电感耦合等离子体质谱法测定铅合金中的微量杂质元素镉和锡   总被引：1，自引：1，他引：0  

郝原芳  刘新  宋丽华  李丽君  徐英奎 《岩矿测试》2016,35(4):378-383

铅合金中的镉和锡由于含量较低,国家标准方法均为单一元素分析,步骤繁琐,检出限高,难以达到理想的检出要求。本文建立了应用电感耦合等离子体质谱法(ICP-MS)测定铅合金中微量级(μg/g级)杂质元素镉和锡的分析方法。采用单一的低浓度硝酸溶解铅合金,用低温慢溶的方式使样品溶解更加完全,减少了多离子对仪器的干扰;通过铅基体匹配和加入酒石酸保证了标准与样品介质的一致性,同时避免了锡的水解;以~(103)Rh作为内标元素,~(111)Cd和~(118)Sn作为测量同位素克服了质谱干扰。方法检出限为镉0.05 ng/g、锡0.04 ng/g,比国家标准方法的检出限(1~6μg/g)低,精密度小于4%。该方法试剂用量少,减少了处理样品的复杂性,实现了合金中微量级元素的准确测定。  相似文献   

非匀一冠层热辐射方向性3维模型构建——以玉米冠层为例     

马红章  刘素美  孙根云  杜永明  孙林  柳钦火 《遥感学报》2016,20(3):374-381

建立适用于多类型植被场景的热辐射方向性模型是进行地表热辐射方向性研究的一种手段。利用真实植株几何及生理参数的统计平均值来刻画理念植株,并给定其空间分布特征,进行不同生长期植被冠层的描述。基于冠层双向孔隙率思想构建了冠层热辐射方向性3维模型,模型继承了孔隙率模型在计算冠层热辐射方向性上的简洁优势同时以几何光学的思想考虑了冠层空间异质性对冠层热辐射方向性的影响。以玉米冠层为例,进行了不同生长期玉米冠层热辐射方向亮温的模拟,通过与实地测量数据的比对表明,本文发展的模型能够较准确地模拟不同生长期玉米植被场景的方向亮温变化规律,模拟误差主要来自理念株的刻画误差、玉米叶片形状的近似以及忽略了多次散射贡献等3个方面。模型的构建方法对稀疏植被场景、浓密植被场景、多类型植被的混合场景均可适用,不同观测几何下的植被场景4组份面积比计算结果有望应用于复杂地表条件下地表返照率的研究。  相似文献   

Ontogenic variation and effect of collection procedure on leaf biomechanical properties of Mediterranean seagrass Posidonia oceanica (L.) Delile          下载免费PDF全文

Carmen B. de los Santos  Bárbara Vicencio‐Rammsy  Gilles Lepoint  François Remy  Tjeerd J. Bouma  Sylvie Gobert 《Marine Ecology》2016,37(4):750-759

Leaf mechanical traits are important to understand how aquatic plants fracture and deform when subjected to abiotic (currents or waves) or biotic (herbivory attack) mechanical forces. The likely occurrence of variation during leaf ontogeny in these traits may thus have implications for hydrodynamic performance and vulnerability to herbivory damage, and may be associated with changes in morphologic and chemical traits. Seagrasses, marine flowering plants, consist of shoot bundles holding several leaves with different developmental stages, in which outer older leaves protect inner younger leaves. In this study we examined the long‐lived seagrass Posidonia oceanica to determine ontogenic variation in mechanical traits across leaf position within a shoot, representing different developmental stages. Moreover, we investigated whether or not the collection procedure (classical uprooted shoot versus non‐destructive shoot method: cutting the shoot without a portion of rhizome) and time span after collection influence mechanical measurements. Neither collection procedure nor time elapsed within 48 h of collection affected measurements of leaf biomechanical traits when seagrass shoots were kept moist in dark cool conditions. Ontogenic variation in mechanical traits in P. oceanica leaves over intermediate and adult developmental stages was observed: leaves weakened and lost stiffness with aging, while mid‐aged leaves (the longest and thickest ones) were able to withstand higher breaking forces. In addition, younger leaves had higher nitrogen content and lower fiber content than older leaves. The observed patterns may explain fine‐scale within‐shoot ecological processes of leaves at different developmental stages, such as leaf shedding and herbivory consumption in P. oceanica.  相似文献   

