Fe₃O₄/Mg(OH)₂复合材料的制备及形貌控制          下载免费PDF全文

韩文生  李丽娟  宋富根  时东  张禹泽  李娜  郭凡 《盐湖研究》2020,28(3):93-98

通过种子沉积法制备出Fe_3O_4/Mg(OH)_2复合材料并进行XRD、SEM测试分析。探究了氨水的浓度与加入速度、搅拌速度及等因素对磁性复合材料形貌的影响。氨水浓度与注入速度的降低,对氢氧化镁基体形貌的影响是相同的,但要使合成磁性复合材料形貌和四氧化三铁粒子在氢氧化镁中分散性均匀,应控制氨水浓度(ω=2.5%)或加入速度在一个合理的较低值。  相似文献   

Photobleaching of chromophoric dissolved organic matter in natural waters: kinetics and modeling   总被引：9，自引：0，他引：9  

Rossana Del Vecchio  Neil V. Blough   《Marine Chemistry》2002,78(4)

The effects of monochromatic and polychromatic UV and visible (VIS) radiation on the optical properties (absorption and fluorescence) of chromophoric dissolved organic matter (CDOM) were examined for a Suwannee River fulvic acid (SRFA) standard and for water from the Delaware and Chesapeake Bays. The primary (direct) loss of absorption and fluorescence occurred at the irradiation wavelength(s), with smaller secondary (indirect) losses occurring outside the irradiation wavelength(s). The efficiency of both direct and indirect photobleaching decreased monotonically with increasing wavelength. Exposure to polychromatic light increased the CDOM absorption spectral slope (S), consistent with previous field measurements. An analysis of the monochromatic photobleaching kinetics argues that a model based on a simple superposition of multiple chromophores undergoing independent photobleaching cannot apply; this conclusion further implies that the absorption spectrum of CDOM cannot arise solely from a simple superposition of the spectra of numerous independent chromophores. The kinetics of CDOM absorption loss with the monochromatic irradiation were employed to create a simple, heuristic model of photobleaching. This model allowed us to examine the importance of the indirect photobleaching losses in determining the overall photobleaching rates as well as to model the photobleaching of natural waters under polychromatic light fields. Application of this model to natural waters closely predicted the change in the CDOM spectral shape caused by photodegradation. The time scale of this process was consistent with field observations acquired during the summertime for coastal waters in the Middle Atlantic Bight (MAB). The results indicate that the ratio of the photodegradation depth to the mixed layer depth is a key parameter controlling the rate of the photobleaching in surface waters.  相似文献   

海湾扇贝产卵的有效积温   总被引：2，自引：1，他引：2  

周玮  孙景伟  李文姬  王鉴 《海洋与湖沼》1999,30(5):564-567

于１９８７－１９９２年,先后５次进行海湾贝人工促熟产卵试验,扇贝均取自大连市长海县海区,为人工养殖越冬的成贝,每次试验所用扇贝个体数量为６０００－６２００个。用数理统计方法分别拟合５次试验中水温与时间的线性关系Ｆ（Ｘ）,并根据产卵时间Ｘｓ和性腺发育生物学零度７．８℃,计算产卵时水量Ｆ（Ｘｓ）和达到性腺发育生物学零度的时间Ｘ７．８。最后用积温公式分别计算有效积温值,并对试验结果进行统计分析。结果表明  相似文献   

同步改正法平均海面传递应用于海南岛礁测绘的探讨          下载免费PDF全文

张亮  车志伟  张景凯 《海洋技术学报》2019,38(5)

同步改正法因其特点和优势被广泛应用于平均海面传递,文中从平均海面的理论定义和实际计算两方面出发,对同步改正平均海面传递法原理进行了论述。利用海南岛周边的长期验潮站数据,按单站传递和多站组网传递分别分析了同步改正平均海面传递的规律。结果表明,单站传递同步观测10 d能满足岛礁测绘对垂直基准面精度的要求,采用多站组网传递能较明显地减少同步时长较短时的极限误差。当采用多站组网平均海面传递同步观测5 d,其极限误差可达10 cm以内,建议在同步观测时间有限时采用该方法。结合海南岛验潮站和岛礁分布情况,同步改正平均海面传递法应用于海南岛礁测绘是可行的。  相似文献   

Pipe laying simulation with an active reel drive     

Marek Szczotka 《Ocean Engineering》2010,37(7):539-548

Dynamic and quasi-static models for analysis of a pipe lay spread are presented in the paper. Depending on the type of a pipe, spooling it on a big drum (reel) may cause plastic deformations. When the pipe is reeled out at sea, again it undergoes plastic deformations. In order to model such a nonlinear behaviour, a model, which includes both elasto-plastic material characteristics and large deformations, is required. Discretisation of the pipe is performed by means of the Rigid Finite Element Method (RFEM), which allows us to study static and dynamic problems, taking into account required properties of the model. Different sea conditions are simulated and analysed. It is shown how operational conditions can limit the ability of laying operation by a dedicated vessel, due to an unstable system response. The second part of the paper presents an upgrade of a passive reel drive by application of an active drive. In the model used for control applications, the pipe is modelled by a neural network. This allows us to perform a real-time calculations. In this fast-response calculation model, nonlinear aspects of the system are taken into account. The improvements in a pipe laying vessel performance are presented by some results of numerical simulations. The conclusions are also formulated.  相似文献   

