元素活动态提取条件和分析方法的应用研究   总被引：1，自引：0，他引：1  

徐进力  邢夏  张鹏鹏  胡梦颖  白金峰  张勤  王学求 《地质学报》2020,94(3):982-990

元素活动态分析作为深穿透地球化学的新方法,得到了广泛的应用。实验对水提取态、黏土吸附态、有机结合态和铁锰氧化物结合态四种元素活动态的提取条件进行了系统研究,分别考察了提取时间、液固比、离心转速、提取液放置时间对提取效果的影响,确定了元素活动态的最佳提取条件:提取时间为24h,液固比为10:1,离心转速4000rpm;提取液采用新型的高分辨率等离子体质谱法(HR-ICP-MS)测定,该仪器具有强大的动态线性范围(10-12~1012)和高灵敏度,使可同时测定的元素拓展至50余种,可以大大提高工作效率。对HR-ICPMS的主要工作条件:辅助气流量、样品气流量和采样深度等利用响应面法进行了优化。本法将传统的过滤法改为离心法,避免了滤纸或穿滤引入的误差;将新型的高分辨率等离子体质谱法(HR-ICP-MS)应用到提取液的测定,提升了多元素同时分析能力,大大提高工作效率,同时也降低了该方法的检出限,改善了测定结果的精密度。依据实验结果,建立了HR-ICP-MS对四种元素活动态的分析方法,分别得到了四种活动态中各元素的方法检出限和方法精密度,水提取态、黏土吸附态、有机结合态和铁锰氧化物结合态中各元素的精密度范围依次为3.4%~38.1%、3.78%~35.7%、2.41%~35.9%、2.26%~32.5%;通过顺序提取,将四个相态中提取到的元素量和残渣中残留进行加和,得到50个元素的加和结果,验证了该方法的准确度(RE)为-29%^-1.3%,满足当前元素活动态的分析测试需求。  相似文献   

宁静期间双峰电流片的观测研究          下载免费PDF全文

汤朝灵  路立  李中元 《地球物理学报》2007,50(4):979-985

2001年8月19日2011～2030UT,AE指数相对较小(40～130 nT),Cluster 卫星穿越磁尾电流片.利用Cluster 观测资料分析,发现宁静期间有双峰电流片存在,这期间没有明显的高速流,没有明显的电流片振荡. 同时,进一步分析双峰电流片中的离子特性发现:质子数密度Np在中性线（<Bx> = 0）附近相对较大,呈非对称性分布;质子温度分布比较均匀;在中性线两侧,质子y方向上的流速Vy方向相反. 最后讨论LHDI（低混杂漂移不稳定性）的非线性演化可能是形成宁静期间双峰电流片的主要机制. 这些对进一步完善电流片形成机制可能有很重要的意义.  相似文献   

Identification of low frequency waves in the vicinity of the terrestrial bow shock     

M.A. BalikhinO.A. Pokhotelov  S.N. Walker  M. Andre 《Planetary and Space Science》2003,51(11):693-702

In this paper, methods for the determination of the wave mode for low frequency waves based on observed differences in phase are reviewed. Examples, using measurements made in the terrestrial foreshock and magnetosheath, are used to illustrate the application of these methods. The use of advance methods such as NARMAX modelling or genetic algorithms to identify the plasma wave mode is also discussed.  相似文献   

Double-Pulse Laser-Driven Jets on OMEGA     

S. Sublett  J. P. Knauer  I. V. Igumenshchev  A. Frank  D. D. Meyerhofer 《Astrophysics and Space Science》2007,307(1-3):47-50

A double-pulse laser drive is used to create episodic supersonic plasma jets that propagate into a low density ambient medium. These are among the first laser experiments to generate pulsed outflow. The temporal laser-intensity profile consists of two 1-ns square pulses separated by 9.6 ns. The laser is focused on a truncated conical plug made of medium Z material inserted into a high-Z washer. Unloading material from the plug is collimated within the cylindrical washer hole, then propagates into the low-Z foam medium. The resulting jet is denser than the ambient medium. Double-pulse jet evolution is compared to that driven by a single laser pulse. The total drive energy is the same for both jets, as if a source with fixed energy generated a jet from either one or two bursts. Radiographs taken at 100 ns show that a single-pulse jet was broader than the double-pulse jet, as predicted by hydrodynamic simulations. Since the initial shock creating the jet is stronger when all the energy arrives in a single pulse, the jet material impacts the ambient medium with higher initial velocity. Detailed comparisons between single- and double-pulsed jet rheology and shock structure are presented. 2-D hydrodynamic simulations are compared to the experimental radiographs. PACS: 52.30.−q 41.75.Jv 42.62.−b 42.68.Sq 47.40.−x 47.56.+r  相似文献   

