基于五种油源的中重度风化溢油的常规鉴定指标的应用效果评估     

贺世杰  王传远  李延太  于洪军  韩彬 《海洋学报(英文版)》2016,35(4):1-8

本文利用采集于我国三大油田的五种原油样品开展了长达210天的溢油风化模拟实验,并依据相对偏差和重复性限数学分析法,进行溢油风化过程分析和诊断比值应用效果评估。研究结果表明:经过210天的风化,溢油鉴定诊断比值发生明显改变;其中来源于萜烷、甾烷和多环芳烃的诊断比值变化率要远低于正构烷烃,可用于中长期风化溢油鉴定。此外,研究发现,在这些有效诊断比值中有4个变化率较小,相对偏差低于5%,保持了较好的稳定性,更适合于重度风化溢油鉴定。  相似文献   

四川盆地东部垫江凹陷三叠系嘉陵江组岩盐氯同位素特征与成钾指标研究   总被引：1，自引：0，他引：1  

唐清敏  张雄  朱正杰  魏玉燕  刘永旺  刘振 《地质学报》2018,92(8):1671-1679

垫江凹陷位于四川盆地东部,是四川盆地三叠纪时期重要的成盐凹陷之一,但当时古卤水是否达到钾盐沉积阶段,是否具备形成海相钾盐的良好条件,一直存在争议。本文通过对垫江凹陷长平3井、高探1井和ZK001井嘉陵江组岩盐样品进行化学成分分析,以及对长平3井典型岩盐样品进行氯同位素分析来判断古卤水沉积阶段和成钾条件。结果发现垫江凹陷三叠系嘉陵江组岩盐δ37 Cl值均为负值,均小于-0.32‰,最低达到-1.18‰,绝大部分岩盐样品溴氯系数大于0.31,有很大一部分样品溴氯系数超过0.45,进一步表明垫江凹陷在嘉陵江期古卤水浓缩已达到钾石盐析出阶段,与岩盐包裹体成分分析结果一致。综合气候-物源-构造因素,认为垫江凹陷三叠纪嘉陵江期气候条件炎热,物质来源丰富,存在次级凹陷,古构造条件优越,具备良好的成钾潜力。  相似文献   

Influence of Sea Surface Temperature on the Predictability of Idealized Tropical Cyclone Intensity     

钟权加  李建平  李舒文  王羱  丁瑞强  张立凤 《热带气象学报(英文版)》2021,27(4):355-367

The role of sea surface temperature (SST) forcing in the development and predictability of tropical cyclone (TC) intensity is examined using a large set of idealized numerical experiments in the Weather Research and Forecasting (WRF) model. The results indicate that the onset time of rapid intensification of TC gradually decreases, and the peak intensity of TC gradually increases, with the increased magnitude of SST. The predictability limits of the maximum 10 m wind speed (MWS) and minimum sea level pressure (MSLP) are ~72 and ~84 hours, respectively. Comparisons of the analyses of variance for different simulation time confirm that the MWS and MSLP have strong signal-to-noise ratios (SNR) from 0-72 hours and a marked decrease beyond 72 hours. For the horizontal and vertical structures of wind speed, noticeable decreases in the magnitude of SNR can be seen as the simulation time increases, similar to that of the SLP or perturbation pressure. These results indicate that the SST as an external forcing signal plays an important role in TC intensity for up to 72 hours, and it is significantly weakened if the simulation time exceeds the predictability limits of TC intensity.  相似文献   

Polycyclic aromatic hydrocarbons and their molecular diagnostic ratios in urban atmospheric respirable particulate matter   总被引：2，自引：5，他引：2  

María del Rosario Sienra  Nelson G. Rosazza  Margarita Prndez 《Atmospheric Research》2005,75(4):267-281

Atmospheric concentrations of polycyclic aromatic hydrocarbons (PAHs) in Santiago de Chile city were evaluated to study particulate PAHs profiles during cold and spring weather periods. Urban atmospheric particulate matter PM10 was collected using High Volume PM10 samplers. Fifteen samples of 24 h during austral winter and 20 samples of 24 h during spring, 2000 were collected at two sampling sites (North–East and Central areas of the city) whose characteristics were representative of the prevailing conditions. Seventeen PAHs were quantified and total PAHs concentration ranged from 1.39 to 59.98 ng m⁻³, with a seasonal variation (winter vs. spring ratio) from 0.5 to 12.6 ng m⁻³. Molecular diagnostic ratios were used to characterize and identify PAHs emission sources such as combustion and biogenic emissions. Results showed that the major sources of respirable organic aerosol PM10 in Santiago are mobile and stationary ones.  相似文献   

Advection in plankton models with variable elemental ratios     

James R. Christian 《Ocean Dynamics》2007,57(1):63-71

As ocean biogeochemical models evolve to permit the elemental composition of plankton populations and dissolved organic matter to vary, each element is normally assigned a separate state variable, which is advected and mixed independently of the others. In a population of cells with varying elemental quotas, the proper currency of the advection operator is subpopulations of similar cells. The spatial gradient in total C, N, or P summed over the spectrum of such subpopulations is identical to that calculated for the population means, so treating the various elements as independent should generally be a valid approximation. However, errors can arise in high-order advection schemes with nonlinear corrector terms, which are not additive across the subpopulations. Some numerical examples indicate that these errors are relatively small [O(10⁻³–10⁻⁴)] but can be as high as O(10⁻²) in certain cases. As grid resolution varies, the error scales approximately to the Courant number.  相似文献   