Practical kinetic modeling of petroleum generation and expulsion     

John G. Stainforth 《Marine and Petroleum Geology》2009

Models for petroleum generation used by the industry are often limited by (a) sub-optimal laboratory pyrolysis methods for studying hydrocarbon generation, (b) over-simple models of petroleum generation, (c) inappropriate mathematical methods to derive kinetic parameters by fitting laboratory data, (d) primitive models of primary migration/expulsion and its coupling with petroleum generation, and (e) insufficient use of subsurface data to constrain the models. Problems (a), (b) and (c) lead to forced compensation effects between the activation energies and frequency factors of reaction kinetics that are wholly artificial, and which yield poor extrapolations to geological conditions. Simple switch or adsorption models of expulsion are insufficient to describe the residence time of species in source rocks. Yet, the residence time controls the thermal stresses to which the species are subjected for cracking to lighter species.  相似文献   

Kinetic and equilibrium studies of copper-dissolved organic matter complexation in water column of the stratified Krka River estuary (Croatia)     

Yoann Louis  Cdric Garnier  Vronique Lenoble  Stphane Mounier  Neven Cukrov  Dario Omanovi&#x;  Ivanka Pieta 《Marine Chemistry》2009,114(3-4):110-119

An interaction of dissolved natural organic matter (DNOM) with copper ions in the water column of the stratified Krka River estuary (Croatia) was studied. The experimental methodology was based on the differential pulse anodic stripping voltammetric (DPASV) determination of labile copper species by titrating the sample using increments of copper additions uniformly distributed on the logarithmic scale. A classical at-equilibrium approach (determination of copper complexing capacity, CuCC) and a kinetic approach (tracing of equilibrium reconstitution) of copper complexation were considered and compared. A model of discrete distribution of organic ligands forming inert copper complexes was applied. For both approaches, a home-written fitting program was used for the determination of apparent stability constants (K_i^equ), total ligands concentration (L_iT) and association/dissociation rate constants (k_i¹,k_i^- 1).A non-conservative behaviour of dissolved organic matter (DOC) and total copper concentration in a water column was registered. An enhanced biological activity at the freshwater–seawater interface (FSI) triggered an increase of total copper concentration and total ligand concentration in this water layer. The copper complexation in fresh water of Krka River was characterised by one type of binding ligands, while in most of the estuarine and marine samples two classes of ligands were identified. The distribution of apparent stability constants (log K₁^equ: 11.2–13.0, log K₂^equ:8.8–10.0) showed increasing trend towards higher salinities, indicating stronger copper complexation by autochthonous seawater organic matter.Copper complexation parameters (ligand concentrations and apparent stability constants) obtained by at-equilibrium model are in very good accordance with those of kinetic model. Calculated association rate constants (k₁¹:6.1–20 × 10³ (M s)^− 1, k₂¹: 1.3–6.3 × 10³ (M s)^− 1) indicate that copper complexation by DNOM takes place relatively slowly. The time needed to achieve a new pseudo-equilibrium induced by an increase of copper concentration (which is common for Krka River estuary during summer period due to the nautical traffic), is estimated to be from 2 to 4 h.It is found that in such oligotrophic environment (dissolved organic carbon content under 83 µM_C, i.e. 1 mg_CL^− 1) an increase of the total copper concentration above 12 nM could enhance a free copper concentration exceeding the level considered as potentially toxic for microorganisms (10 pM).  相似文献   

水产养殖遥感监测及信息自动提取方法研究   总被引：2，自引：0，他引：2  

关学彬  张翠萍  蒋菊生  曹建华 《国土资源遥感》2009,(2):41-44

以海南省文昌地区为例,在沿海地区尝试利用遥感监测的手段提取水产养殖地块和面积.采用面向对象的分类方法进行监测,取得了理想效果,同时也提出了提高分类精度的建议.  相似文献   

基于EMD的中国大陆强震活动特征分析   总被引：1，自引：0，他引：1  

李志雄  朱航  刘杰  曾钢平  丘学林 《地震》2007,27(3):57-62

利用EMD方法对中国大陆年度最大地震时间序列进行逐级分解, 得到5个本征模态函数(IMF)项和1个趋势项, 分析了各个IMF分量不同的周期成分同地球自转速度变化、 太阳黑子活动和潮汐运动等环境因子之间的相关关系, 初步探讨了各个IMF分量的物理机理及其对中国大陆地震活动的影响。  相似文献   

山区年、月平均温度推算方法的研究   总被引：9，自引：0，他引：9  

卢其尧 《地理学报》1988,(3)

本文提出了山区年、月平均温度空间分布的推算方法,并提供了相应的小地形温度订正值。该方法在福建省沙溪流域山区实际应用的结果表明,能有效地揭示山区年、月平均温度空间分布的宏观与微观变化,效果满意,精度较高。  相似文献