广西官村岩溶溪流中生物地球化学控制的DIC和NO3-昼夜变化研究     

张陶  蒲俊兵  袁道先  李建鸿 《地质学报》2016,90(8):1965-1976

为了解岩溶区控制溪流中溶解无机碳(DIC)和NO_3~-昼夜变化的生物地球化学过程以及DIC和NO_3~-日变化量,于2014-07-22~2014-07-24期间,在广西壮族自治区融安县官村溪流中包括地下河出口(CK)和下游雷崖村(LY)设置两个监测点同时对水体物理化学参数以及C、N同位素(δ~(13) CDIC、δ~(15) N-NO_3~-和δ~(18) O-NO_3~-)展开了为期2d的高分辨率昼夜监测采样工作。结果发现CK点各物理化学参数没有表现出昼夜变化,但是LY点Ca2+、DIC以及PCO2表现出明显的昼夜变化规律,即白天下降夜间上升且与DO和pH表现出明显的负相关关系。相对于CK点,在白天水生光合生物光合作用导致LY点DIC下降的同时δ~(13) CDIC上升,而在夜间呼吸作用导致LY点DIC上升的同时δ~(13) CDIC下降且部分时间段要低于CK点δ~(13) CDIC值。溪流中的NH4+在监测期间基本上都在下降而NO_3~-离子在夜间和上午时间段都在上升,δ~(15) N-NO_3~-却表现出下降的趋势,且比较接近δ~(15) N-NO_3~-初始值,而NO_3~-离子在下午时间段出现下降的趋势。结果表明溪流中DIC昼夜变化主要受到水生植物的光合作用和呼吸作用控制,且通过质量平衡方程计算得知溪流中由于光合作用吸收无机碳而转为有机碳的量为0.94kgC/d,这部分有机碳可以形成相对长期稳定的自然C汇。溪流在夜间和上午时间段发生了N的硝化作用,增长量为2.08kgN/d,但在下午时间段(12:00~18:00)发生了N的同化作用,损失量为0.42kgN/d。溪流输出的NO_3~--N的量为1.66kgN/d,表明在富碳、富钙的岩溶溪流中,有利于水生光合生物的生长,促进N的同化作用的发生,从而减少溪流输出NO_3~--N的量,说明岩溶区溪流N的生物地球化学过程可能在昼夜尺度上改变水质。  相似文献   

内蒙古东升庙和炭窑口多金属硫化物矿床铁同位素地球化学特征及其成矿指示意义     

高兆富  朱祥坤  高文革  王炳林  孙剑  罗照华  包创  唐超 《地质学报》2016,90(2):352-360

本文报道了内蒙古狼山成矿带内两个最大的铅锌多金属硫化物矿床——东升庙矿床和炭窑口矿床中黄铁矿、黄铜矿单矿物的铁同位素研究结果。东升庙矿床绢云石墨片岩中不规则状黄铁矿的铁同位素组成δ~(56)Fe_(-IRMM)值在+0.04‰~+1.11‰之间,呈现铁的重同位素富集,指示了海水中的铁以氧化态沉淀并在成岩期转化成黄铁矿的矿化过程。东升庙和炭窑口矿床富硫化物矿石中黄铁矿和黄铜矿的铁同位素组成δ~(56)Fe_(-IRMM)值的变化范围为-1.33‰~+0.08‰,具有热液成矿特征,指示金属成矿物质来源于热液流体。另外,绢云石墨片岩中脉状黄铁矿的铁同位素组成δ~(56)Fe_(-IRMM)值的变化范围为-0.39‰~-0.04‰,处于矿石黄铁矿和围岩不规则状黄铁矿之间,指示脉状黄铁矿是热液矿化的产物,并在成矿过程中混入了围岩中早先形成的富集铁的重同位素的黄铁矿。绢云石墨片岩中广泛发育的不规则状黄铁矿与赋存在绢云石墨片岩中的富硫化物矿体具有完全不同的铁同位素组成,指示热液活动对不规则状黄铁矿没有明显成矿物质贡献,因此同沉积热液活动成矿的可能性不大。结合赋存在白云石大理岩中硫化物矿体的顶、底部常见硅化的白云石大理岩角砾,本文提出后生矿化是东升庙多金属硫化物矿体的主要成矿方式。另外,东升庙矿床和炭窑口矿床的矿石硫化物具有相似的铁同位素组成特征,指示两者的成矿物质来源具有相似性。  相似文献   

