Fast Oxidation Reaction of Nitrite by Dissolved Oxygen in the Freezing Process in the Tropospheric Aqueous Phase     

Norimichi Takenaka  Tohru Daimon  Akihiro Ueda  Keiichi Sato  Masaru Kitano  Hiroshi Bandow  Yasuaki Maeda 《Journal of Atmospheric Chemistry》1998,29(2):135-150

Nitrite oxidation in the tropospheric aqueous phase by freezing was evaluated by freezing a field sample. Nitrite oxidation by dissolved oxygen in the freezing process is much faster than by other oxidation processes, such as reactions with ozone, hydrogen peroxide or dissolved oxygen in an aqueous solution at pHs 3 to –6. At pH 4.5 and 25°C, the lifetime of nitrite in the aqueous phase is ca. 1 hr in oxidation by ozone (6×10^-10 mol dm^-3), ca. 10 hr in oxidation by H₂O₂ (2×10^-4 mol dm^-3), and 7.5 hr (Fischer and Warneck, 1996) in photodissociation at midday in summer. Under the same conditions at a temperature below 0°C, the lifetime of nitrite in the freezing process is estimated as ca. 2 sec when the droplets are frozen within a second. The reaction by freezing is affected by the presence of salts, such as NaCl or KCl, or orgnaic compounds, such as methanol or acetone. The results of freezing a field rain or fog sample showed that nitrite oxidation proceeds below pH 6, and the conversion ratio of nitrate from nitrite increases with decreasing pH. The oxidation of nitrite by freezing was also observed in freezing fog particles generated by an ultrasonic humidifier. The ratios of the concentrations of ions in the winter sample to those in the summer sample (or those in the fog sample) were almost the same values. However, the concentration of nitrite in the winter sample was lower than that estimated by the ratios of other ions. From the present study, it seems that the freezing process plays an important role in the nitrite sink process in the tropospheric aqueous phase.  相似文献   

中国东海济舟岛南部春季水华的影响要素研究     

FU Dongyang  HUANG Zhaojun  ZHANG Yuanzhi  PAN Delu  DING Youzhu  LIU Dazhao  ZHANG Ying  MAO Zhihu  CHEN Jianfang 《海洋学报(英文版)》2015,34(3):51-58

A soil circulation occurs in the south of Cheju Island in the spring. Nutrients and its influence on chlorophyll a(Chl a) around the circulations were studied from April 9 to May 6, 2007. Spring bloom with elevated concentrations of Chl a was observed during the investigation. High concentrations of phosphate, nitrate and silicate at 0.6, 12, and 8 mmol/m3, respectively, were detected. A low water temperature prevented the growth of phytoplankton. Chl a concentrations in the study area might be strongly associated with the high silicate concentration.  相似文献   

Capturing temporal variability for estimates of annual hydrochemical export from a first‐order agricultural catchment in southern Ontario,Canada     

M. L. Macrae  M. C. English  S. L. Schiff  M. Stone 《水文研究》2007,21(13):1651-1663

This 2‐year study (2000, 2001) reports annual nutrient (phosphorus, nitrate) export from a first‐order agricultural watershed in southern Ontario based on an intensive monitoring programme. The importance of storm and melt events in annual export estimates is demonstrated and the temporal variability in nutrient loading during events is related to processes occurring within the catchment. The feasibility of predicting event‐related nutrient export from hydrometric data is explored. The importance of sampling frequency throughout events is also shown. Export of total phosphorus (TP), soluble reactive phosphorus (SRP) and nitrate ( ) for 2000 and 2001 averaged 0·35 kg ha^?1 year^?1, 0·09 kg ha^?1 year^?1, and 35 kg ha^?1 year^?1 (as N) respectively. Approximately 75% of annual TP export, 80% of annual SRP export and 70% of annual export occurred during 28 events per year. A small number of large‐magnitude events (>34 mm) accounted for 18–42% of annual TP export, 0–61% of annual SRP export and 13–33% of annual NO export. Our results show that temporal variability in nutrient export is largely governed by discharge in this basin, and export can be predicted from discharge. SRP and TP export can also be predicted from discharge, but only for events that are not large in magnitude. The sampling interval throughout events is important in obtaining precise estimates of nutrient export, as infrequent sampling intervals may over‐ or under‐estimate nutrient export by ± 45% per event for P. This study improves our understanding of and P export patterns and our ability to predict or model them by relating temporal variability in event nutrient export to discharge and processes occurring within the basin, and also by exploring the significance of sampling interval in the context of the importance of individual events, season and temporal variability during events. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