基于SPOT6遥感影像的滩涂湿地入侵种互花米草植株高度的反演研究   总被引：1，自引：0，他引：1  

周在明  杨燕明  陈本清 《海洋学报》2016,38(6):1-7

本文以SPOT6 高空间分辨率遥感影像为数据源,通过植被覆盖度和地上生物量两个参数进行滩涂湿地入侵种互花米草植株高度的估算研究。结果表明,三沙湾滩涂湿地互花米草植株高度平均值为2.04 m,以1~2 m和2~3 m植株为主要分布高度,分布面积分别为6.83 km2和10.31 km2,占研究区互花米草总面积的33.83%和51.06%,小于1 m和大于3 m的互花米草仅占9.26%和5.84%。估算值与真实值之间的均方根误差为0.204,绝对误差为0.04~0.37 m。该方法是对高空间分辨率光学影像应用研究的重要尝试,其反演方法具有较好的可行性,可较为准确的获取滩涂湿地植株高度信息。  相似文献   

使用多普勒超声成像比较栉孔扇贝与虾夷扇贝循环生理特征     

郝杰华  许强  汝少国  杨红生 《海洋与湖沼》2016,47(1):29-35

将先进的多普勒超声成像技术运用于栉孔扇贝(Chlamys farreri)和虾夷扇贝(Patinopecten yessoensis)循环生理学的研究中,首次量化了扇贝心率(HR)、血流加速度(ABF)、收缩峰值速度(PS)、舒张末期速度(ED)、血液最大瞬时血流量(Max-IBF)、血液最小瞬时流量(Min-IBF)、收缩期与舒张期流速比(S/D)和阻力指数(RI)等指标,对比了两种不同耐温性扇贝的循环生理指标差异。结果表明,两种扇贝HR、ABF、PS、ED、Max-IBF、Min-IBF与水温均呈正相关;在10—25°C间,栉孔扇贝和虾夷扇贝HR范围分别为16—39、14—31次/min,ABF范围分别为1.75—15.84、0.99—7.41cm/s2,PS范围分别为3.54—8.09、2.32—8.85cm/s,ED范围分别为1.51—3.15、1.09—4.23cm/s,Max—IBF范围分别为0.051—0.193、0.137—0.316m L/s、Min—IBF范围分别为0.025—0.072、0.022—0.131m L/s、RI范围分别为0.49—0.69、0.42—0.54,S/D范围为2.28—2.83、1.75—2.12。同一温度下栉孔扇贝的HR、ABF、PS、ED指标水平均高于虾夷扇贝,Max-IBF、Min-IBF水平均低于虾夷扇贝;两种扇贝RI和S/D指标均在一定范围内波动。研究显示,虾夷扇贝在较低的心脏和血流搏动节律下保持了高效的血液流通,从而以相对较少的能量消耗维持了其机体代谢对血液循环的需求,这也与其冷水性的生态习性相适应。  相似文献   

