黄铁矿对有机质成烃的催化作用讨论   总被引：22，自引：0，他引：22  

张景廉  张平中 《地球科学进展》1996,11(3):282-287

粘土矿物，碳酸盐，石英等无机矿物对有机质演化的催化作用已被确认，有机质干酪根类型还与黄铁矿含量，形态有关，而其中硫的含量直接影响到干酪根反应的活化能，反应速率，指出黄铁矿也是一种有效的催化剂。鉴于世界原油中有很大一部分产自高硫酪根，深入研究其中的机理是当前石油地球化学中的一项刻不容缓的任务。  相似文献   

东营凹陷民丰地区天然气生成机理与化学动力学研究   总被引：3，自引：0，他引：3  

王秀红  金强  胡晓庆  陈涛  宋国奇  王力  王娟  林腊梅  陈志伟 《沉积学报》2008,26(3):525-530

民丰地区天然气存在源岩热解和原油裂解成因的争议。本文采用高压釜封闭体系对该区烃源岩和原油样品分别进行了热模拟实验,从烃类气体生成过程、气态烃与部分单体烃生成动力学特征讨论了二者的生气机理,认为原油裂解比源岩热解生气活化能高30～40 kJ/mol,原油比源岩生气需要更高的热力学条件。模拟实验证实,成熟阶段源岩热解气与原油裂解气相比,以环烷烃和芳烃相对含量低为特征,与民丰地区产出的天然气组成更接近,据此认为该区天然气主要为源岩热解成因。  相似文献   

Looking for a White Male Effect in Generation Z: Race,Gender, and Political Effects on Environmental Concern and Ambivalence     

J. Tom Mueller  Lauren E. Mullenbach 《社会与自然资源》2018,31(8):925-941

The “White male effect” has been presented in past literature as a way to explain the tendency for White males to have lower environmental concern and risk perceptions than female and non-White individuals. Recently, research has proposed the “White male effect” may be a “conservative White male effect,” due to findings that political ideology impacts environmental concern. This study used a sample of young college-educated adults from Generation Z to test whether the conservative White male effect is present for environmental concern and ambivalence toward a proenvironmental worldview in this younger generation. Online surveys were distributed to undergraduate students at a large northeastern university in spring of 2016. A total of 1,940 surveys were returned. Results showed a lack of a unique White male, or conservative White male, effect above and beyond differences explained by gender, Whiteness, and political affiliation. The implications of this effect’s absence are discussed.  相似文献   

基于鲁棒自适应策略的燃气轮机系统控制器设计     

谭雪琴  苏晓杰 《南京气象学院学报》2018,10(2):166-172

太阳能、风能和潮汐能等可再生能源的发电系统,具有间歇性发电的特性.因此,具有快速响应、发电效率高的燃气轮机发电系统,能够在可再生能源发电间歇出现时充当替代系统,不仅稳固电网的负荷能力,还有助于推动可再生能源的发展.由于燃气轮机是一个模型包含未知的复杂非线性系统,目前针对转速环节主要采取传统PID控制技术.然而,实际运行中系统工况发生变化时,控制器参数不能随着这些变化做出相应的调整,使得控制效果欠佳,执行器故障的出现也可能导致系统无法正常工作.因而,本文针对单轴燃气轮机的孤岛发电模式,结合燃气轮机系统特性,基于反步法的设计思路,引入不依赖于系统模型的鲁棒自适应控制策略,并加入容错控制和Nussbaum函数构造转速控制器.在控制器设计过程中融合动态面方法,解决高阶系统中反步法引起的计算爆炸问题.最后,通过仿真,验证了控制器的可靠性.  相似文献   

新一代天气雷达布网设计的有效覆盖和地形遮挡分析   总被引：4，自引：3，他引：1  

朱丹  谷军霞  师春香  周自江 《气象》2018,44(11):1434-1444

一般情况下,地形影响造成的雷达波束遮挡是长期保持不变的。研究雷达地形遮挡情况有助于提升雷达探测资料的有效性和可靠性。利用先进星载热发射和反射辐射仪全球数字高程模型地形数据,对我国已建成的208个新一代天气雷达站点进行地形遮挡分析,计算业务体扫模式(Volume Coverage Pattern modes, VCP)21的九个仰角下200 km范围内雷达反射率的波束阻挡系数,绘制观测仰角分别为0.5°、1. 45°、2. 4°和3. 35°时雷达有效观测区域的覆盖图,计算相应的有效覆盖面积。结果表明全国新一代天气雷达站200 km范围内0. 5°、1. 45°、2. 4°和3. 35°仰角平均遮挡比例分别为30. 7%、8. 5%、2. 5%和1.0%,平均有效覆盖面积分别为83210.5、109354.2、118170.9、121631.5 km~2,只有少数几个雷达站受邻近山脉地形遮挡影响严重,雷达站总体有效覆盖情况较好。  相似文献   