沂源县田庄水库农业面源氮素淋滤行为研究   总被引：1，自引：0，他引：1  

宋辉  刘庆福 《地下水》2010,32(2):71-73

受农业面源影响,典型山区水库-田庄水库氮素超标,通过模拟土壤在不同降雨强度与不同降雨类型下的淋滤行为,探讨氮素淋溶释放规律,并对田庄水库农业面源氮素入库量进行了计算。结果表明,降雨类型和降雨强度只影响土壤中氨氮峰值浓度出现的时间,对其数值影响不大,由于土壤中硝氮含量较高,使降雨强度和类型对其淋出液中的硝氮峰值浓度产生的时间和数值都有所影响;农业面源氮污染通过田庄水库四条入库河流年均排入水库中的硝氮总量高达604．49t,氨氮为23．85t。  相似文献   

新疆东天山南缘富钾硝酸盐盐湖成矿带地质特征及资源潜力   总被引：3，自引：0，他引：3  

葛文胜  刘斌  邱斌  宋文杰  蔡克勤  付强 《矿床地质》2010,29(4):640-648

新疆东部是中国主要的盐类矿床聚集区,在东天山南缘形成了巨大的富钾硝酸盐盐湖成矿带。文章在系统总结东天山南缘富钾硝酸盐成矿带地质特征、成矿条件特征和晶间卤水特征的基础上,分析了富钾硝酸盐矿床成矿的地质条件、物质来源和气候因素,以及已有矿床的资源状况和资源潜力,指出富钾硝酸盐矿床是一种特殊类型的盐类矿床,特殊的构造条件是该类矿床物质来源和成矿作用发生的重要因素,晶间卤水和层间、裂隙卤水具有较大的资源潜力。加强该区富钾硝酸盐矿床的研究和勘查评价工作,不仅可以丰富中国陆相盐类矿床成盐理论,而且可以为罗布泊钾盐基地提供后续资源保障,同时也有利于新疆新型钾、氮肥工业基地的建立。  相似文献   

钠土泥浆在构造破碎带型复杂地层钻进中的应用          下载免费PDF全文

廖远苏  廖长生  卓廉明  胡啟锋 《探矿工程》2010,37(8):5-9

应用钠土泥浆,解决了锡坑矿区复杂地层钻进中运用其它措施难以解决的塌、漏、掉等问题,保证了后续施工的钻孔质量,提高了钻进效率和经济效益。通过钠土泥浆与钙土泥浆及其它无固相冲洗液类比分析,得出了钠土泥浆在该矿区取得好成效的机理。针对赣南构造破碎带型复杂地层钻进中存在的问题,借鉴锡坑矿区的成功经验,提出应重视对钠土泥浆的研究和应用的建议。  相似文献   

利用氮氧同位素研究桂林寨底地下河硝酸盐来源   总被引：3，自引：0，他引：3  

王松  裴建国  梁建宏 《地质灾害与环境保护》2010,21(4):54-56,81

工农业生产的迅速发展使地下水硝酸盐氮(NO3-—N)污染成为世界性的环境问题。地下水中硝酸盐的来源研究在水文地质结构特殊的西南岩溶地区就显得尤为重要。稳定氮同位素和氧同位素在地下水硝酸盐的来源示踪研究中有着广泛的应用。本研究选取岩溶地区典型地下河——广西桂林寨底地下河为研究对象,通过氮氧同位素数据,判断寨底地下河硝酸盐来源是以动物粪便为主的农家肥,为该区地下水的保护和利用提供科学依据。  相似文献   

青海地区盐渍土分布规律及其独特工程特性探讨     

罗友弟 《岩土工程技术》2010,24(2):75-78,83

针对青海一些地区盐渍土当硫酸钠含量小于1%时也会产生盐胀,而超氯盐渍土却不会产生溶陷的事实,进行了较为深入细致的论证和研究。以数据、事实为依据,得出了与现行理论及规范有较大出入的论断。  相似文献   