Predictive geochemical mapping using environmental correlation     

《Applied Geochemistry》2016

The distribution of chemical elements at and near the Earth's surface, the so-called critical zone, is complex and reflects the geochemistry and mineralogy of the original substrate modified by environmental factors that include physical, chemical and biological processes over time.Geochemical data typically is illustrated in the form of plan view maps or vertical cross-sections, where the composition of regolith, soil, bedrock or any other material is represented. These are primarily point observations that frequently are interpolated to produce rasters of element distributions. Here we propose the application of environmental or covariate regression modelling to predict and better understand the controls on major and trace element geochemistry within the regolith. Available environmental covariate datasets (raster or vector) representing factors influencing regolith or soil composition are intersected with the geochemical point data in a spatial statistical correlation model to develop a system of multiple linear correlations. The spatial resolution of the environmental covariates, which typically is much finer (e.g. ∼90 m pixel) than that of geochemical surveys (e.g. 1 sample per 10-10,000 km²), carries over to the predictions. Therefore the derived predictive models of element concentrations take the form of continuous geochemical landscape representations that are potentially much more informative than geostatistical interpolations.Environmental correlation is applied to the Sir Samuel 1:250,000 scale map sheet in Western Australia to produce distribution models of individual elements describing the geochemical composition of the regolith and exposed bedrock. As an example we model the distribution of two elements – chromium and sodium. We show that the environmental correlation approach generates high resolution predictive maps that are statistically more accurate and effective than ordinary kriging and inverse distance weighting interpolation methods. Furthermore, insights can be gained into the landscape processes controlling element concentration, distribution and mobility from analysis of the covariates used in the model. This modelling approach can be extended to groups of elements (indices), element ratios, isotopes or mineralogy over a range of scales and in a variety of environments.  相似文献   

Laboratory Simulation of the Formation Process of Surface Geochemical Anomalies Applied to Hydrocarbon Exploration     

WANG Guojian  TANG Yuping  CHENG Tongjin  TANG Junhong  FAN Ming  LU Li 《《地质学报》英文版》2016,90(6):2149-2162

The formation mechanisms and processes of geochemical anomalies used as proxies in surface geochemistry exploration (SGE) have not been well understood. Previous studies cannot realize 3D measurement of microseeping hydrocarbons from reservoirs to the surface, which made it difficult to understand the features and pathways of deep hydrocarbon microseepages. Understanding the processes of hydrocarbon microseepages will contribute to the acceptance and effectiveness of surface geochemistry. Based on a simplified geological model of hydrocarbon microseepages, including hydrocarbon reservoir, direct caprock, overlying strata and Quaternary sediments, this work established a 3D experimental system to simulate the mechanisms and processes of deep hydrocarbon microseepes extending to the surface. The dispersive halos of microseeping hydrocarbons in the subsurface were adequately described by using this 3D experimental system. Results indicate that different migration patterns of hydrocarbons above the point gas source within the simulated caprock and overlying strata can be reflected by the ratio of i-butane to n-butane (i-C4/n-C4), which follow diffusion and infiltration (buoyancy) mechanisms. This is not the case for vertical measurement lines far from the point gas source. A vertical gas flow in the form of a plume was found during hydrocarbon microseepage. For sampling methods, the high-density grid sampling is favorable for delineating prospecting targets. Hydrocarbon infiltration or buoyancy flow occurs in the zones of infiltration clusters, coupling with a diffusion mechanism at the top of the water table and forming surface geochemical anomalies. These results are significant in understanding hydrocarbon microseepage and interpreting SGE data.  相似文献   