应用NASA MERRA再分析资料对一次高原切变线的诊断分析   总被引：1，自引：1，他引：0  

陈佳  李国平 《气象科学》2018,38(3):320-330

利用2016年6月29—30日地面及高空常规观测资料、CMORPH融合降水资料以及时空分辨率较高的NASA MERRA 0.625°×0.5°逐3 h再分析资料,对一次高原切变线过程进行了天气动力学诊断分析。运用广义位温、广义湿位涡和涡生参数等诊断量对切变线系统的生成及其降水分布进行分析。结果显示:广义位温等值线梯度大值区与大气水汽的聚集区相对应。切变线降水的发生、发展与广义湿位涡的分布及演变有较好的对应关系,低层大气广义湿位涡的正异常大值对降水发生有一定关联。广义湿位涡正负异常值之间的零线可较好表征高原切变线的位置。广义湿位涡中心强度对切变线生成与发展有一定指示意义。涡生参数可作为高原切变线生成和加强的一个明显前兆信号。  相似文献   

CINRAD/SA(B)发射机激励放大器芯片级故障诊断流程     

潘新民  白水成  崔炳俭 《气象与环境科学》2017,40(3):119-124

激励放大器是发射机射频放大链电路前级功率放大器,对雷达探测资料可靠性具有重要作用。研究芯片级故障诊断流程,一方面可以解决台站技术保障人员无法故障定位到芯片级的技术难题;另一方面,芯片级故障维修可达到大大降低维修成本的目的。雷达故障一般分为参数调整不当导致性能下降故障和器件损坏造成参数异常故障。为此,通过总结出CINRAD/SA(B)发射机激励放大器信号流程、故障树图集,在依据同步信号时序关系及关键点波形参数基础上,研究出规范化的激励放大器调试技术和方法,以及激励放大器芯片级故障诊断定位流程,并列举了依据激励放大器芯片级故障诊断定位流程,修复激励放大器集成块N8损坏,导致+8 V电源不正常,造成激励放大器无功率输出,以及激励放大器的第二级功放模块故障导致激励放大器输出功率低的两个故障的典型个例,以检验维修效果。实际应用结果表明:芯片级激励放大器故障诊断定位流程可以快速定位发射机激励放大器故障点到故障器件,方法简洁、思路清晰、操作规范,基层雷达站技术人员容易掌握;激励放大器调试技术和方法,能解决激励放大器参数调整不当导致激励放大器性能下降故障,可有效提高新一代天气雷达技术保障水平。  相似文献   

关于地理空间元数据技术发展趋势的理论探讨   总被引：2，自引：2，他引：0  

周新忠  余木良  陶亮  郭朋飞 《测绘科学》2007,32(2):172-175

随着“数字地球”、“数字中国”等的实施,地理空间元数据作为促进海量空间信息管理和共享的有力工具,其应用有了较快的发展。本文在分析我国地理空间元数据应用现状的基础上,结合地理空间元数据的应用特点,分析了地理空间元数据的标准化、互操作、自动生成等趋势是地理空间元数据发展的必然,并论述了与这些发展趋势相关的实施方法和技术,以及这些趋势之间的辩证关系。  相似文献   

Burial,Maturation, and Petroleum Generation History of the Arkoma Basin and Ouachita Foldbelt,Oklahoma and Arkansas     

Byrnes  Alan P.  Lawyer  Gary 《Natural Resources Research》1999,8(1):3-26

Removed overburden, burial, maturation, and petroleum generation analysis indicates that maturity in the Arkoma Basin and the Ouachita Foldbelt is explained effectively using simple burial models that account for the significant surface erosion that has occurred and assuming geothermal gradients similar to present-day gradients have been approximately constant through geologic time. Regional models, based on analysis at 115 well locations, indicate that from 5,000 to 15,000 ft (1.5–4.5 km) of section, differing with location from north to south and west to east, has been removed from the Arkoma Basin region, and as much as 25,000–40,000 ft (7.5–12 km) have been removed from areas of the Ouachita Foldbelt. Based on burial and thermal history reconstruction, increasing maturation from west to east across the basin is primarily the result of increasing overburden and subsequent surface erosion from west to east. The models predict most publicly available vitrinite reflectance data within a factor of 1.5 at two standard deviations. Comparison of model and measured reflectance-depth trends in six wells indicates that hydrothermal fluid movement should not have modified reflectance by more than approximately 20% in the center of the basin. Analysis indicates that most of the basin is overmature for oil production from intervals below the Spiro Sandstone, except to the north and northwest. Although thermal maturities are high, methane is stable throughout the basin. Except for the basal Arbuckle Group, all formations were thermally immature for oil generation prior to burial by the Mississippian and Morrowan in the Ouachita Foldbelt of Oklahoma and by the Atokan and Desmoinesian over most of the basin and study area. In the deeper part of the present basin, all strata entered and passed through the oil window during or within 10 My after Atokan time. Because no additional major quantities of hydrocarbons were generated after Atokan time, the hydrocarbons must have been emplaced and trapped during this brief time interval.  相似文献   

Seismic imaging of the axial region of the Valu Fa Ridge, Lau Basin—the accretionary processes of an intermediate back-arc spreading ridge     

Ian M. Turner  Christine Peirce  & Martin C. Sinha 《Geophysical Journal International》1999,138(2):495-519

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