Molecular weight distribution,analytical and spectroscopic characterization of humic fractions sequentially isolated by organic solvents from a brown coal humic acid     

Nicola Senesi  Sandor Sipos 《Organic Geochemistry》1985,8(2):157-162

A sequential fractionation procedure employing a series of selected mild organic solvents of different polarity has been applied for the isolation of chemically different organic fractions from a brown coal humic acid. Elemental composition, molecular weight distribution, i.r. and electron spin resonance analysis were carried out on the isolated humic fractions. They were characterized by: (a) a low polydispersity, (b) a decreasing aliphatic and increasing aromatic character along the series, (c) very different molecular weight which significantly correlated with E₄/E₆ ratios (particle aggregation and molecular association) and free radical concentrations (chemical and biochemical activity). Significant correlations were found between physico-chemical parameters of the isolated humic fractions, i.e. M_n, M_w, E₄/E₆ ratios, spins/g contents and the dielectric constants of the solvents used. This suggested the efficiency of the applied procedure in isolating chemically different organic fractions from the bulk, original humic acid.  相似文献   

2D magnetic resonance tomography applied to karstic conduit imaging   总被引：1，自引：1，他引：1  

J.-F. Girard  M. Boucher  A. Legchenko  J.-M. Baltassat 《Journal of Applied Geophysics》2007,63(3-4):103-116

Karstic conduits play a crucial role for water supply in many parts of the world. However, the imaging of such targets is generally a difficult task for most geophysical methods. Magnetic Resonance Sounding (MRS) is a geophysical method designed for imaging of water bearing structures. Initially, MRS was developed for characterizing horizontally stratified aquifers. However, when applying a 1D MRS measuring setup to the imaging of 2D–3D targets, the size of which may be much smaller than the loop, the accuracy and the lateral resolution may not be sufficient. We have studied the possibility of simultaneously processing several MRS aligned along a profile to perform a Magnetic Resonance Tomography (MRT). This work emphasizes the gain of resolution for 2D–3D imagery of MRT versus the interpolation of 1D inversion results of MRS along the same profile. Numerical modelling results show that the MRT response is sensitive to the size and location of the 2D target in the subsurface. Sensitivity studies reveal that by using the coincident transmitting/receiving (TX/RX) setup and shifting the loop around the anomaly area, the depth, section and position of a single karstic conduit with a size smaller than the MRS loop size can be resolved. The accuracy of the results depends on the noise level and signal level, the latter parameter being linked to the depth and volume of the karstic conduit and the water content in the limestone matrix. It was shown that when applying MRT to the localization of 2D anomalies such as karstic conduits, the inclination of the geomagnetic field, the orientation of the MRT profile and the angle of crossover of the conduit by the MRT profile must be taken into account. Otherwise additional errors in interpretation should be expected. A 2D inversion scheme was developed and tested. Both numerical and experimental results confirm the efficiency of the developed approach.  相似文献   

Experimental study of surface texture and resonance mechanism of booming sand     

Qu JianJun  Zhang KeCun  Sun Bo  Jiang ShengXiang  Dong GuangRong  Zu RuiPing  Fang HaiYan 《中国科学D辑(英文版)》2007,50(9):1351-1358

The sound-producing mechanism of booming sand has long been a pending problem in the blown sand physics. Based on the earlier researches, the authors collected some silent sand samples from Teng- ger Desert, Australian Desert, Kuwait Desert, beaches of Hainan Island and Japanese coast as well as the soundless booming sand samples from the Mingsha Mountain in Dunhuang to make washing ex- periments. In the meantime the chemical corrosion experiment of glass micro-spheres, surface coating experiment and SEM examination were also conducted. The experimental results show that the sound production of booming sand seems to have nothing to do with the presence of SiO2 gel on the surface of sand grains and unrelated to the surface chemical composition of sand grains but is related to the resonance cavities formed by porous (pit-like) physical structure resulting from a number of factors such as wind erosion, water erosion, chemical corrosion and SiO2 gel deposition, etc. Its resonance mechanism is similar to that of Hemholz resonance cavity. Under the action of external forces, nu- merous spherical and sand grains with smooth surface and porous surface are set in motion and rub with each other to produce extremely weak vibration sound and then become audible sound by human ears through the magnification of surface cavity resonance. However the booming sands may lose their resonance mechanism and become silent sand due to the damping action caused by the invasion of finer particles such as dust and clay into surface holes of sand grains. Therefore, clearing away fine pollutants on the quartz grain surface is an effective way to make silent sand emit audible sound.  相似文献   