华南大规模低温成矿的主要科学问题   总被引：9，自引：7，他引：2  

胡瑞忠  付山岭  肖加飞 《岩石学报》2016,32(11):3239-3251

大面积低温成矿是全球独特的重要成矿事件。华南地区扬子地块西南部面积约50万平方千米的广大范围,低温矿床广泛发育,包括卡林型金矿床、MVT型Pb-Zn矿床和脉型锑、汞、砷等矿床,构成华南低温成矿域。该成矿域由川滇黔接壤区的Pb-Zn、右江盆地Au-Sb-As-Hg和湘中盆地Sb-Au等三个矿集区组成。其中的矿床主要赋存于沉积岩中,受断裂构造控制,形成于100~250℃的低温条件下。以往的研究取得了重要进展,但成矿时代、成矿动力学背景、成矿物质基础和成矿过程等关键科学问题一直悬而未决。近年的研究表明,这些矿床可能形成于200~230Ma(印支期)和130~160Ma(燕山期)两个时期,除川滇黔Pb-Zn矿集区由盆地卤水演化成矿外,其余两个矿集区的形成可能均受印支期和燕山期的深部岩浆活动驱动,尽管成矿流体中的水主要是大气成因地下水。本专题报道了近年来这些方面的最新研究进展,包括20篇文章,主要涉及这些低温矿床的地质地球化学特征、成矿时代、矿床成因和成矿动力学背景等。  相似文献   

青岛冷水团的消亡机理研究   总被引：1，自引：0，他引：1  

张启龙  刘志亮  齐继峰  杨德周  郑冬梅 《海洋学报》2016,38(5):27-33

本文基于多年月平均水温资料,分析了青岛冷水团的长消过程,并利用气候态月平均大气数据和数值模拟结果,探讨了青岛冷水团的消亡机理。结果表明,青岛冷水团3月出现,4月成型,5月最盛,6月减弱,7月消失;南黄海6-7月间偏南风的增强和温跃层以下反气旋涡的减弱是青岛冷水团消亡的动力机制,而海面净热通量的下传和水平热量的输入则是青岛冷水团消亡的热力机制。  相似文献   

Foundations of petroleum prediction based on the activation of geochemical processes by direct current     

V.Yu. Shigaev 《Russian Geology and Geophysics》2018,59(11):1508-1513

Petroleum prediction in local objects and the applicability of geologic environment parameters in this regard are considered. The proposed guidelines for petroleum potential prediction are based on the analysis of the distribution of typomorphic epigenetic multivalent elements loosely fixed in rocks before and after electric current treatment. The advantage of geoelectrochemical methods providing data on the chemical composition of above-productive deposits is demonstrated.  相似文献   

Origin of natural sulfur-metal chimney in the Tangyin hydrothermal field,Okinawa Trough: constraints from rare earth element and sulfur isotopic compositions     

