河流调整中的熵、熵产生和能耗率的变化   总被引：8，自引：0，他引：8       下载免费PDF全文

徐国宾  练继建 《水科学进展》2004,15(1):1-5

河流是一个真正的开放系统,而不是孤立系统或封闭系统。运用经典热力学和非平衡态热力学基本原理,分析研究了河流调整中的熵、熵产生和能耗率的变化。指出:熵和熵产生是两个不同的概念;最小熵产生原理等价于最小能耗率原理;冲积河流在调整过程中遵循最小熵产生原理或最小能耗率原理,而不是最大熵原理。  相似文献   

超轻型井点降水新技术的研究与应用          下载免费PDF全文

宁晋生  朱淑兰  武先岭  习胜强 《探矿工程》2004,31(2):6-8

分析了轻型井点降水设备的现状与不足，提出了超轻型井点降水新技术，即对现有轻型井点降水设备进一步轻化。介绍了轻化改进的措施，并通过工程检验，取得了良好效果。  相似文献   

The structural role of Ti in aluminosilicate liquids in the glass transition range: insights from heat capacity and shear viscosity measurements     

Mathieu Roskosz  M.J Toplis 《Geochimica et cosmochimica acta》2004,68(3):591-606

The shear viscosities and 1 bar heat capacities of glasses and melts along the 67mol% silica isopleth in the system SiO₂-Al₂O₃-Na₂O-TiO₂ have been determined in the temperature ranges 780-1140 K and 305-1090 K respectively. Anomalous behaviour of both these properties is observed for compositions rich in TiO₂ and/or Al₂O₃, an observation attributed to liquid-liquid phase separation followed by anatase crystallization. For samples which do not show anomalous behaviour, it is found that the partial molar heat capacity of the TiO₂ component previously determined in Al-free compositions reproduces our heat capacities to within 1.3%. Viscosity data show that addition of TiO₂ tends to increase viscosity and melt fragility at constant temperature. Furthermore, heat capacity and viscosity data may be combined within the framework of the Adam-Gibbs theory to extract values of the configurational entropy of the liquids and qualitative estimates of the variation of the average energy barrier to viscous flow. Configurational entropy at 900K is inferred to decrease upon addition of TiO₂, in contrast to previous results from Al-free systems. The compositional limit separating normal from anomalous behaviour, as well as the data for homogenous melts have been used to constrain the structural role of Ti in these samples. Our data are consistent with a majority of Ti in five-fold coordination associated with a titanyl bond, in agreement with previous spectroscopic studies. Furthermore, we find no evidence for a Ti-Al interaction in our samples, and we are led to the conclusion that Al and Ti are incompletely mixed, a hypothesis consistent with the observed reduction of configurational entropy upon addition of TiO₂, suggesting an important role of medium range order in controlling the variations in thermodynamic properties.  相似文献   

基于灰关联分析的GPS高程拟合加权平均函数模型权函数优选   总被引：6，自引：0，他引：6  

邱斌  朱建军 《测绘信息与工程》2004,29(1):13-14

基于灰色系统理论的灰关联分析方法,提出了权函数的优选方法,实例分析表明其具有较好的实用价值.  相似文献   

Entropy Analysis of Multiple Scale Causality and Qualitative Causal Shifts in Spatial Systems*     

Jonathan D. Phillips 《The Professional geographer》2005,57(1):83-93

Spatial systems are typically characterized by multiple controlling factors and processes operating at different spatial and temporal scales (multiple scale causality [MSC]). An entropy decomposition‐based approach to MSC is presented here in two contexts. First, given maps or distributions of an observed phenomenon at two or more scales, the contribution at more local or global (relative to the primary scale of observation) controls to the observed entropy can be estimated. Second, a theoretical treatment of the entropy decomposition equations shows that as the range of scale is increased by broadening or narrowing resolutions or by incorporating more controls, the influence of larger or smaller‐scale influences not only changes, but may change qualitatively, e.g., in terms of having positive (entropy‐increasing) or negative (information‐increasing) effects. Such qualitative causal shifts have implications for efforts to use any single causal explanation across the molecular to planetary spatial and instantaneous to geological range of scales relevant to physical geography. The entropy decomposition method is illustrated with an application to soil landscapes in the Ouachita Mountains, Arkansas.  相似文献   

