Adsorption of Au(III) and Au(I) complexes on δ-MnO2     

Yong Ran  Jiamo Fu  R. J. Gilkes  R. W. Rate 《中国科学D辑(英文版)》1999,42(2):172-181

The sorption of AuCl₄ ⁻,AuCl₂ ⁻ and Au(S₂O₃)^3- on δ-MnO₂ was investigated at pH2–11.6, 0.01 mol/L and 0.1 mol/L NaNO₃ solutions. At pH 4 in two electrolyte strength solutions, Au sorption densities on δ-MnO₂ are 0.18–0.21 and 0.28μmoL/m² for AuCl₄ ⁻ and Au(S₂O₃)₂ ^3-, respectively, and the Au surface coverage is approximate to or lower than 1%. This adsorption of the two Au complexes decreases as the solution pH increases, which conforms to the sorption regularity of the anion on δ-MnO₂. The Au sorption decreases in the sequence of Au(S₂O₃)₂ ^3- >AuCl₄ ⁻ >AuC1₂ ⁻. The intrinsic equilibrium constants (logK ^int) of the three Au complexes are 1.17–2.7, much higher than those of Cu and Cd. The hydrolysis products of AuCl₄ ^- are preferentially adsorbed by δ-MnO₂ and the inner-sphere Au-surface complexes are formed on the surface. Project supported by the National Studying-abroad Foundation, the National Natural Science Foundation of China (Grant No. 49573200) and the Australian Mining Industry.  相似文献   

数字地震仪(或雷达)的文件格式及其转换方法   总被引：3，自引：0，他引：3  

胡家富  段永康 《地震地磁观测与研究》1999,20(3):36-41

详细介绍了ＳＥＧ新规定的ＳＥＧ－２标准及其文件结构,这一标准不但适用于数字地震仪,而且也适用于地质雷达等数字化记录设备。同时给出了一个在ＩＢＭ－ＰＣ环境不读取ＳＥＧ－２数据文件的Ｃ语言示范程序,根据这个示范程序,用户可以很方便地将ＳＥＧ－２数据文件转换成适用于特定应用软件的数据格式。  相似文献   

TritonX-100－5-Br-PADAP光度法测定铜和镍   总被引：2，自引：0，他引：2  

萨木嘎  刘颖  嘎日迪 《岩矿测试》1999,18(4):5

研究了非离子型表面活性剂Ｔｒｉｔｏｎ Ｘ－ １００ 存在下,用５ － Ｂｒ － ＰＡＤＡＰ 光度法测定铜、镍的方法。结果表明：在ｐＨ９ ．０ 的硼砂缓冲介质中,５ － Ｂｒ － ＰＡＤＡＰ 与铜和镍生成紫红色络合物,λＣｕｍ ａｘ ＝ ５７５ ｎｍ ,εＣｕ ＝ １ ．０４ ×１０５ Ｌ·ｍｏｌ－ １·ｃｍ － １ ;λＮｉｍ ａｘ ＝ ５７５ ｎｍ ,εＮｉ ＝ １ ．１４ ×１０５ Ｌ·ｍｏｌ－ １·ｃｍ － １ 。铜和镍的质量浓度分别在０ ～５６０ μｇ／ Ｌ和０ ～４４０ μｇ／ Ｌ符合比尔定律。加入六偏磷酸钠后,由于偏磷酸镍的形成,镍不再与５ － Ｂｒ － ＰＡＤＡＰ 显色,可通过铜及铜镍总量的测定,计算出镍的含量。用该方法实测了钢样中铜和镍的含量,结果与推荐值相符,对铜和镍５ 次测定的ＲＳＤ均小于５ ％ 。  相似文献   

Improved Method for Calculating Anthropogenic CO2 in the Upper Layer of the North Pacific Subtropical Gyre along 175°E     

Yoshiyuki Takahashi  Eiji Matsumoto  Yutaka W. Watanabe 《Journal of Oceanography》1999,55(6):717-729

Seawater samples were collected in the North Pacific along 175°E during a cruise of the Northwest Pacific Carbon Cycle Study (NOPACCS) program in 1994. Many properties related to the carbonate system were analyzed. By using well-known ratios to correct for chemical changes in seawater, the CO₂ concentration at a given depth was back calculated to its initial concentration at the time when the water left the surface in winter. We estimated sea-surface CO₂ and titration alkalinity (TA) in present-day winter, from which we evaluated the degree of air-sea CO₂ disequilibrium in winter was. Using a correction factor for air-sea CO₂ disequilibrium in winter, we reconstructed sea-surface CO₂ in pre-industrial times. The difference between the back-calculated initial CO₂ and sea-surface CO₂ in pre-industrial times should correspond to anthropgenic CO₂ input. Although the mixing of different water masses may cause systematic error in the calculation, we found that the nonlinear effect induced by the mixing of different water masses was negligible in the upper layer of the North Pacific subtropical gyre along 175°E. The results of our improved method of assessing the distribution of anthropogenic CO₂ in that region show marked differences from those obtained using the previous back-calculation method.  相似文献   

从正反两个角度探讨摆式波力电站的吸能机制     

李继刚  李殿森 《海洋技术学报》1999,18(1):55-59

本文主要论述了摆式波力电站的吸能机制,提出了吸能原理,从力和作功的角度探讨了吸能的实质,分析比较了几种摆板运动方程形式之间的联系和区别。给出了波能转换效率的定义,并进一步分析了波能转换效率的组成和性质。  相似文献   

水声学方法对黄河口水下底坡失稳现象研究     

阎通  李萍  杨作升  庞重光 《中国海洋大学学报(自然科学版)》1999,(2)

