应 ,同一物质在不同矿物中的扩散速率在特定温度下趋于汇聚 ,Ar扩散的转折温度为 (86 0± 10 0 )℃ ,H扩散的转折温度为 (330± 50 )℃。这为地质过程中Ar和H扩散的封闭温度提供了一种借鉴 ,因此伴随Ar扩散的地质时钟在低于 86 0℃时才开始启动 ,共存矿物间的氢同位素地质温度计仅当温度低于 330℃时才是有效的。  相似文献