Are peatlands in different states with respect to their thermodynamic behaviour? A simple test of peatland energy and entropy budgets     

Fred Worrall  Ross Morrison  Chris Evans  Joerg Kaduk  Susan Page  Alex Cumming  Mark Rayment  Nicholas Kettridge 《水文研究》2021,35(12):e14431

Whilst all ecosystems must obey the second law of thermodynamics, these physical bounds and controls on ecosystem evolution and development are largely ignored across the ecohydrological literature. To unravel the importance of these underlying restraints on ecosystem form and function, and their power to inform our scientific understanding, we have calculated the entropy budget of a range of peat ecosystems. We hypothesize that less disturbed peatlands are ‘near equilibrium’ with respect to the second law of thermodynamics and thus respond to change by minimizing entropy production. This ‘near equilibrium’ state is best achieved by limiting evaporative losses. Alternatively, peatlands ‘far-from-equilibrium’ respond to a change in energy inputs by maximizing entropy production which is best achieved by increasing evapotranspiration. To test these alternatives this study examined the energy balance time series from seven peatlands across a disturbance gradient. We estimate the entropy budgets for each and determine how a change in net radiation (ΔR_n) was transferred to a change in latent heat flux (ΔλE). The study showed that: (i) The transfer of net radiation to latent heat differed significantly between peatlands. One group transferred up to 64% of the change in net radiation to a change in latent heat flux, while the second transferred as little as 27%. (ii) Sites that transferred the most energy to latent heat flux were those that produced the greatest entropy. The study shows that an ecosystem could be ‘near equilibrium’ rather than ‘far from equilibrium’.  相似文献   

A fully coupled THM model based on a non‐equilibrium thermodynamic approach and its application          下载免费PDF全文

Z. Zhang  X. Cheng 《国际地质力学数值与分析法杂志》2017,41(4):527-554

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基于地性线分级的DEM信息量计算方法研究   总被引：1，自引：0，他引：1  

张萍  江文萍  邓晓龙  李伟 《测绘与空间地理信息》2016,(7)

主要对基于DEM提取的地性线进行信息量的定量分析,探讨地性线的信息量与分辨率、地形单元的关系。这个过程中首先利用河网的自相似理论研究与当前DEM所代表的地貌详细程度相适宜的地性线提取的阈值区间,并讨论此阈值下地性线的分级,以此为基础通过以该分级为权重进行DEM地形信息量的计算。实践证明,这种顾及地性线等级的DEM信息量计算方法能较准确地反映地性线的分布规律和不同等级的要素造成的信息量度量差异。  相似文献   

基于等价权抗差估计和线性规划的天线曲面拟合算法     

苏小文  李志静  黄浩 《测绘与空间地理信息》2016,(7):207-209

现有天线曲面拟合算法均基于最小二乘法,难以消除多个粗差对拟合结果的影响。本文基于等价权抗差估计思想,利用线性规划计算残差初值,再进行选权迭代计算。通过算例,证明本文方法能较好地探查多个粗差,且计算结果精度更高。  相似文献   

纹理特征向量与最大化熵法相结合的SAR影像非监督变化检测   总被引：1，自引：0，他引：1  

庄会富  邓喀中  范洪冬 《测绘学报》2016,45(3):339-346

合成孔径雷达(SAR)影像具有明显的斑点噪声,在变化检测中,一般需要考虑空间邻域信息。本文结合SAR影像丰富的纹理信息,提出一种考虑空间邻域信息的高分辨率SAR影像非监督变化检测方法,用基于灰度共生矩阵(GLCM)的32维纹理特征向量构造差异影像。通过最大化熵法自动选取阈值,对精度指标随窗口大小的变化进行回归分析,得到适合于变化检测的窗口为11×11。试验表明,本文方法优于马尔科夫随机场法,可以减小斑点噪声的影响,有效提高高分辨率SAR影像变化检测的精度。  相似文献