Formation of radical species in photolyzed CH₄:N₂ ices     

Robert Hodyss  Heather R. Howard  Jay D. Goguen 《Icarus》2011,214(2):748-753

We report photochemical studies of thin cryogenic ice films composed of N₂, CH₄ and CO in ratios analogous to those on the surfaces of Neptune’s largest satellite, Triton, and on Pluto. Experiments were performed using a hydrogen discharge lamp, which provides an intense source of ultraviolet light to simulate the sunlight-induced photochemistry on these icy bodies. Characterization via infrared spectroscopy showed that C₂H₆ and C₂H₂, and HCO are formed by the dissociation of CH₄ into H, CH₂ and CH₃ and the subsequent reaction of these radicals within the ice. Other radical species, such as C₂, , CN, and CNN, are observed in the visible and ultraviolet regions of the spectrum. These species imply a rich chemistry based on formation of radicals from methane and their subsequent reaction with the N₂ matrix. We discuss the implications of the formation of these radicals for the chemical evolution of Triton and Pluto. Ultimately, this work suggests that , CN, HCO, and CNN may be found in significant quantities on the surfaces of Triton and Pluto and that new observations of these objects in the appropriate wavelength regions are warranted.  相似文献   

0917号台风“芭玛”折向东南向移动原因分析     

魏新  王力群  李海宁 《海洋预报》2012,29(1):6-12

利用NCEP全球数据同化系统(GDAS)1°×1°分析资料,对0917号台风"芭玛"折向东南向移动原因进行了分析。结果表明,中高纬度环流调整是"芭玛"折向东南向移动的根本原因;0918号台风"茉莉"通过改变外围环境场的强度、形状对"芭玛"台风产生间接影响,而两台风之间逆时针互旋以及台风"茉莉"外围强大的环流对台风"芭玛"的直接作用是台风"芭玛"折向东南向移动的关键。对台风"芭玛"经纬向UV最大风速变化诊断分析表明,"芭玛"经纬向UV最大风速中心的转移对"芭玛"折向东南向移动有重要影响,经纬向UV最大风速差的变化对"芭玛"转向具有预示作用,经纬向最大风速差的合成风方向与台风中心未来移动方向有一定的关系。  相似文献   

Application of Advanced Oxidation Processes for Polycyclic Aromatic Hydrocarbons Removal from Municipal Treatment Sludge          下载免费PDF全文

Gizem Karaca  Yücel Tasdemir 《洁净——土壤、空气、水》2015,43(2):191-196

  相似文献   

Photoinduced Reductive Decomposition of Perflurooctanoic Acid in Water: Effect of Temperature and Ionic Strength          下载免费PDF全文

Chaojie Zhang  Yan Qu  Xiaoyun Zhao  Qi Zhou 《洁净——土壤、空气、水》2015,43(2):223-228

  相似文献   

Characterization of Dissolved Organic Matter in Lake Baiyangdian Using Spectroscopic Techniques and Multivariate Statistical Analysis          下载免费PDF全文

Jun Cui  Dong‐hai Yuan  Xu‐jing Guo  Lian‐sheng He  Jiang‐wei He  Hai‐yan Li  Jun‐qi Li 《洁净——土壤、空气、水》2016,44(11):1444-1452

  相似文献   

Assessment of Erythemal UV Level in Nepal Based on Solar UV Estimates from Total Ozone Mapping Spectrometer     

Binod Kumar BHATTARAI  Berit KJELDSTAD  Trond Morten THORSETH 《大气科学进展》2011,28(4):789-796

Nepal lies on the southern slope of Himalaya in Asia. In a width ranging between 150 and 250 km, the altitude varies greatly from about 100 m at its southern border to a maximum of 8848 min the northern part. Like the variation in altitude, climatic condition varies quite a lot. Long-term monthly mean erythemal UV daily dose values for Nepal are evaluated using Total Ozone Mapping Spectrometer (TOMS) estimation from the time of its overpass between 1996 and 2003. The results are presented as summer and winter maps of mean UV levels in each satellite grid. The mean winter erythemal UV daily dose ranges between 2.1 and 3.6 kJ m-2 whereas summer values are found to lie between 4.6 and 9.7 kJ m-2. The altitude variation increases the UV levels by about 0.2 kJ km-1 in winter months, and 0.9 kJ km-1 in summer. A multiyear monthly average erythemal daily dose in most of the areas shows that the summer value is about three times higher than that in winter. Although year-to-year variation is not pronounced in high- and mid-elevation regions, UV levels seemed to decrease from 1997 to 2002 in the southern part of the country in the low elevation region by about 5.35%. Due to the combined effects of the altitude, low ozone concentration in the troposphere, and thin air, surface UV radiation at higher altitudes is found to be higher than in the surrounding regions.  相似文献   