ICP—光量计测定地质样品中的Sc     

宁军  张立行  陈虹 《国土资源》1997,(3)

本方法是用ＩＣＰ—光量计测定地质样品中的Ｓｃ，用氢氟酸—盐酸溶解样品，对几个国家级标样进行测定，结果与推荐值一致。方法检出限为Ｓｃ：０．２２μｇ／ｇ，本方法简单、快速、准确  相似文献   

Electrostatic dust-cyclotron waves in plasmas with opposite polarity grains     

N. D'Angelo 《Planetary and Space Science》2002,50(4):375-378

The dispersion relation is derived for electrostatic dust-cyclotron (EDC) waves in a collisional plasma with dust grains having both positive and negative charges. The critical electric fields for excitation of two EDC modes in such a plasma are numerically calculated for a laboratory-type plasma.  相似文献   

密云综合孔径射电望远镜的干扰抑制(英文)     

杨以培  郑怡嘉  张喜镇  陈宏升  武肖涛  彭勃 《中国天文和天体物理学报》1991,(1)

MSRT(密云综合孔径望远镜)从1985年起投入工作。在多年的观测中经常发现来自外部的强大干扰,严重影响着成图的质量。为了抑制观测过程中出现的各类干扰,我们发展了两种软件技术——剔除法和频域滤波法。滤波法的优点在于保留了全部观测信息,适合于长时间强干扰的情形。剔除法对脉冲形的干扰更为敏感有效。这两种技术的配合使用能有效、灵活地抑制各种不同干扰的影响。  相似文献   

Astrophysically Useful Parameters for Some Vibronic Transitions of AlH and BH     

B. Karthikeyan  V. Raja  N. Rajamanickam  S. P. Bagare 《Astrophysics and Space Science》2006,306(4):231-234

For molecular identification in astrophysical sources, an astrophysicist needs some spectroscopic parameters such as dissociation energy, vibrational or rotational temperature of the source, band or line wavelengths, transition probability parameters, etc. The Franck-Condon(FC) factors are proportional to the transition probabilities. In this study, the FC factors and r-centroids for the vibronic (vibration-electronic) transitions C ¹ Σ ⁺ → X ¹ Σ ⁺ of aluminium hydride (AlH), b ³ Σ ^{( −)} → a ³ Π, C ¹ Σ ⁺ → A ¹ Π & C ^′1 Δ → Δ ¹ Π of boron hydride (BH) have been evaluated and the results are presented in tables which include band origin/head wavelengths. The physical & astrophysical significances of our evaluated FC factors & r-centroids have been discussed and the possible presence of AlH in sunspot umbral spectra is also predicted. PACS: 33 · 70 · Ca  相似文献   

Observational limits on intergalactic matter     

Bogdan Wszolek 《Astrophysics and Space Science》1995,227(1-2):151-155

Intergalactic gas and dust are very difficult to detect. Several methods to detect intergalactic gas have been developed. The results of these methods have provided qualitative arguments and quantitative limits on the amount of intergalactic matter in the intergalactic environment. We present here arguments as to why the density of intergalactic matter is higher than previously thought possible.  相似文献   

Bounding greybody and deflection angle of improved Schwarzschild black hole     

《New Astronomy》2022

In this paper, we study the weak deflection angle in the spacetime of improved Schwarzschild black hole using the method derived by Gibbons and Werner. To do so, we derive the optical curvature from the optical metric and calculate deflection angle in weak field limits by using the Gauss–Bonnet theorem. Moreover, we study the effect of the plasma medium on the weak gravitational lensing using the Gauss–Bonnet theorem. Furthermore, we also study the graphical analysis of the deflection angle in both the plasma and non-plasma mediums. Moreover, we obtain the bound on greybody for improved Schwarzschild black hole.  相似文献