海潮负荷对自由核章动参数拟合的影响   总被引：3，自引：1，他引：3  

徐建桥  孙和平  罗少聪 《测绘学报》2001,30(3):214-219

基于武汉基准台超导重力仪重力潮汐观测资料 ,利用根据不同海潮模型获得的负荷重力改正值对观测数据作海潮改正 ,拟合了地球自由核章动 ( FCN)共振参数。结果表明 FCN的本征周期为 435 .2恒星日 ,品质因子为 4730 ,复共振强度为 ( - 6.34× 1 0 - 4,- 0 .0 9× 1 0 - 4)°/h。不同的海潮模型对 FCN本征周期和共振强度实部计算结果的影响很小 ,差异分别不超过± 1 .6%和± 7.7% ,对品质因子 Q值和共振强度虚部拟合结果的影响非常显著。基于 Ori96全球海潮模型得到的重力改正值可以很好地解释武汉基准台周日重力潮汐观测残差。  相似文献   

Long internal waves in shear flows: topographic resonance and wave-induced global instability     

Bang-ji Wang  Larry G. Redekopp   《Dynamics of Atmospheres and Oceans》2001,33(4)

Issues pertaining to a mechanism whereby long internal waves in shallow seas may give rise to enhanced rates of resuspension of sedimentary material are addressed. The proposed mechanism is intimately related to the creation of conditions in the bottom boundary layer which are favorable for flow separation and spontaneous onset of global instability. It is shown that long waves generated by topographic resonance and propagating upstream against the oncoming current, especially a sheared current, have a strong tendency to release a coherent, pulsating dynamics in their footprint. The passage-through-resonance problem for a sheared, stratified flow is considered, conditions for topographic resonance in the flow model are defined, and preliminary results for the unsteady dynamics in the boundary layer under the footprint of a long wave packet are presented.  相似文献   

Resonant period and Q of the Celtic Sea and Bristol Channel     

R.A. Heath 《Estuarine, Coastal and Shelf Science》1981,12(3):291-301

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Extended Fundamental Model of Resonance     

Sławomir Breiter 《Celestial Mechanics and Dynamical Astronomy》2003,85(3):209-218

Fundamental models are the simplest, one degree of freedom Hamiltonians that serve as a tool to understand the qualitative effects of various resonances. A new, extended fundamental model (EFM) is proposed in order to improve the classical, Andoyer type, second fundamental model (SFM). The EFM Hamiltonian differs from the SFM by the addition of a term with the third power of momentum; it depends on two free parameters. The new model is studied for the case of a first-order resonance, where up to five critical points can be present. Similarly, to the respective SFM, it admits only the saddle-node bifurcations of critical points, but its advantage lies in the capability of generating the separatrix bifurcations, known also as saddle connections. The reduction of parameters for the EFM has been performed in a way that allows the use of the model in the case of the so-called abnormal resonance.  相似文献   

综合小波分析与分形方法进行弱磁异常识别   总被引：1，自引：0，他引：1  

耿喜哲  张春华 《物探与化探》2002,26(2):126-130,125

利用小波分析塔式算法对单一分形模型数据进行处理,结合“随机共振”理论,对高精度弱磁异常中的噪声和误差进行有效的分析评价,依据趋势分析方法获得的剩余磁异常,提出“加窗移动”最小二乘方法对应用非整数阶微积分的布郎运动正态随机行走进行控制,为高精度弱磁异常的有效识别提供有益的指导。  相似文献   

利用核磁共振技术对丘陵油田低渗储层可动油的研究   总被引：1，自引：0，他引：1  

刘曰强  朱晴  梁文发  阳兴华 《新疆地质》2006,24(1):52-54

为了定量评价储层可动油饱和度及渗流能力,应用核磁共振技术对丘陵油田40块岩心的可动油饱和度进行了定量测试.研究表明,丘陵油田低渗透储层可动油饱和度值的分布范围是4.8%~56.7%,平均值为33.4%.可动油饱和度高低与岩心孔隙度、渗透率及驱油效率呈正相关关系.各类储层可动油饱和度差异较大,储层沉积微相及物性决定了可动油饱和度和渗流能力的大小.  相似文献   

NUMERICAL EXPERIMENTS OF EFFECT OF SSTA OVER THE INDIAN OCEAN ON ATMOSPHERIC LOW-FREQUENCY OSCILLATION IN THE EXTRATROPICAL LATITUDE     

邱明宇  陆维松  陈汇林  蔡亲波 《热带气象学报(英文版)》2007,13(1):73-76

Numerical experiments on forcing dissipation and heating response of dipole (unipole) are carried out using global spectral models with quasi-geostrophic barotropic vorticity equations. For each experiment model integration is run for 90 days on the condition of three-wave quasi-resonance. The results are given as follows: Under the effects of dipole (unipole) forcing source and basic flow intensity, there exist strong interactions among the three planetary waves and quasi-biweekly and intraseasonal oscillation of the three planetary waves. In the meantime, the changes in the intensity of dipole or unipole forcing source and basic flow have different frequency modulation effects on LFO in the middle and higher latitudes. The results of the stream function field of three quasi-resonant waves evolving with time confirm that the low-frequency oscillation exists in extratropical latitude.  相似文献