刺参雌核发育二倍体的诱导及其早期生长发育     

聂鸿涛  李琪  于瑞海 《中国海洋大学学报(自然科学版)》2011,41(9):31-35

紫外线照射使精子遗传物质失活,用细胞松弛素B(CB)处理受精卵抑制第二极体释放,诱导刺参(Apostichopusjaponicus)雌核发育二倍体。用强度为2561μW/(cm2.s)的紫外线(254 nm)照射不同时间的精子与正常卵子受精。结果发现随照射时间的增加,卵裂率、早期胚胎存活率和小耳幼虫发生率逐渐降低,照射30 s时小耳幼虫发生率降为0。受精后35 min,显微镜下观察到有20%~30%受精卵排出第1极体时,用浓度0.5μg/mL的CB持续处理受精卵20 min,诱导出刺参第二极体抑制型雌核发育二倍体,雌核发育二倍体发育速度低于正常二倍体。微卫星分析表明,雌核发育二倍体诱导成功率为93.3%。  相似文献   

大气臭氧层,紫外辐射与人类健康   总被引：16，自引：0，他引：16  

柳燕 《地球物理学进展》1998,13(3):103-110

本文首先评述了近数十年来大气Ｏ３层的演变,其中包括全球与中国地区及南极臭氧洞的情况,之后,评述了由此引发的达地面太阳紫外辐射强度的变化,以及对人类健康与环境的影响。  相似文献   

Performance of A Combination Process of UV/H2O2/Micro‐Aeration for Oxidation of Dichloroacetic Acid in Drinking Water     

WenHai Chu  N. Y. Gao  Y. Deng 《洁净——土壤、空气、水》2009,37(3):233-238

The decomposition of dichloroacetic acid (DCAA) in water using a UV/H₂O₂/micro‐aeration process was investigated in this paper. DCAA cannot be removed by UV radiation, H₂O₂ oxidation or micro‐aeration alone, while UV/H₂O₂/micro‐aeration combination processes have proved effective and can degrade this compound completely. With initial concentrations of about 110 μg/L, more than 95.1% of DCAA can be removed in 180 min under UV intensity of 1048.7 μW/cm², H₂O₂ dosage of 30 mg/L and micro‐aeration flow rate of 2 L/min. However, more than 30 μg/L of DCAA was left after 180 min by UV/H₂O₂ combination process without micro‐aeration with the same UV intensity and H₂O₂ dosage. The effects of applied UV radiation intensity, H₂O₂ dose, initial DCAA concentration and pH on the degradation of DCAA have been examined in this study. Degradation mechanisms of DCAA with hydroxyl radical oxidation have been discussed. The removal rate of DCAA was sensitive to operational parameters. There was a linear relationship between rate constant k and UV intensity and initial H₂O₂ concentration, which indicated that a higher removal capacity can be achieved by improvement of both factors. A newly found nitrogenous disinfection by‐product (N‐DBP)‐DCAcAm, which has the potential to form DCAA, was easier to remove than DCAA by UV/H₂O₂ and UV/H₂O₂/micro‐aeration processes. Finally, a preliminary cost comparison revealed that the UV/H₂O₂/micro‐aeration process was more cost‐effective than the UV/H₂O₂ process in the removal of DCAA from drinking water.  相似文献   

Optimization of a Photo‐assisted Fenton Oxidation Process: A Statistical Model for MDF Effluent Treatment     

Maedeh Galehdar  Habibollah Younesi  Mojtaba Hadavifar  Ali Akbar Zinatizadeh 《洁净——土壤、空气、水》2009,37(8):629-637

In the present study, the effects of initial COD (chemical oxygen demand), initial pH, Fe²⁺/H₂O₂ molar ratio and UV contact time on COD removal from medium density fiberboard (MDF) wastewater using photo‐assisted Fenton oxidation treatment were investigated. In order to optimize the removal efficiency, batch operations were carried out. The influence of the aforementioned parameters on COD removal efficiency was studied using response surface methodology (RSM). The optimal conditions for maximum COD removal efficiency from MDF wastewater under experimental conditions were obtained at initial COD of 4000 mg/L, Fe²⁺/H₂O₂ molar ratio of 0.11, initial solution pH of 6.5 and UV contact time of 70 min. The obtained results for maximum COD removal efficiency of 96% revealed that photo‐assisted Fenton oxidation is very effective for treating MDF wastewater.  相似文献