对黄河三角洲东北部地区的高分辨率水声学资料进行了综合研究。根据所记录的破坏土体变形程度、运动产生的平面形状和地貌特征形态,对土体失稳过程进行分类：浅表土体变形、塌陷凹坑、滑坡和沉积物重力流。结果表明：（１）浅表土体形变的变形程度最低,出现在研究区斜坡上部平滑海底,主要为绳网状泄水构造和表层拉张裂隙。（２）塌陷凹坑在研究区内广泛出现,是局部土体液化后发生了垂直沉降的结果。（３）滑坡多发生在水下斜坡的中上部,由弧形塌陷区、狭窄的冲沟通道和负地形沉积物堆积区组成。滑坡陡坎后缘发现拉张裂隙。（４）沉积物重力流是土体发生变形程度最大,搬运距离最长的土体破坏变形形式。局部区域多次受到沉积物重力流切割和充填作用。  相似文献   

基于ST-ConvLSTM的南海海表面CO₂分压的空间和时间序列预测     

高宇  李爽  郝鹏  宋金宝 《海洋与湖沼》2023,54(6):1573-1585

海表面二氧化碳分压(pCO₂)的未来变化趋势,对统计评估全球碳收支以及理解全球气候变化背景下的海洋酸化现象至关重要。目前传统的海面pCO₂预测方法大部分基于有限的实测数据,然而实测数据存在着时间和地理方面的制约,且计算成本较高。近年来,随着时空观测数据的爆炸性增长,基于深度学习的数据驱动模型在海表面pCO₂预测方面中表现出良好的潜力。然而,由于多种环境因素与海表面pCO₂之间的关系错综复杂,到目前为止尚无十分简单有效的相关模型来对海表面pCO₂进行预测。为应对这一挑战,利用时空卷积长短时记忆神经网络(ST-ConvLSTM)模型,通过海面温度(sea surface temperature, SST)、海面盐度(sea surface salinity, SSS)、叶绿素a浓度(chl a)和海面pCO₂数据,预测南海的海面pCO₂,并将2019年1～12月的数据作为测试集对模型的表现进行了验证。结果显示, ST-ConvLSTM模型...  相似文献   

Velocity structure in the South Yellow Sea basin based on first-arrival tomography of wide-angle seismic data and its geological implications     

Weina Zhao  Zhiqiang Wu  Fanghui Hou  Xunhua Zhang  Tianyao Hao  Hanjoon Kim  Yanpeng Zheng  Shanshan Chen  Huigang Wang 《海洋学报(英文版)》2023,42(2):104-119

The South Yellow Sea basin is filled with Mesozoic–Cenozoic continental sediments overlying pre-Palaeozoic and Mesozoic–Palaeozoic marine sediments. Conventional multi-channel seismic data cannot describe the velocity structure of the marine residual basin in detail, leading to the lack of a deeper understanding of the distribution and lithology owing to strong energy shielding on the top interface of marine sediments. In this study, we present seismic tomography data from ocean bottom seismogra...  相似文献   

Comparative assessment of nitrogen fixation rate by ¹⁵N₂ tracer assays in the South China Sea     

Danyang Li  Minfang Zheng  Yusheng Qiu  Limin Lai  Nengwang Chen  Hongmei Jing  Run Zhang  Min Chen 《海洋学报(英文版)》2023,42(1):75-82

Nitrogen fixation is one of the most important sources of new nitrogen in the ocean and thus profoundly affects the nitrogen and carbon biogeochemical processes. The distribution, controlling factors, and flux of N₂ fixation in the global ocean remain uncertain, partly because of the lack of methodological uniformity. The 15N₂ tracer assay (the original bubble method → the 15N₂-enriched seawater method → the modified bubble method) is the mainstream method for field measurements of N₂ fixation rates (NFRs), among which the original bubble method is the most frequently used. However, accumulating evidence has suggested an underestimation of NFRs when using this method. To improve the availability of previous data, we compared NFRs measured by three 15N₂ tracer assays in the South China Sea. Our results indicate that the relationship between NFRs measured by the original bubble method and the 15N₂-enriched seawater method varies obviously with area and season, which may be influenced by incubation time, diazotrophic composition, and environmental factors. In comparison, the relationship between NFRs measured by the original bubble method and the modified bubble method is more stable, indicating that the N₂ fixation rates based on the original bubble methods may be underestimated by approximately 50%. Based on this result, we revised the flux of N₂ fixation in the South China Sea to 40 mmol/(m2·a). Our results improve the availability and comparability of literature NFR data in the South China Sea. The comparison of the 15N₂ tracer assay for NFRs measurements on a larger scale is urgently necessary over the global ocean for a more robust understanding of the role of N₂ fixation in the marine nitrogen cycle.  相似文献   

不同碳源对球孢鱼腥藻生长的影响   总被引：2，自引：0，他引：2  

沈银武  利群  朱家明  路景舒  王乾麟 《湖泊科学》1993,5(4):341-344

本文研究了有机碳源和无机碳源对球胞鱼腥藻生长的影响,结果表明:有机碳源中葡萄糖以0.5—1.0μg/mL、蔗糖以5.0μg/mL促进其生长效果最好;无机碳源中,碳酸钠以10.0—15.0μg/mL、碳酸氢钠以10.0μg/mL效果最好。葡萄糖和蔗糖的浓度高低对球孢鱼腥藻叶绿素a的含量没有明显影响,但前者略高于后者。碳酸钠和碳酸氢钠的浓度在5.0μg/mL时均提高了叶绿素a含量。四种碳源都提高了球孢鱼腥藻的同氮活性,有机碳源中蔗糖优于葡萄塘,无机碳源中碳酸钠优于碳酸氢钠。  相似文献