Computational methods for fitting statistical distribution models of multi-site binding equilibria     

Rudolph S. Parrish  E. Michael Perdue 《Mathematical Geology》1989,21(2):199-219

Statistical distribution models of multi-site binding equilibria have potential applicability in the study of acid-base and metal complexation chemistry of humic substances in soils, sediments, and natural waters. A mathematical derivation is presented for the general continuous model for the case of proton binding; computational methods are described for fitting numerically the parameters in such models. Among models considered are those based on nontruncated, truncated, and bimodal (mixed) distributions. Specific emphasis is placed on Gaussian distribution models.  相似文献   

Patterns of dissolved organic matter in subarctic peatlands     

T. R. Moore 《地球表面变化过程与地形》1987,12(4):387-397

Samples of water from poor to very rich fens in the Schefferville region of subarctic Quebec revealed strong spatial and temporal variations in dissolved organic carbon (DOC), ranging from 2 to 40 mg 1^?1. Concentrations of DOC tend to increase during the summer and decrease in the autumn, at most sites, which probably reflects increased plant tissue decomposition and higher rates of evapotranspiration. Principal components analysis revealed that DOC is strongly associated with Fe, NO^?₃-N and NO^?₂-N, but essentially independent of other chemical properties of the peat water, such as pH, Ca, Mg, K, P, and NH⁺₄-N. Based on observed concentrations of DOC and estimates of summer runoff (June to September), export of DOC from four peatlands ranges from 1·1 to 4·9 gCm^?2, with the lowest values for peatlands underlain by dolomite. Molecular weight fractionation of four samples revealed significant differences in the dissolved organic matter (DOM), with the largest fractions (GF/C to 10 000 nmw) being dominant in the more acid samples. The ratio of absorbance at 400 and 600 nm wavelengths (E₄:E₆) has been used as a simple indicator of differences in DOM type, ranging from 3 to 15. There is a strong seasonal pattern of increasing E₄:E₆ ratio during the summer at many sites, though this ratio is essentially independent of other chemical properties of peat waters.  相似文献   

Seasonality in UV transparency of an alpine lake is associated to changes in phytoplankton biomass   总被引：1，自引：0，他引：1  

Ruben Sommaruga  Günther Augustin 《Aquatic Sciences - Research Across Boundaries》2006,68(2):129-141

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矿物材料应用于香烟过滤嘴降害的研究现状与展望     

吴敏  李胜荣 《岩石矿物学杂志》2007,26(2):171-176

总结了近几十年来包括活性炭、沸石、蒙脱石、海泡石、麦饭石、凹凸棒石、氧化铝、氢氧化钠、明矾、纳米材料等矿物材料作为卷烟滤嘴添加剂以去除烟气中有毒有害物质的研究和实验应用及效果。实验结果和市场调查表明,活性炭是减少卷烟危害最快、香烟市场应用增长最快的过滤嘴添加剂。从降低卷烟有害成分的比例和成本等综合因素来看,铝硅酸盐类滤嘴和多材料复合滤嘴亦有很好的应用前景和市场需求,应积极进行研制。  相似文献   

Humic Ion-Binding Model VI: An Improved Description of the Interactions of Protons and Metal Ions with Humic Substances   总被引：1，自引：0，他引：1  

Edward Tipping 《Aquatic Geochemistry》1998,4(1):3-47

Humic Ion-Binding Model VI, a discrete site/electrostatic model of the interactions of protons and metals with fulvic and humic acids, is applied to 19 sets of published data for proton binding, and 110 sets for metal binding. Proton binding is described with a site density, two median intrinsic equilibrium constants, two parameters defining the spread of equilibrium constants around the medians, and an electrostatic constant. Intrinsic equilibrium constants for metal binding are defined by two median constants, log K_MA and log K_MB, which refer to carboxyl and weaker-acid sites respectively, together with a parameter, LK₁, defining the spreads of values around the medians. A further parameter, LK₂, takes account of small numbers of strong binding sites. By considering results from many data sets, a universal average value of LK₁ is obtained, and a correlation established between log K_MB and log K_MA. In addition, a relation between LK₂ and the equilibrium constant for metal-NH₃ complexation is tentatively suggested. As a result, metal-binding data can be fitted by the adjustment of a single parameter, log K_MA. Values of log K_MA are derived for 22 metal species. Model VI accounts for competition and ionic strength effects, and for proton-metal exchange.  相似文献   

A two-dimensional photochemical model of the stratosphere with Rayleigh scattering     

Guido Visconti  Gianni Pitari  Derek Cunnold 《Pure and Applied Geophysics》1980,118(2):1033-1051

Computations of concentrations of minor stratospheric gases using a two-dimensional model of the stratosphere are reported. The model includes Rayleigh scattering. This results in an increase in the photodissociation rate computation time by a factor of 1.5. The effect of ground albedo is assessed by comparing our results with a calculation of photolysis rates for a constant albedo with latitude. Comparison of results with a reference model including only molecular absorption are also made. The largest differences (50%) occur in NO and OH. An approximate expression for including the effects of Rayleigh scattering and surface reflectance in multi-dimensional models is suggested.  相似文献   

Evaluation of Estrogenic Activity and Measurement of EDCs in Wastewater Treatment Plants     

B. C. Lee  J. Y. Jung  H. K. Kim 《中国海洋大学学报(英文版)》2006,5(4):351-356

1IntroductionDuringthe past several years,concern hasincreasedover the potential pollution of watershed by estrogeniccompounds,including steroidal hormones fromhumanand ani mal sources.Effluents from wastewater treat-ment plants are sources of endocrine-d…  相似文献   

一些有机物对Ph、Zn、Cu迁移与沉积作用的实验研究   总被引：1，自引：0，他引：1  

姚志健  肖宗峰  韩蔚田 《现代地质》1994,8(1):94

根据一些有机物在成矿溶液中存在的可能性,作者相继就中性、酸性与碱性氨基酸,以及酒石酸在铅、锌、铜迁移与沉积过程中的作用,进行了模拟实验研究。结果表明,在从９０～２１０℃范围内,酸性氨基酸在热卤水中的存在,比中性和碱性氨基酸更有利于铅、锌、铜的活化、迁移。而酒石酸在热卤水中的存在,只在９０℃或更低时,才是铅、锌等金属活化、迁移的最佳温度条件。且无论哪种有机物在热卤水中的存在,随作用时间及温度的变化,不同金属的活化、迁移明显不同。这表明,金属与氨基酸或其它有机物形成的易溶络合物,其稳定性不仅与金属、氨基酸等有机物的种类有关,而且还受温度的显著影响。  相似文献   

从来克丁物质与微生物相互作用看水产无脊椎动物对疾病的防御活动     

陈皓文  孙丕喜 《海洋科学进展》1998,(1)

本文从水产无脊椎动物与环境的关系论述其来克丁物质的功能;来克丁与微生物间的相互作用包括相互作用中有关来克丁、微生物种类,作用部位和作用物质等。从来克丁在水产无脊椎动物识别外来物质,包括抵御病原体的作用看,健康发展的水产业之一项关键任务便是认识和掌握来克丁在御防病害活动中的机理。  相似文献   

海洋微藻中若干活性物质的开发现状与展望   总被引：4，自引：0，他引：4  

林丽玉 《台湾海峡》1999,18(2):168-171

海洋微藻的开发应用是近几年国内,外的研究热点之一,预计在本世纪末和下世纪半有更大的发展。本文概述了开发利用海洋微藻生产β－胡萝卜素,不饱和脂肪酸,蛋白质及其他生物活性物质的国内,外研究现状与展望。  相似文献