The elastic properties of single-crystal fayalite as determined by dynamical measurement techniques     

Donald G. Isaak  Earl K. Graham  Jay D. Bass  Hong Wang 《Pure and Applied Geophysics》1993,141(2-4):393-414

We present new elasticity measurements on single-crystal fayalite and combine our results with other data from resonance, pulse superposition interferometry, and Brillouin scattering to provide a set of recommended values for the adiabatic elastic moduliC _ij and their temperature variations. We use a resonance method (RPR) with specimens that were previously investigated by pulse superposition experiments. The nineC _ij of fayalite are determined from three new sets of measurements. One set of our newC _ij data is over the range 300–500 K. We believe that the relatively large discrep ncies found in someC _ij are due in large part to specimen inhomogeneities (chemical and microstructural) coupled with differences in the way various techniques sample, rather than only systematic errors associated with experimental procedures or in the preparations of the specimens.Our recommendeaC _ij's (GPa) and (C _ij/T) _p (GPa/K) are: The resulting values for the isotropic bulk and shear moduli,K _s and , and their temperature derivatives are:K _s=134(4) GPa; =50.7(0.3) GPa; (K _s/T) _p =–0.024(0.005) GPa/K; and (/T) _p =–0.013(0.001) GPa/K. An important conclusion is thatK _s increases as the Fe/(Fe+Mg) ratio in olivine is increased.  相似文献   

The “Zero-order Model” revisited: Paul Schindler's influence on the development of trace metal scavenging models     

Santschi  Peter H.  Honeyman  Bruce D.  Quigley  Matthew S. 《Aquatic Sciences - Research Across Boundaries》1993,55(4):230-239

In 1975 Paul Schindler produced the first oceanic trace metal scavenging model to explicitly include the role of surface chemistry as a control on trace metal water column residence times. The eighteen years that have elapsed since the publication of Schindler's seminal paper have seen the development of a variety of oceanic scavenging models; yet, the fundamental insight of his Zero-order Model remains the benchmark. This paper describes the role of Paul Schindler's work on surface chemistry in providing a framework for the current generation of trace element scavenging models.  相似文献   

Kinetics of redox cycling of iron coupled with fulvic acid     

Yiwei Deng  Werner Stumm 《Aquatic Sciences - Research Across Boundaries》1993,55(2):103-111

The kinetics of conversion of iron(III) (hydr)oxides to ferrous iron mediated by fulvic acid have been investigated in order to improve the understanding of the redox cycling of iron at the oxic-anoxic boundary in natural waters. Under the conditions similar to natural waters, fulvic acid is able to reduce the iron(III) (hydr)oxide. The kinetics of the reaction depend on the reactivity of iron(III) (hydr)oxides and the reducing power of the fulvic acid. The rate of reaction is 60 nm/h obtained under following conditions: total concentration of Fe(III) 1.0 × 10^–4 M, pH 7.5, fulvic acid 5 mg/L. The rate is considered as a net result of reduction and oxidation in the > Fe^III-OH/Fe(II) wheel coupled with fulvic acid. In a real natural water system, reductants other than fulvic acid may be of importance. The results obtained in the laboratory, however, provide evidence that the Fe(OH)₃(s)/Fe(II) redox couple is able to act as an electron-transfer mediator for the oxidation of natural organic substances, such as fulvic acid by molecular oxygen either in the absence of microorganisms or as a supplement to microbial activity.  相似文献   

Brønsted reactions on oxide mineral surfaces and the temperature-dependence of their dissolution rates     

William H. Casey  Marcus A. Cheney 《Aquatic Sciences - Research Across Boundaries》1993,55(4):304-313

The pH-dependence of oxide dissolution rates is controlled by Brønsted acid-base reactions at the mineral surface. These reactions are rapid but depend explicitly on temperature, as do the subsequent slow rates of bond hydrolysis. The net result is that dissolution rates vary in a complicated fashion with temperature and solution pH. The enthalpy changes of acid-base reactions on oxide materials are sufficiently similar, however, that general statements can be made about their contribution. The enthalpy changes from proton adsorption to a hydroxyl functional group (SOH), or to a deprotonated functional group (SO ^–), are generally exothermic. The enthalpy changes become increasingly endothermic, however, as charge accumulates on the mineral surface and the charged species interact electrostatically. The result is that mineral dissolution rates are least sensitive to temperature, as measured with an Arrhenius-like rate law, at pH conditions near the Point of Zero Net Proton Charge.  相似文献   

Asteroid motion near the 3 : 1 resonance     

John D. Hadjidemetriou 《Celestial Mechanics and Dynamical Astronomy》1993,56(4):563-599

A mapping model is constructed to describe asteroid motion near the 3 : 1 mean motion resonance with Jupiter, in the plane. The topology of the phase space of this mapping coincides with that of the real system, which is considered to be the elliptic restricted three body problem with the Sun and Jupiter as primaries. This model is valid for all values of the eccentricity. This is achieved by the introduction of a correcting term to the averaged Hamiltonian which is valid for small values of the ecentricity.We start with a two dimensional mapping which represents the circular restricted three body problem. This provides the basic framework for the complete model, but cannot explain the generation of a gap in the distribution of the asteroids at this resonance. The next approximation is a four dimensional mapping, corresponding to the elliptic restricted problem. It is found that chaotic regions exist near the 3 : 1 resonance, due to the interaction between the two degrees of freedom, for initial conditions close to a critical curve of the circular model. As a consequence of the chaotic motion, the eccentricity of the asteroid jumps to high values and close encounters with Mars and even Earth may occur, thus generating a gap. It is found that the generation of chaos depends also on the phase (i.e. the angles andv) and as a consequence, there exist islands of ordered motion inside the sea of chaotic motion near the 3 : 1 resonance. Thus, the model of the elliptic restricted three body problem cannot explain completely the generation of a gap, although the density in the distribution of the asteroids will be much less than far from the resonance. Finally, we take into account the effect of the gravitational attraction of Saturn on Jupiter's orbit, and in particular the variation of the eccentricity and the argument of perihelion. This generates a mixing of the phases and as a consequence the whole phase space near the 3 : 1 resonance becomes chaotic. This chaotic zone is in good agreement with the observations.  相似文献   

