Treatment of Arsenic Contaminated Groundwater Using Calcium Impregnated Granular Activated Carbon in a Batch Reactor: Optimization of Process Parameters     

Prasenjit Mondal  Bikash Mohanty  Chandrajit Balomajumder 《洁净——土壤、空气、水》2010,38(2):129-139

This paper is an experimental investigation into the removal of arsenic species from simulated groundwater by adsorption onto Ca²⁺ impregnated granular activated carbon (GAC‐Ca) in the presence of impurities like Fe and Mn. The effects of adsorbent concentration, pH and temperature on the percentage removal of total arsenic (As(T)), As(III) and As(V) have been discussed. Under the experimental conditions, the optimum adsorbent concentration of GAC‐Ca was found to be 8 g/L with an agitation time of 24 h, which reduced As(T) concentration from 188 to 10 μg/L. Maximum removal of As(V) and As(III) was observed in a pH range of 7–11 and 9–11, respectively. Removal of all the above arsenic species decreased slightly with increasing temperature. The presence of Fe and Mn increased the adsorption of arsenic species. Under the experimental conditions at 30°C, the maximum percentage removals of As(T), As(III), As(V), Fe, and Mn were found to be ca. 94.3, 90.6, 98.0, 100 and 63%, respectively. It was also observed that amongst the various regenerating liquids used, a 5 N H₂SO₄ solution exhibited maximum regeneration (ca. 91%) of the spent GAC‐Ca.  相似文献   

路基沉降预测的三点修正指数曲线法   总被引：2，自引：0，他引：2  

陈善雄  王星运  许锡昌  余飞  秦尚林 《岩土力学》2011,32(11):3355-3360

科学、合理地预测路基工后沉降量是高速铁路建设的关键环节。针对武广高速铁路路基沉降量级小、数据相对波动大的实测数据,探讨了指数曲线法对无砟轨道路基沉降预测的适用性,发现指数曲线法不能直接应用于量级小、数据相对波动较大的沉降预测。把三点法的基本思想引入指数曲线模型,对指数曲线法进行了改进,提出了路基沉降预测的三点修正指数曲线模型。结合武广高速铁路路基沉降观测数据,分析了三点修正指数曲线模型的特性。分析表明,在整个沉降曲线上选取3个关键点作为预测样本,很好地回避了数据波动带来的影响;沉降曲线上“拐点”以后的沉降规律更符合指数曲线模型,因此,应取沉降曲线上“拐点”以后的数据作为样本值,所取三点应能尽量反映沉降发展的趋势。三点修正指数曲线法预测结果稳定、相关系数高,具有一定的工程应用价值  相似文献   

动载下饱和重塑黄土的骨干曲线变化研究   总被引：1，自引：0，他引：1  

廖红建  肖正华  刘健 《岩土力学》2011,32(2):375-379

针对饱和重塑黄土进行了一系列等向固结和偏压固结下的排水与不排水动三轴试验,分析了饱和重塑黄土的动力性质、骨干曲线模型及其影响因素。基于动三轴试验结果,探讨了在考虑累积塑性应变影响下,修正Hardin-Drnevich模型的适用性。结果表明,考虑累积塑性应变时,修正Hardin-Drnevich模型能够较好地模拟饱和重塑黄土的骨干曲线试验结果。进而分析了等向固结和偏压固结、固结围压、波形和排水条件等因素对饱和重塑黄土骨干曲线的影响,得到偏压固结和固结围压的增大使骨干曲线上移,土体强度增加,而波形对骨干曲线的影响较小;排水条件下的骨干曲线较不排水条件下的有所上移,土体强度增加。所得结论可供工程设计人员参考。  相似文献   