台山核电邻近海域春秋季浮游植物群落结构特征     

粟丽  黄梓荣  徐珊楠  陈作志 《海洋科学》2016,40(9):61-68

根据2013年4月(春季)和9月(秋季)2个航次调查数据,对台山核电邻近海域浮游植物种类组成、时空分布及多样性指数等群落特征进行了分析。共鉴定浮游植物3门61种,其中硅藻类48种,占78.69%;甲藻类11种,占18.03%;金藻类2种,占3.28%。种类组成以暖水种和广温种为主。浮游植物丰度均值春季(11.78×107个/m3)与秋季(29.37×107个/m3)无明显差异;然而丰度水平变化较大,整体表现为春秋两季核电站温排水口附近站位均低于远离站位。春秋两季浮游植物优势种共出现了7种,春季仅出现了中肋骨条藻Skeletonema costatum1种,优势度高达0.996;秋季出现了7种,包括中肋骨条藻(0.291)、柔弱拟菱形藻Pseudo-nitzschia delicatissima(0.222)、拟弯角毛藻Chaetoceros pseudocurvisetus(0.214)和并基角毛藻Chaetoceros decipiens(0.056)等。海域春季Shannon-Wiener多样性指数H′、Pielou均匀度指数J′和Margalef物种丰富度指数D均值分别为0.55、0.18和0.50;秋季分别为2.80、0.62和0.80。多样性指数显示台山核电附近海域水质状态受到了一定程度的污染。  相似文献   

Effect of the Dry Ashing Method on Cadmium Isotope Measurements in Soil and Plant Samples     

Wei‐Xin Lv  Hao‐Ming Yin  Meng‐Shu Liu  Fang Huang  Hui‐Min Yu 《Geostandards and Geoanalytical Research》2021,45(1):245-256

A dry ashing method is commonly used to remove organic material from samples prior to geochemical analysis. In the course of this study, the Cd isotope ratios of a series of soil and plant reference materials and samples were studied to evaluate the effect of the dry ashing method on measurement results of Cd isotope ratios. The samples were pre‐treated using the dry ashing method and high‐pressure bomb for comparison. The results show that the digestion using high‐pressure bombs did not lead to Cd loss, but using the dry ashing method would cause different proportions of Cd loss. The whole range of Cd isotope difference between two methods was from ?0.07‰ to 3.01‰. There was also an obvious difference in measured Cd isotope ratios from the same leaf sample pre‐treated independently by the dry ashing method, indicating that the amount of Cd loss and the effect on Cd isotope measurement during dry ashing is related to the properties of the samples. Therefore, dry ashing may not be appropriate for the removal of organic material in Cd isotope ratio measurement, especially for samples with high organic contents. The δ^114/110Cd values of reference materials NIST SRM 1573a and GSD‐30 are reported for the first time in this study.  相似文献   

Poor fen succession over ombrotrophic peat related to late Holocene increased surface wetness in subarctic Quebec,Canada     

MICHELLE GARNEAU  ALEXANDRE LAMARRE  ÉLISABETH C. ROBERT  GABRIEL MAGNAN  HANS ASNONG  STEVE PRATTE 《第四纪科学杂志》2013,28(8):748-760

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The influence of medium-range transport on O3 levels at a rural site in Israel     

Batia Lifshitz  Mordechai Peleg  Menachem Luria 《Journal of Atmospheric Chemistry》1988,7(1):19-33

Simultaneous ozone measurements were made at a rural site, 25 km SSW of the city of Jerusalem, and in the center of the city during a period of 28 months. The ozone data were supplemented by SO₂, NO/NO _x ,and meteorological measurements at both sites. Elevated ozone concentrations were recorded at the rural site, mostly during the spring months (May and June) during which the monthly averages and the monthly averages of the daily 30 min maximum levels equalled those measured in the city. During the summer months, both average and peak levels were lower at the rural site by 20 and 35 ppb. The increased ozone levels at the rural site were accompanied by a parallel increase of SO₂ and NO _x ,suggesting hat the excess ozone at the rural site is a result of a transformation during transport of air pollutants from coastal sources.  相似文献   

淮北煤田早二叠世化石植物古生态     

杜美利 《中国煤田地质》1994,6(4):21-25

淮北煤田早二叠世化石植物丰富，其形成于炎热多雨的热带滨海三角洲沉积体系中。下三角洲平原是该区化石植物最宜生长的地方。早二叠世该区化石植物常形成四类植物群落：森林沼泽植物群落、沿岸水生植物群落、高地植物群落、三角洲平原真蕨及种子蕨混生植物群落（早期）、树蕨－大羽羊齿类雨林植物群落（晚期）。随着时间的推移，这四类植物群落的结构及面貌发生着不断的变化；其演替显示，早二叠世晚期该区气侯更加湿热，雨林气侯更为普遍。  相似文献