Interpolation by regularized spline with tension: I. Theory and implementation   总被引：3，自引：0，他引：3  

Helena Mitáová  Lubos Mitá 《Mathematical Geology》1993,25(6):641-655

Bivariate and trivariate functions for interpolation from scattered data are derived. They are constructed by explicit minimization of a general smoothness functional, and they include a tension parameter that controls the character of the interpolation function (e.g., for bivariate case the surface can be tuned from a membrane to a thin steel plate), Tension can be applied also in a chosen direction, for modeling of phenomena with a simple type of anisotropy. The functions have regular derivatives of all orders everywhere. This makes them suitable for analysis of surface geometry and for direct application in models where derivatives are necessary. For processing of large datasets (thousands of data points), which are now common in geosciences, a segmentation algorithm with a flexible size of overlapping neighborhood is presented. Simple examples demonstrating flexibility and accuracy of the functions are presented.On leave from the Department of Physical Geography and Cartography, Comenius University, Mlynská dolina, Bratislava, Czechoslovakia.On leave from the Institute of Physics, Dúbravská cesta 9, Bratislava, Czechoslovakia.  相似文献   

EAR70、CLDAS和ERA Interim表层土壤温度在中国地区的评估     

单帅  师春香  沈润平  白磊 《气象科技》2021,49(6):830-837

本文利用2010—2015年2400多国家气象站逐小时观测数据对覆盖中国的EAR70、CLDAS和ERA Interim 3种表层土壤温度进行了评估和对比。结果表明：空间上CLDAS表层土壤温度精度最高（平均误差为-0.5 ℃，均方根误差为3.0 ℃，相关系数为0.96），受益于CLDAS高精度的陆面初始场，EAR70平均误差得到了改善；时间上ERA Interim再分析表层土壤温度在6:00和夏、秋季精度会明显下降，再分析表层土壤温度在数值较高时段表现出冷偏差，原因是模拟的土壤温度数值上升速度慢，对应的参数化方案有待改进。再分析表层土壤温度在东北地区冬季存在冷偏差，可能和积雪覆盖有关，陆面参数化方案也有待提高。在地形复杂的青藏高原地区，融合地面观测的CLDAS提高了大气驱动的质量进而改进了土壤的模拟。ERA Interim分辨率较粗不适合在青藏高原或者沿海地区使用，结合了CLDAS的EAR70在青藏高原精度提高。土壤表层温度的精度随着高精度的土壤状态初始场进入模式中时间延长会显著下降。因此，CLDAS的实时同化方式，能够有效提高在分析数据的精度。  相似文献   

Multi-level dissipation element analysis of the surface temperature of the South China Sea     

《Dynamics of Atmospheres and Oceans》2021

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Impact cratering - a review,with special reference to the economic importance of impact structures and the Southern African impact crater record     

W. U. Reimold 《Earth, Moon, and Planets》1995,70(1-3):21-45

Only since several decades has impact cratering been recognized as an important surface process on all planetary bodies in the Solar System. However, as the process has not yet been effectively introduced into geological curricula, it is necessary to inform a wider public about its importance for (i) planetary formation and (ii) evolution, (iii) the understanding of this process as a geological process, (iv) the terrestrial impact crater record and its limitations, and (v) the recognition criteria for terrestrial impact structures, as well as (vi) the need of improvement of the impact cratering record in the light of the potential danger of an impact catastrophe on this planet. It is, particularly for developing countries, of interest to examine the economic and educational-environmental potential of impact structures. That it is possible to carry out an effective, low-budget geological investigation of impact structures within a Second World environment is demonstrated by the discussion of the progress that has been made in recent years with regard to the Southern African impact crater record. Several recommendations on how to improve, on the one hand, the terrestrial impact crater record and, on the other, their general working situation by activation of workers in Developing Countries are discussed.  相似文献   

The gawler ranges,South Australia: an unusual volcanic massif     

E. M. Campbell  C. R. Twidale 《The Australian geographer》1991,22(1):24-33

The volcanic residuals of the Gawler Ranges together form an extensive massif that in its gross morphology differs markedly from most exposures of silicic volcanic rocks. The upland developed in two stages, the first involving differential fracture‐controlled subsurface weathering, the second the stripping of the regolith. As a result, an irregular weathering front was exposed, with domical projections prominent. These bornhardts are etch forms, and they are of considerable antiquity.

The differential weathering of the rock mass reflects the exploitation of various fracture systems by shallow groundwaters. Orthogonal fracture systems at various scales, sheet fractures and columnar joints control the morphology of the bornhardts in gross and in detail.

The exploitation of the structural base, which was established in the Middle Protero‐zoic, probably took place throughout the Late Proterozoic and the Palaeozoic, though only minor remnants of the Proterozoic land surface remain. The major landscape features developed during the Mesozoic. The weathering which initiated the bornhardts occurred in the Jurassic or earlier Mesozoic, and the landforms were exposed in Late Cretaceous to Early Tertiary times.

Though structural forms dominate the present landscape, some major and some minor landforms are best explained in terms of climatic changes of the later Cainozoic. The palaeodrainage system, established under humid conditions by the Early Tertiary, was alluviated during the Cainozoic arid phases, and salinas were formed. The sand dunes of the region also reflect this aridity.  相似文献