《China Geology》2018,1(2):225-235

For the first time, we present the rare earth element (REE) and sulfur isotopic composition of hydrothermal precipitates recovered from the Tangyin hydrothermal field (THF), Okinawa Trough at a water depth of 1206 m. The natural sulfur samples exhibit the lowest ΣREE concentrations (ΣREE= 0.65×10^–6–4.580×10^–6) followed by metal sulfides (ΣREE=1.71×10^–6–11.63×10^–6). By contrast, the natural sulfur-sediment samples have maximum ΣREE concentrations (ΣREE=11.54×10^–6–33.06×10^–6), significantly lower than those of the volcanic and sediment samples. Nevertheless, the δEu, δCe, (La/Yb)_N, La/Sm, (Gd/Yb)_N and normalized patterns of the natural sulfur and metal sulfide show the most similarity to the sediment. Most hydrothermal precipitate samples are characterized by enrichments of LREE (LREE/HREE=10.09–24.53) and slightly negative Eu anomalies or no anomaly (δEu=0.48–0.99), which are different from the hydrothermal fluid from sediment-free mid-oceanic ridges and back-arc basins, but identical to the sulfides from the Jade hydrothermal field. The lower temperature and more oxidizing conditions produced by the mixing between seawater and hydrothermal fluids further attenuate the leaching ability of hydrothermal fluid, inducing lower REE concentrations for natural sulfur compared with metal sulfide; meanwhile, the negative Eu anomaly is also weakened or almost absent. The sulfur isotopic compositions of the natural sulfur (δ³⁴S=3.20‰–5.01‰, mean 4.23‰) and metal sulfide samples (δ³⁴S=0.82‰–0.89‰, mean 0.85‰) reveal that the sulfur of the chimney is sourced from magmatic degassing.  相似文献   

甘肃省龙首山芨岭铀矿床成矿热液流体特征研究     

赵如意  王博  陈毓川  王刚  陈云杰  聂利  李涛 《地球学报》2018,39(3):282-294

芨岭铀矿是中国北方最典型的钠交代型铀矿床之一,文章通过对芨岭矿床ZKJ9-4钻孔深部所见含矿蚀变闪长岩、近矿蚀变闪长岩、远矿蚀变闪长岩、闪长岩原岩地球化学特征和组分迁移计算及矿体中心部位的淡粉红色方解石脉流体包裹体特征、均一温度、盐度和激光拉曼光谱研究,认为芨岭钠交代型铀矿床的成矿流体含有大量碳酸铀酰络合物[UO_2(CO_3)_2]~(2–)和[UO_2(CO_3)_2]~(4–)的同时还含有丰富的SiO_2、Na~+、Ca~(2+)、Mg~(2+)、Fe~(2+)、Mn~(2+)、∑REE、U、Th、Ga、Sr、Zr、Ba、Rb、Nb、Mo、Cd、Sn、Hf、Ti、Ta、CO_2、H_2S和CH_4等组分,成矿流体具有较强的还原性,并对MnO、K_2O、Cr和Co具有较强的交代溶蚀作用。成矿流体是起源于岩浆演化晚期的再平衡岩浆水,热液温度为(300±20)℃,盐度为2.99 wt%~4.57 wt%NaCl,密度为0.75~0.77 g/cm~3。流体沸腾是芨岭钠交代型铀矿成矿物质的早期卸载机制,晚期成矿流体中加入了大量的大气降水,流体混合作用进一步促进了成矿物质的卸载。  相似文献   

黄河口清水沟河道的冲淤过程与模拟          下载免费PDF全文

郑珊  吴保生  周云金  王开荣  韩沙沙 《水科学进展》2018,29(3):322-330

为揭示黄河口清水沟河道长时段的冲淤演变规律并建立其冲淤计算方法,分析了清水沟1976—2015年的时空冲淤演变过程,采用河床演变的滞后响应模型,考虑河口来水来沙及河道延伸与蚀退的影响,建立了清水沟累计冲淤量的计算方法。结果表明:1976—1980年改道初期清水沟改道点上游先冲后淤,改道点下游淤滩塑槽,淤积量随着下游河道展宽而增加,1980年后改道点上、下游河道冲淤过程趋于一致;受水沙条件等因素影响,1980—1986年清水沟主槽冲刷展宽,之后主槽淤积萎缩;1996年清八改汊和2002年小浪底水库"调水调沙"原型试验以来,河道转淤为冲,2002年后河道冲刷速率随时间指数衰减;河床演变的滞后响应模型可计算清水沟长时段的冲淤过程,该方法可为预测未来清水沟冲淤演变趋势提供科学参考。  相似文献