有限元与改进单纯形法联合编程技术在位移反分析中的应用   总被引：1，自引：0，他引：1  

肖铭钊  周承豪  程芸  冯晓腊  杨俊梅 《岩土力学》2011,32(3):899-904

根据弹性地基梁法基本思想,考虑基坑分步开挖和逐级加撑的动态施工因素,通过有限元计算模拟基坑实际开挖过程。结合现场监测数据,采用位移反分析方法反演各土层m 值,并准确预测后续工况支护体的变形。采用有限元通用软件ANSYS内嵌的APDL语言编程建立支护体有限元计算模型,并应用数学软件MATLAB编制“改进单纯形法”优化程序,编写了接口程序,实现了MATLAB对ANSYS模型的实时循环调用和逐步寻优。武汉长江隧道武昌明挖段基坑工程算例证明,基于单纯形法的联合编程技术能方便、高效地被应用于支护体位移反分析预测中。建立了基于本工况预测下一工况或相邻断面的扩展型位移反分析预测模型,预测结果与实测结果拟合程度较高。  相似文献   

砂土中单桩基础冲刷的修正应变楔计算          下载免费PDF全文

杨晓峰  张陈蓉  黄茂松  袁聚云  高博雷 《地震工程学报》2016,38(4):549-553

由冲刷引起的深水结构物桩基础周围土体损失致使基础水平承载性能下降的问题越发受到重视。应变楔方法假设桩前土体抵抗为三维楔形体,其尺寸发展与楔形体区域土体发挥的内摩擦角有关,从而得到水平受荷桩的p-y曲线。本文对应变楔方法进行修正和拓展,建立非线性位移假设以考虑桩前楔形体区域土体应变沿深度的非均匀分布,将冲刷坑底以上土体的有效自重作用等效为竖向荷载,对楔形体的深度进行修正,以解决楔形体方法只适用于地表水平的情况,得到砂土中单桩基础冲刷的修正应变楔计算方法;并通过与模型试验及三维有限元分析的对比来验证该方法的合理性。分析结果表明:冲刷深度增加会显著降低桩基水平承载性能,冲刷深度3.2D和6.4D情况下的桩顶位移比平均值分别趋近于1.8和3.0;相比有限元方法,本文修正SW方法计算的p-y曲线结果与实测结果更为接近。  相似文献   

基于MSAVI-WI特征空间的新疆渭干河-库车河流域绿洲土壤盐渍化研究   总被引：5，自引：0，他引：5  

丁建丽  瞿娟  孙永猛  张永福 《地理研究》2013,32(2):223-232

土壤盐渍化是造成干旱区土地荒漠化及生态恶化的重要原因,及时获取大尺度高精度土壤盐渍信息是防治工作的基础。选取新疆塔里木盆地北缘渭干河—库车河流域三角洲绿洲为研究区,利用Lansat-TM数据与野外实测数据分析盐渍化土壤与修改型土壤调整植被指数(MSAVI)、湿度指数(WI)之间的关系,在此基础上提出了MSAVI-WI特征空间概念,构建了土壤盐渍化遥感监测指数模型(MWI)。结果表明:MWI与土壤表层含盐量相关性较高,其相关性为0.844,精度高于土壤盐渍监测常用的盐分指数与实测数据的相关性。MWI能较好的反映盐渍化土壤地表植被及土壤水分的组合变化,具有明确的生物物理意义,并且特征参量简单,理论上易于理解,实践上易于实现,MWI模型的构建有利于干旱区大尺度土壤盐渍化定量监测与评价工作的开展。  相似文献   

深部围岩流变特性试验研究及其模型辨识   总被引：2，自引：2，他引：0       下载免费PDF全文

刘正  高文华  刘栋  邓修甫 《水文地质工程地质》2012,39(4):43-48

采用分级增量循环加卸载方式,对湖南湘煤集团牛马司矿业公司水井头煤矿-300m东大巷二煤层底板粉砂岩进行了单轴蠕变特性试验,详细探讨了轴向蠕变变形特征,蠕变速率与时间和应力水平的关系,瞬时弹性模量和变形模量变化特征.试验结果表明,当应力水平低于岩石的长期强度时,粉砂岩只发生衰减蠕变,应力水平对蠕变速率变化的影响不明显;当应力水平高于岩石的长期强度时,岩石等速蠕变阶段明显.对流变试验数据进行深入分析的基础上,进行了流变模型辨识和基于最小二乘法的参数确定.根据不同应力水平下加卸载过程中岩石的蠕变特点,提出了采用改进的两原模型模拟岩石的蠕变特性.模型计算结果表明,改进后的西元模型既能够较好地描述低应力下的衰减蠕变,又能较精确地描述高应力下岩石的衰减蠕变和等速蠕变特性.  相似文献   