A darkling beetle population in West Texas during the 1997–1998 El Niño     

Richard J. Deslippe  Jesus R. Salazar  Yu-Jie Guo 《Journal of Arid Environments》2001,49(4):711

We examined the abundance and distribution of Eleodes extricata (Tenebrionidae) in a semi-arid region of West Texas. During the 2-year study, climatic conditions were extreme but opposite, with 1997 being unusually wet and mild, and 1998 being unusually dry and hot. These conditions were associated with striking differences in the population structure of the beetles. Under identical pitfall-sampling efforts, we captured 1562 and 671 individuals in 1997 and 1998, respectively. Capture rates were lowest in grassland, and highest in sand shinnery oak, and within the latter, they were lowest in blowouts, intermediate along the edges of blowouts, and highest under vegetative cover. Sex ratios were consistently female-biased, and the degree of bias increased from spring through fall in both years. These increases were more pronounced in 1998, with the sex ratios of early and late sampling periods differing by over four-fold, from 1·15 to 5·00. Females were heavier than males, and the dry masses of both sexes increased from spring though fall in both years. As with sex ratios, these increases were more pronounced in 1998. Only the largest beetles survived the drought, illustrating how extreme conditions can exert especially strong directional selection, and affect sex ratios in populations with sexual size dimorphism.  相似文献   

Sediment shear Q from airgun OBS data   总被引：2，自引：0，他引：2  

P. D. Bromirski  L. N. Frazer  F. K. Duennebier 《Geophysical Journal International》1992,110(3):465-485

  相似文献   

Remineralization Ratios in the Subtropical North Pacific Gyre   总被引：2，自引：0，他引：2  

Yuan-Hui Li  David M. Karl  Christopher D. Winn  Fred T. Mackenzie  Kathleen Gans 《Aquatic Geochemistry》2000,6(1):65-85

Based on a new mixing model of two end-members, the water column remineralization ratios of P/N/C_org - O₂ = 1/13 ± 1/135 ± 18/170 ± 9 are obtained for the Hawaii Ocean Time-series (HOT) data set at station ALOHA. The traditional Redfield ratios of P/N/C_org/–O₂ = 1/16/106/138 have standard deviations of more than 50%, when they are based on the average composition of phytoplankton. Apparently, the remineralization processes in the water column have smoothed out the observed large variability of plankton compositions. A new molar formula for the remineralized plankton may be written as ₁₃₅H₂₈₀O₁₀₅N₁₃P or C₂₅(CH₂O)₁₀₁(CH₄)₉(NH₃)₁₃(H₃PO₄). Oxidation of this formula results inC₂₅(CH₂O)₁₀₁(CH₄)₉(NH₃)₁₃(H₃PO₄) + 170O₂ 135CO₂ + 132H₂O + 13NO₃ ^- + H₂PO₄ ^- + 14H⁺.For comparison, remineralization using Redfield's formula gives:(CH₂O)₁₀₆(NH₃)₁₆(H₃PO₄) + 138O₂ 106CO₂ + 122H₂O + 16NO₃ ^-+ H₂PO₄ ^- + 17H⁺  相似文献   

Carbon isotope ratios of C_4 plants in loess areas of North China     

WANG Guoan  HAN Jiamao  ZHOU Liping  XIONG Xiaogang  TAN Ming  WU Zhenhai  PENG Jun 《中国科学D辑(英文版)》2006,49(1)

Recent stable carbon isotope studies have shown that the occurrence of C4 plants on the Earth was much later than that of C3 plants and there was a global ex-pansion of C4 biomass around 5―8 million years ago[1]. Although far fewer species use the C4 pat…  相似文献   

A technique for atmospheric measurements of stable carbon isotope ratios of isoprene,methacrolein, and methyl vinyl ketone     

R. Iannone  R. Koppmann  J. Rudolph 《Journal of Atmospheric Chemistry》2007,58(3):181-202

A technique was developed to measure stable carbon isotope ratios (¹³C/¹²C) of light volatile organic compounds (VOCs) such as isoprene, methacrolein (MACR) and methyl vinyl ketone (MVK) using gas chromatography combustion isotope ratio mass spectrometry (GCC-IRMS). An automated sampling and cryofocussing system allowed for the extraction of VOCs from air samples of up to 140 L of air collected over 3 h, and the subsequent ¹³C/¹²C analysis of the VOCs by GCC-IRMS. Chromatography using selective transfer between two columns was used to improve the separation for selected compounds, increasing peak resolution and attaining less noisy baselines. Still, some target compounds could not be completely separated from co-eluting peaks. To reduce the bias of isotope ratio determinations, which can result from incomplete peak resolution, a peak-fitting procedure has been developed. In cases of overlapping peaks or substantial baseline drift, this peak fitting allows more accurate determination of isotope ratios than conventional integration schemes. Comparisons between off-line IRMS measurements and a peak-evaluation procedure using a prepared VOC gas-phase standard show that isotope ratios derived from large (>1 ng of carbon per peak) and well-resolved peaks have a reproducibility of ±0.3‰. With smaller masses in the range of 0.1–1 ng of carbon, reproducibility decreased to ±(0.5–0.8)‰. For a 140 L sample of air, such small masses of carbon correspond to mixing ratios in the low pptV range. The developed measurement technique was applied to a small set of ambient air samples taken during hot, sunny periods from late May to early August, 2005, at Forschungszentrum Jülich, Germany, a semi-rural area. The range of δ¹³C values determined for isoprene, benzene, and toluene are consistent with those reported in the literature. GCC-IRMS results of δ¹³C for ambient samples of isoprene, MACR, and MVK, measured at mixing ratios of 15–280 pptV, are presented and discussed.  相似文献