Measurement of trace nitrate concentrations in seawater by ion chromatography with valve switching     

杜娟  法芸  郑岳  李学兵  杜芳林  杨海燕 《中国海洋湖沼学报》2014,32(3):732-736

An ion chromatographic method with a valve switching facility was developed to determine trace nitrate concentrations in seawater using two pumps, two different suppressors, and two columns. A carbohydrate membrane desalter was used to reduce the high concentrations of sodium salts in samples. In this method, trace nitrate was eluted from the concentrator column to the analytical columns, while the matrix flowed to waste. Neither chemical pre-treatment nor sample dilution was required. In the optimized separation conditions, the method showed good linearity （R〉0,99） in the 0.05 and 50 mg/L concentration range, and satisfactory repeatability （RSD〈5%, n=6）. The limit of detection for nitrate was 0.02 mg/L. Results showed that the valve switching system was suitable and practical for the determination of trace nitrate in seawater.  相似文献   

Controls on surface water chemistry in two lake‐watersheds in the Adirondack region of New York: differences in nitrogen solute sources and sinks     

Mari Ito  Myron J. Mitchell  Charles T. Driscoll  Robert M. Newton  Chris E. Johnson  Karen M. Roy 《水文研究》2007,21(10):1249-1264

The southwestern Adirondack region of New York receives among the highest rates of atmospheric nitrogen (N) deposition in the USA. Atmospheric N deposition to sensitive ecosystems, like the Adirondacks, may increase the acidification of soils through losses of exchangeable nutrient cations, and the acidification of surface waters associated with enhanced mobility of nitrate (NO₃^?). However, watershed attributes, including surficial terrestrial characteristics, in‐lake processing, and geological settings, have been found to complicate the relationships between atmospheric N deposition and N drainage losses. We studied two lake‐watersheds in the southwestern Adirondacks, Grass Pond and Constable Pond, which are located in close proximity (～26 km) and receive similarly high N deposition, but have contrasting watershed attributes (e.g. wetland area, geological settings). Since the difference in the influence of N deposition was minimal, we were able to examine both within‐ and between‐watershed influences of land cover, the contribution of glacial till groundwater inputs, and in‐lake processes on surface water chemistry with particular emphasis on N solutes and dissolved organic carbon (DOC). Monthly samples at seven inlets and one outlet of each lake were collected from May to October in 1999 and 2000. The concentrations of NO₃^? were high at the Grass Pond inlets, especially at two inlets, and NO₃^? was the major N solute at the Grass Pond inlets. The concentrations of likely weathering products (i.e. dissolved Si, Ca²⁺, Mg²⁺, Na⁺) as well as acid neutralizing capacity and pH values, were also particularly high at those two Grass Pond inlets, suggesting a large contribution of groundwater inputs. Dissolved organic N (DON) was the major N solute at the Constable Pond inlets. The higher concentrations of DON and DOC at the Constable Pond inlets were attributed to a large wetland area in the watershed. The DOC/DON ratios were also higher at the Constable Pond inlets, possibly due to a larger proportion of coniferous forest area. Although DON and DOC were strongly related, the stronger relationship of the proportion of wetland area with DOC suggests that additional factors regulate DON. The aggregated representation of watershed physical features (i.e. elevation, watershed area, mean topographic index, hypsometric‐analysis index) was not clearly related to the lake N and DOC chemistry. Despite distinctive differences in inlet N chemistry, NO₃^? and DON concentrations at the outlets of the two lakes were similar. The lower DOC/DON ratios at the lake outlets and at the inlets having upstream ponds suggest the importance of N processing and organic N sources within the lakes. Although an inverse relationship between NO₃^? and DOC/DON has been suggested to be indicative of a N deposition gradient, the existence of this relationship for sites that receive similar atmospheric N deposition suggest that the relationship between NO₃^? and the DOC/DON ratio is derived from environmental and physical factors. Our results suggest that, despite similar wet N deposition at the two watershed sites, N solutes entering lakes were strongly affected by hydrology associated with groundwater contribution and the presence of wetlands, whereas N solutes leaving lakes were strongly influenced by in‐lake processing. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献