An efficient focusing model for generation of freak waves   总被引：1，自引：1，他引：0  

LIU Zanqiang  ZHANG Ningchuan  YU Yuxiu 《海洋学报(英文版)》2011,30(6):19-26

Based on the Longuet-Higgins wave model theory, the previews studies have shown that freak waves can be generated in finite space and time successfully. However, as to generating high nonlinear freak waves, the simulation results will be unrealistic. Therefore, a modified phase modulation method for simulating high nonlinear freak waves was developed. The surface elevations of some wave components at certain time and place are positive by modulating the corresponding random initial phases, then the total surface elevation at the focused point is enhanced and furthermore a freak wave event is generated. The new method can not only make the freak wave occur at certain time and place, but also make the simulated wave surface time series satisfy statistical properties of the realistic sea state and keep identical with the target wave spectrum. This numerical approach is of good precision and high efficiency by the comparisons of the simulated freak waves and the recorded freak waves.  相似文献   

Fe-ZSM-5分子筛催化降解染料废水的研究     

毕海超  赵俊梅  董建芳  李义 《岩矿测试》2013,32(1):119-123

传统的Fenton均相亚铁盐催化剂处理染料废水,具有难以避免的二次污染和亚铁离子流失问题。分子筛催化剂相比传统催化剂具有高效环保的特点,在催化氧化染料废水领域有着良好的前景。本文通过液相离子交换法制备了Fe-ZSM-5非均相分子筛催化剂,替代传统的亚铁盐催化剂,应用X射线衍射对制备的Fe-ZSM-5分子筛催化剂进行表征,表明随离子交换次数的增加,Fe-ZSM-5催化剂负载的铁量上升,且较好地保持了分子筛结构,有利于提高亚铁离子的催化能力。通过实验确定了Fe-ZSM-5催化剂催化反应的最佳温度、pH值、Fe-ZSM-5的用量、反应时间等工艺参数,比较了Fe-ZSM-5催化剂和传统Fenton均相催化剂降解染料废水的脱色率和废水中铁离子的残留量,结果表明Fe-ZSM-5的脱色率达到98.5%,相比于Fenton均相催化剂的脱色率提升约3%;两种催化剂的铁离子残留量差别显著,Fe-ZSM-5催化剂处理的废水中只产生微量的Fe离子,可以认为Fe-ZSM-5非均相分子筛催化剂有效地解决了催化剂损耗和二次污染问题。  相似文献   

Determination of passive earth pressure with lower bound finite elements limit analysis and modified pseudo-dynamic method     

《Geomechanics and Geoengineering》2013,8(3):218-229

ABSTRACT

The present study deals with the determination of passive earth pressure under seismic condition by following the lower bound finite elements limit analysis and modified pseudo-dynamic methodology. In accordance with the lower bound finite elements formulation, the stress field was modelled using a three-noded triangular elements, while the passive pressure was determined via linear optimisation. The parametric study was performed, for a vertical rigid retaining wall, by varying the magnitude of seismic acceleration in horizontal direction (k_h) between 0 and 0.3, while the vertical seismic acceleration (k_v) was kept equal to 0 or 0.5 k_h. Furthermore, the damping coefficient for dry cohesionless backfill was kept ξ = 10%. The obtained results in various cases were found to be in good agreement with those found in the literature. It is expected that this method can be further used for solving other important geotechnical stability problems.  相似文献